
(a)
Interpretation:
Major product should be drawn for the given reactions according the reagents mentioned.
Concept introduction:
- Hydroboration: addition of water molecule across the double bond of
alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product. - Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
- Hydrogenation: addition of hydrogen molecule across the double bond in presence of
transition metal catalyst is known as hydrogenation process. - Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.
To find: the product in the given reaction.
(b)
Interpretation:
Major product should be drawn for the given reactions according the reagents mentioned.
Concept introduction:
- Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
- Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
- Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
- Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.
To find: the product in the given reaction.
(c)
Interpretation:
Major product should be drawn for the given reactions according the reagents mentioned.
Concept introduction:
- Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
- Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
- Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
- Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.
To find: the product in the given reaction.
(d)
Interpretation:
Major product should be drawn for the given reactions according the reagents mentioned.
Concept introduction:
- Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
- Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
- Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
- Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.
To find: the product in the given reaction.
(e)
Interpretation:
Major product should be drawn for the given reactions according the reagents mentioned.
Concept introduction:
- Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
- Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
- Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
- Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.
To find: the product in the given reaction.
(f)
Interpretation:
Major product should be drawn for the given reactions according the reagents mentioned.
Concept introduction:
- Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
- Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
- Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
- Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.
To find: the product in the given reaction.
(g)
Interpretation:
Major product should be drawn for the given reactions according the reagents mentioned.
Concept introduction:
- Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
- Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
- Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
- Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.
To find: the product in the given reaction.
(h)
Interpretation:
Major product should be drawn for the given reactions according the reagents mentioned.
Concept introduction:
- Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
- Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
- Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
- Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.
To find: the product in the given reaction.
(i)
Interpretation:
Major product should be drawn for the given reactions according the reagents mentioned.
Concept introduction:
- Hydroboration: addition of water molecule across the double bond of alkene is known as hydroboration reaction. This reaction gives anti-Markovnikov’s addition product.
- Hydro halogenation: addition of hydrogen and halogen molecules across the double bond of alkene is known as hydro halogenation reaction
- Syn-dihydroxylation: syn- dihydroxylation is a process of adding two –OH groups from the same plane to the alkene.
- Hydrogenation: addition of hydrogen molecule across the double bond in presence of transition metal catalyst is known as hydrogenation process.
- Anti-dihydroxylation: two hydroxyl groups adding across the double bond from both the planes is known as anti-dihydroxylation. This anti-hydroxylation happens when alkene is treated with peroxy acids followed by aqueous acid.
To find: the product in the given reaction.

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Chapter 9 Solutions
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