Concept explainers
(a)
Interpretation:
The type of isomer represented by the pair
Concept Introduction:
Isomers:
The compounds with same molecular formula but differ in the arrangement of the atom are said to be isomers.
Linkage isomers:
Linkage isomerism occurs with ambidentate ligands that are capable of coordinating in more than one way.
Example:
(a)

Answer to Problem 9C.11E
The type of isomer represented by the pair
Explanation of Solution
In the isomer
(b)
Interpretation:
The type of isomer represented by the pair
Concept Introduction:
Ionization Isomers:
Ionization isomers occur when a ligand is bound to the metal center exchanges places with an anion or neutral molecule that was previously outside the coordination complex.
(b)

Answer to Problem 9C.11E
The type of isomer represented by the pair
Explanation of Solution
In this pair of isomers the hydroxide ion which is bound with central atom is exchanged its place with the sulphate ligand which present outside the nucleus of the complex. Thus these isomers are ionization isomers.
(c)
Interpretation:
The type of isomer represented by the pair
Concept Introduction:
Refer to part (a).
(c)

Answer to Problem 9C.11E
The type of isomer represented by the pair
Explanation of Solution
In the isomer
(d)
Interpretation:
The type of isomer represented by the pair
Concept Introduction:
Refer to part (b).
(d)

Answer to Problem 9C.11E
The type of isomer represented by the pair
Explanation of Solution
In this pair of isomers the chloride ion which is bound with central atom is exchanged its place with the bromide ligand which present outside the nucleus of the complex. Thus these isomers are ionization isomers.
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Chapter 9 Solutions
ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM
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