Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
Book Icon
Chapter 9.12, Problem 36PTS

(a)

Interpretation Introduction

Interpretation:

Major product should be drawn for the given reactions according the reagents mentioned.

Concept introduction:

  • Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
  • Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
  • Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
  • Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
  • Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.

To find: the product in the given reaction.

(b)

Interpretation Introduction

Interpretation:

Major product should be drawn for the given reactions according the reagents mentioned.

Concept introduction:

  • Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
  • Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
  • Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
  • Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
  • Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.

To find: the product in the given reaction.

(c)

Interpretation Introduction

Interpretation:

Major product should be drawn for the given reactions according the reagents mentioned.

Concept introduction:

  • Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
  • Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
  • Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
  • Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
  • Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.

To find: the product in the given reaction.

(d)

Interpretation Introduction

Interpretation:

Major product should be drawn for the given reactions according the reagents mentioned.

Concept introduction:

  • Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
  • Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
  • Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
  • Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
  • Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.

To find: the product in the given reaction.

(e)

Interpretation Introduction

Interpretation:

Major product should be drawn for the given reactions according the reagents mentioned.

Concept introduction:

  • Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
  • Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
  • Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
  • Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
  • Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.

To find: the product in the given reaction.

(f)

Interpretation Introduction

Interpretation:

Major product should be drawn for the given reactions according the reagents mentioned.

Concept introduction:

  • Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
  • Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
  • Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
  • Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
  • Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.

To find: the product in the given reaction.

(g)

Interpretation Introduction

Interpretation:

Major product should be drawn for the given reactions according the reagents mentioned.

Concept introduction:

  • Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
  • Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
  • Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
  • Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
  • Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.

To find: the product in the given reaction.

 (h)

Interpretation Introduction

Interpretation:

Major product should be drawn for the given reactions according the reagents mentioned.

Concept introduction:

  • Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
  • Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
  • Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
  • Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
  • Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.

To find: the product in the given reaction.

(i)

Interpretation Introduction

Interpretation:

Major product should be drawn for the given reactions according the reagents mentioned.

Concept introduction:

  • Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
  • Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
  • Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
  • Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
  • Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.

To find: the product in the given reaction.

Blurred answer
Students have asked these similar questions
Use solubility rules to provide balance molecular equation, total, and net ionic equation
Br HO ? HO ✓ OH
Use the literature Ka value of the acetic acid, and the data below to answer these questions. Note: You will not use the experimental titration graphs to answer the questions that follow.  Group #1:   Buffer pH = 4.35 Group #2: Buffer pH = 4.70 Group #3: Buffer pH = 5.00 Group #4: Buffer pH = 5.30 Use the Henderson-Hasselbalch equation, the buffer pH provided and the literature pKa value of acetic acid to perform the following: a) calculate the ratios of [acetate]/[acetic acid] for each of the 4 groups buffer solutions above. b) using the calculated ratios, which group solution will provide the best optimal buffer (Hint: what [acetate]/[acetic acid] ratio value is expected for an optimal buffer?) c) explain your choice

Chapter 9 Solutions

Organic Chemistry

Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY