PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
11th Edition
ISBN: 9780198826910
Author: ATKINS
Publisher: Oxford University Press
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Question
Chapter 9, Problem 9A.5DQ
Interpretation Introduction
Interpretation:
The consequences of resonance have to be predicted.
Concept introduction:
Sometimes, the single structure of molecule is not able to define all physical and chemical properties of a molecule. Therefore, all properties of molecules can be identified by the combination of different structures of the considered molecule. This phenomenon is known as the resonance and structures are known as resonance structures.
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b. Which of the above are the products?
c. Which reactant is the electron donor?
d. Which reactants are the electron acceptors?
e. Which of the products are now reduced?
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
OCH 3
(Choose one)
OH
(Choose one)
Br
(Choose one)
Explanation
Check
NO2
(Choose one)
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Chapter 9 Solutions
PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
Ch. 9 - Prob. 9B.1STCh. 9 - Prob. 9A.1DQCh. 9 - Prob. 9A.2DQCh. 9 - Prob. 9A.3DQCh. 9 - Prob. 9A.4DQCh. 9 - Prob. 9A.5DQCh. 9 - Prob. 9A.1AECh. 9 - Prob. 9A.1BECh. 9 - Prob. 9A.2AECh. 9 - Prob. 9A.2BE
Ch. 9 - Prob. 9A.3AECh. 9 - Prob. 9A.3BECh. 9 - Prob. 9A.4AECh. 9 - Prob. 9A.4BECh. 9 - Prob. 9A.5AECh. 9 - Prob. 9A.5BECh. 9 - Prob. 9A.6AECh. 9 - Prob. 9A.6BECh. 9 - Prob. 9A.7AECh. 9 - Prob. 9A.7BECh. 9 - Prob. 9A.8AECh. 9 - Prob. 9A.8BECh. 9 - Prob. 9A.1PCh. 9 - Prob. 9A.2PCh. 9 - Prob. 9A.3PCh. 9 - Prob. 9B.2DQCh. 9 - Prob. 9B.3DQCh. 9 - Prob. 9B.1AECh. 9 - Prob. 9B.1BECh. 9 - Prob. 9B.2AECh. 9 - Prob. 9B.2BECh. 9 - Prob. 9B.3AECh. 9 - Prob. 9B.3BECh. 9 - Prob. 9B.4AECh. 9 - Prob. 9B.4BECh. 9 - Prob. 9B.1PCh. 9 - Prob. 9B.2PCh. 9 - Prob. 9B.3PCh. 9 - Prob. 9C.1DQCh. 9 - Prob. 9C.2DQCh. 9 - Prob. 9C.3DQCh. 9 - Prob. 9C.4DQCh. 9 - Prob. 9C.1AECh. 9 - Prob. 9C.1BECh. 9 - Prob. 9C.2AECh. 9 - Prob. 9C.2BECh. 9 - Prob. 9C.3AECh. 9 - Prob. 9C.3BECh. 9 - Prob. 9C.4AECh. 9 - Prob. 9C.4BECh. 9 - Prob. 9C.5AECh. 9 - Prob. 9C.5BECh. 9 - Prob. 9C.6AECh. 9 - Prob. 9C.6BECh. 9 - Prob. 9C.2PCh. 9 - Prob. 9C.4PCh. 9 - Prob. 9D.1DQCh. 9 - Prob. 9D.2DQCh. 9 - Prob. 9D.3DQCh. 9 - Prob. 9D.4DQCh. 9 - Prob. 9D.1AECh. 9 - Prob. 9D.1BECh. 9 - Prob. 9D.2AECh. 9 - Prob. 9D.2BECh. 9 - Prob. 9D.3AECh. 9 - Prob. 9D.3BECh. 9 - Prob. 9D.4AECh. 9 - Prob. 9D.4BECh. 9 - Prob. 9D.5AECh. 9 - Prob. 9D.5BECh. 9 - Prob. 9D.6AECh. 9 - Prob. 9D.6BECh. 9 - Prob. 9D.7AECh. 9 - Prob. 9D.7BECh. 9 - Prob. 9D.1PCh. 9 - Prob. 9E.1DQCh. 9 - Prob. 9E.2DQCh. 9 - Prob. 9E.3DQCh. 9 - Prob. 9E.4DQCh. 9 - Prob. 9E.5DQCh. 9 - Prob. 9E.1AECh. 9 - Prob. 9E.1BECh. 9 - Prob. 9E.2AECh. 9 - Prob. 9E.2BECh. 9 - Prob. 9E.3AECh. 9 - Prob. 9E.3BECh. 9 - Prob. 9E.4AECh. 9 - Prob. 9E.4BECh. 9 - Prob. 9E.6AECh. 9 - Prob. 9E.6BECh. 9 - Prob. 9E.1PCh. 9 - Prob. 9E.2PCh. 9 - Prob. 9E.3PCh. 9 - Prob. 9E.6PCh. 9 - Prob. 9.1IACh. 9 - Prob. 9.2IACh. 9 - Prob. 9.4IA
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- For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects O donating O withdrawing O no inductive effects Resonance Effects Overall Electron-Density ○ donating ○ withdrawing O no resonance effects O electron-rich O electron-deficient O similar to benzene Cl O donating O withdrawing ○ donating ○ withdrawing O no inductive effects O no resonance effects O Explanation Check O electron-rich O electron-deficient similar to benzene X © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessarrow_forwardIdentifying electron-donating and For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects NH2 ○ donating NO2 Explanation Check withdrawing no inductive effects Resonance Effects Overall Electron-Density ○ donating O withdrawing O no resonance effects O donating O withdrawing O donating withdrawing O no inductive effects Ono resonance effects O electron-rich electron-deficient O similar to benzene O electron-rich O electron-deficient O similar to benzene olo 18 Ar 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forwardRank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic aromatic substitution. Explanation Check Х (Choose one) OH (Choose one) OCH3 (Choose one) OH (Choose one) © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centerarrow_forward
- Assign R or S to all the chiral centers in each compound drawn below porat bg 9 Br Brarrow_forwarddescrive the energy levels of an atom and howan electron moces between themarrow_forwardRank each set of substituents using the Cahn-Ingold-Perlog sequence rules (priority) by numbering the highest priority substituent 1.arrow_forward
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