Products should be drawn for the given reactions based on their reagents. Concept introduction: Syn -dihydroxylation: syn - dihydroxylation is a process of adding two –OH groups from the same plane to the alkene . Trans -dihydroxylation: trans - dihydroxylation is a process of adding two –OH groups from different planes to the alkene To find: the products during the syn-dihydroxylation of the trans-2-butene.

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Answer 1

Question

Chapter 9.10, Problem 33CC

(a)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

(b)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

(c)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

(d)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

(e)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

(f)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

Answer 2

Question

Chapter 9.10, Problem 33CC

(a)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

(b)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

(c)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

(d)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

(e)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

(f)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

Expert Solution & Answer

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Answer 3

Question

Chapter 9.10, Problem 33CC

(a)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

(b)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

(c)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

(d)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

(e)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

(f)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

Expert Solution & Answer

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Answer 4

Question

Chapter 9.10, Problem 33CC

(a)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

(b)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

(c)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

(d)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

(e)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

(f)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

Expert Solution & Answer

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Answer 5

Chapter 9.10, Problem 33CC

(a)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

(b)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

(c)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

(d)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

(e)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

(f)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

Answer 6

Chapter 9.10, Problem 33CC

(a)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

Answer 7

Chapter 9.10, Problem 33CC

(a)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

Answer 11

(c)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

Answer 12

(d)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the syn-dihydroxylation of the trans-2-butene.

Answer 16

(f)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

Answer 17

(f)

Interpretation Introduction

Interpretation:

Products should be drawn for the given reactions based on their reagents.

Concept introduction:

Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.

Trans-dihydroxylation: trans- dihydroxylation is a process of adding two –OH groups from different planes to the alkene

To find: the products during the anti-hydroxylation of the cis-2-butene.

Answer 18

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Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 9.3 - Prob. 3PTS Ch. 9.3 - Prob. 4ATS Ch. 9.3 - Prob. 5ATS Ch. 9.3 - Prob. 2LTS Ch. 9.3 - Prob. 7PTS Ch. 9.3 - Prob. 8ATS Ch. 9.3 - Prob. 9ATS Ch. 9.4 - Prob. 10CC Ch. 9.4 - Prob. 11CC Ch. 9.4 - Prob. 3LTS

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Chapter 9 Solutions