Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 9.8, Problem 26CC

 (a)

Interpretation Introduction

Interpretation:

Major product should be found for the given alkene while adding bromine and water.

Concept introduction:

  • Addition of bromine molecule in presence of water gives the halohydrin formation.
  • Addition of bromine and hydroxide group across the double bond of alkene is known as halohydrin formation.
  • Addition of bromine molecule to alkene in absence of water molecule gives vicinal halide product with anti-addition.
  • Generally, bromination reactions proceeds through a 3-membered cyclic bromonium intermediate then attack of water molecule at most substituted carbon position of the alkene. 

To find: the major product formed during bromination reaction for the given alkene.

(b)

Interpretation Introduction

Interpretation:

Major product should be found for the given alkene while adding bromine and water.

Concept introduction:

  • Addition of bromine molecule in presence of water gives the halohydrin formation.
  • Addition of bromine and hydroxide group across the double bond of alkene is known as halohydrin formation.
  • Addition of bromine molecule to alkene in absence of water molecule gives vicinal halide product with anti-addition.
  • Generally, bromination reactions proceeds through a 3-membered cyclic bromonium intermediate then attack of water molecule at most substituted carbon position of the alkene. 

To find: the major product formed during bromination reaction for the given alkene.

(c)

Interpretation Introduction

Interpretation:

Major product should be found for the given alkene while adding bromine and water.

Concept introduction:

  • Addition of bromine molecule in presence of water gives the halohydrin formation.
  • Addition of bromine and hydroxide group across the double bond of alkene is known as halohydrin formation.
  • Addition of bromine molecule to alkene in absence of water molecule gives vicinal halide product with anti-addition.
  • Generally, bromination reactions proceeds through a 3-membered cyclic bromonium intermediate then attack of water molecule at most substituted carbon position of the alkene. 

To find: the major product formed during bromination reaction for the given alkene.

(d)

Interpretation Introduction

Interpretation:

Major product should be found for the given alkene while adding bromine and water.

Concept introduction:

  • Addition of bromine molecule in presence of water gives the halohydrin formation.
  • Addition of bromine and hydroxide group across the double bond of alkene is known as halohydrin formation.
  • Addition of bromine molecule to alkene in absence of water molecule gives vicinal halide product with anti-addition.
  • Generally, bromination reactions proceeds through a 3-membered cyclic bromonium intermediate then attack of water molecule at most substituted carbon position of the alkene. 

To find: the major product formed during bromination reaction for the given alkene.

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