Chemistry for Today: General Organic and Biochemistry
9th Edition
ISBN: 9781337514576
Author: Seager
Publisher: Cengage
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Textbook Question
Chapter 9, Problem 9.141E
What is the formula of the hydronium ion?
a.
b.
c.
d.
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Q2: Ranking Acidity
a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly
explain the ranking. Use Table 2.2 as reference.
Ha
Нь
HC
H-N
Ha
OHe
b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is
more acidic? Explain. (Hint: use resonance structures to help)
Name the functional groups on atenolol.
H
H-N
atenolol
Ν
H-N
OH Н
Answer d, e, and f
If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1
Chapter 9 Solutions
Chemistry for Today: General Organic and Biochemistry
Ch. 9 - Write the dissociation equations for the following...Ch. 9 - Write the dissociation equations for the following...Ch. 9 - Each of the following produces a basic solution...Ch. 9 - Prob. 9.4ECh. 9 - Identify each Brnsted acid and base in the...Ch. 9 - Prob. 9.6ECh. 9 - Prob. 9.7ECh. 9 - Prob. 9.8ECh. 9 - Prob. 9.9ECh. 9 - Write equations to represent the Brnsted acid...
Ch. 9 - Write a formula for the conjugate base formed when...Ch. 9 - Write a formula for the conjugate base formed when...Ch. 9 - Prob. 9.13ECh. 9 - Prob. 9.14ECh. 9 - The following reactions illustrate Brnsted...Ch. 9 - Prob. 9.16ECh. 9 - Write equations to illustrate the acid-base...Ch. 9 - Prob. 9.18ECh. 9 - Prob. 9.19ECh. 9 - Prob. 9.20ECh. 9 - Prob. 9.21ECh. 9 - Prob. 9.22ECh. 9 - The acid H3C6H5O7 forms the citrate ion, C6H5O73,...Ch. 9 - The acid H2C4H4O4 forms the succinate ion,...Ch. 9 - Prob. 9.25ECh. 9 - Prob. 9.26ECh. 9 - Calculate the molar concentration of OH in water...Ch. 9 - Calculate the molar concentration of OH in water...Ch. 9 - Calculate the molar concentration of H3O+ in water...Ch. 9 - Prob. 9.30ECh. 9 - Classify the solutions represented in Exercises...Ch. 9 - Classify the solutions represented in Exercises...Ch. 9 - Prob. 9.33ECh. 9 - Prob. 9.34ECh. 9 - Determine the pH of water solutions with the...Ch. 9 - Prob. 9.36ECh. 9 - Prob. 9.37ECh. 9 - Determine the pH of water solutions with the...Ch. 9 - Determine the [H+] value for solutions with the...Ch. 9 - Determine the [H+] value for solutions with the...Ch. 9 - Prob. 9.41ECh. 9 - Prob. 9.42ECh. 9 - The pH values listed in Table 9.1 are generally...Ch. 9 - Prob. 9.44ECh. 9 - Prob. 9.45ECh. 9 - Prob. 9.46ECh. 9 - Prob. 9.47ECh. 9 - Using the information in Table 9.4, describe how...Ch. 9 - Write balanced molecular equations to illustrate...Ch. 9 - Write balanced molecular equations to illustrate...Ch. 9 - Prob. 9.51ECh. 9 - Prob. 9.52ECh. 9 - Prob. 9.53ECh. 9 - Prob. 9.54ECh. 9 - Write balanced molecular, total ionic, and net...Ch. 9 - Prob. 9.56ECh. 9 - Prob. 9.57ECh. 9 - Prob. 9.58ECh. 9 - Prob. 9.59ECh. 9 - Prob. 9.60ECh. 9 - Prob. 9.61ECh. 9 - Prob. 9.62ECh. 9 - Prob. 9.63ECh. 9 - Prob. 9.64ECh. 