Instant cold packs used to treat athletic injuries contain solid NH 4 NO 3 and a pouch of water. When the pack is squeezed, the pouch breaks and the solid dissolves, lowering the temperature because of the endothermic reaction NH 4 NO 3 (s) → H 2 O NH 4 NO 3 (aq) Δ H =+25.7kJ What is the final temperature in a squeezed cold pack that contains 50.0 g of NH 4 NO 3 dissolved in 125 mL of water? Assume a specific heat of 4.18 J/(g• °C) for the solution, an initial temperature of 25.0 °C, and no heat transfer between the cold pack and the environment.
Instant cold packs used to treat athletic injuries contain solid NH 4 NO 3 and a pouch of water. When the pack is squeezed, the pouch breaks and the solid dissolves, lowering the temperature because of the endothermic reaction NH 4 NO 3 (s) → H 2 O NH 4 NO 3 (aq) Δ H =+25.7kJ What is the final temperature in a squeezed cold pack that contains 50.0 g of NH 4 NO 3 dissolved in 125 mL of water? Assume a specific heat of 4.18 J/(g• °C) for the solution, an initial temperature of 25.0 °C, and no heat transfer between the cold pack and the environment.
Instant cold packs used to treat athletic injuries contain solid NH4NO3 and a pouch of water. When the pack is squeezed, the pouch breaks and the solid dissolves, lowering the temperature because of the endothermic reaction
NH
4
NO
3
(s)
→
H
2
O
NH
4
NO
3
(aq)
Δ
H
=+25.7kJ
What is the final temperature in a squeezed cold pack that contains 50.0 g of NH4NO3 dissolved in 125 mL of water? Assume a specific heat of 4.18 J/(g• °C) for the solution, an initial temperature of 25.0 °C, and no heat transfer between the cold pack and the environment.
How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 9 Solutions
Chemistry, Books a la Carte Edition and Modified Mastering Chemistry with Pearson eText & ValuePack Access Card (7th Edition)
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