9 - Prob. 9.65ECh. 9 - Prob. 9.66ECh. 9 - Prob. 9.67ECh. 9 - Prob. 9.68ECh. 9 - Prob. 9.69ECh. 9 - Prob. 9.70ECh. 9 - Determine the number of moles of each of the...Ch. 9 - Prob. 9.72ECh. 9 - Prob. 9.73ECh. 9 - Determine the number of equivalents and...Ch. 9 - Determine the number of equivalents and...Ch. 9 - Prob. 9.76ECh. 9 - Prob. 9.77ECh. 9 - Prob. 9.78ECh. 9 - Prob. 9.79ECh. 9 - The Ka values have been determined for four acids...Ch. 9 - Prob. 9.81ECh. 9 - Prob. 9.82ECh. 9 - Prob. 9.83ECh. 9 - Prob. 9.84ECh. 9 - Prob. 9.85ECh. 9 - Prob. 9.86ECh. 9 - Arsenic acid (H3AsO4) is a moderately weak...Ch. 9 - Explain the purpose of doing a titration.Ch. 9 - Prob. 9.89ECh. 9 - Prob. 9.90ECh. 9 - Prob. 9.91ECh. 9 - Prob. 9.92ECh. 9 - Prob. 9.93ECh. 9 - Prob. 9.94ECh. 9 - Prob. 9.95ECh. 9 - Prob. 9.96ECh. 9 - A 25.00-mL sample of gastric juice is titrated...Ch. 9 - A 25.00-mL sample of H2C2O4 solution required...Ch. 9 - Prob. 9.99ECh. 9 - Prob. 9.100ECh. 9 - The following acid solutions were titrated to the...Ch. 9 - The following acid solutions were titrated to the...Ch. 9 - Prob. 9.103ECh. 9 - Prob. 9.104ECh. 9 - Prob. 9.105ECh. 9 - Prob. 9.106ECh. 9 - Prob. 9.107ECh. 9 - Predict the relative pH greater than 7, less than...Ch. 9 - Prob. 9.109ECh. 9 - Explain why the hydrolysis of salts makes it...Ch. 9 - How would the pH values of equal molar solutions...Ch. 9 - Write equations similar to Equations 9.48 and 9.49...Ch. 9 - Prob. 9.113ECh. 9 - Prob. 9.114ECh. 9 - Prob. 9.115ECh. 9 - a.Calculate the pH of a buffer that is 0.1M in...Ch. 9 - Which of the following acids and its conjugate...Ch. 9 - Prob. 9.118ECh. 9 - Prob. 9.119ECh. 9 - What ratio concentrations of NaH2PO4 and Na2HPO4...Ch. 9 - Prob. 9.121ECh. 9 - Prob. 9.122ECh. 9 - Prob. 9.123ECh. 9 - Prob. 9.124ECh. 9 - Prob. 9.125ECh. 9 - Prob. 9.126ECh. 9 - Prob. 9.127ECh. 9 - Prob. 9.128ECh. 9 - Prob. 9.129ECh. 9 - Bottles of ketchup are routinely left on the...Ch. 9 - Prob. 9.131ECh. 9 - Prob. 9.132ECh. 9 - Prob. 9.133ECh. 9 - Prob. 9.134ECh. 9 - Prob. 9.135ECh. 9 - Prob. 9.136ECh. 9 - Prob. 9.137ECh. 9 - A base is a substance that dissociates in water...Ch. 9 - Prob. 9.139ECh. 9 - Prob. 9.140ECh. 9 - What is the formula of the hydronium ion? a.H+...Ch. 9 - Which of the following substances has a pH closest...Ch. 9 - Dissolving H2SO4 in water creates an acid solution...Ch. 9 - Prob. 9.144ECh. 9 - A common detergent has a pH of 11.0, so the...Ch. 9 - Prob. 9.146ECh. 9 - The pH of a blood sample is 7.40 at room...Ch. 9 - Prob. 9.148ECh. 9 - Prob. 9.149ECh. 9 - Prob. 9.150ECh. 9 - Prob. 9.151ECh. 9 - Which of the following compounds would be...Ch. 9 - A substance that functions to prevent rapid,...Ch. 9 - Which one of the following equations represents...Ch. 9 - Which reaction below demonstrates a neutralization...Ch. 9 - In titration of 40.0mL of 0.20MNaOH with 0.4MHCl,...Ch. 9 - When titrating 50mL of 0.2MHCl, what quantity of...
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