Use the average bond dissociation energies in Table 9.3 to calculate approximate reaction enthalpies in kilojoules for the following processes: (a) 2 C H 4 ( g ) → C 2 H 6 ( g ) + H 2 ( g ) (b) C 2 H 6 ( g ) + F 2 ( g ) → C 2 H 5 F ( g ) + H F ( g ) (c) N 2 ( g ) + 3 H 3 ( g ) → 2 N H 3 ( g )
Use the average bond dissociation energies in Table 9.3 to calculate approximate reaction enthalpies in kilojoules for the following processes: (a) 2 C H 4 ( g ) → C 2 H 6 ( g ) + H 2 ( g ) (b) C 2 H 6 ( g ) + F 2 ( g ) → C 2 H 5 F ( g ) + H F ( g ) (c) N 2 ( g ) + 3 H 3 ( g ) → 2 N H 3 ( g )
Solution Summary: The author explains the Gibb's equation of thermodynamic purposed a relation between S,
Use the average bond dissociation energies in Table 9.3 to calculate approximate reaction enthalpies in kilojoules for the following processes: (a)
2
C
H
4
(
g
)
→
C
2
H
6
(
g
)
+
H
2
(
g
)
(b)
C
2
H
6
(
g
)
+
F
2
(
g
)
→
C
2
H
5
F
(
g
)
+
H
F
(
g
)
(c)
N
2
(
g
)
+
3
H
3
(
g
)
→
2
N
H
3
(
g
)
Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.
(30 MARKS) Give the major product(s
) formed including relevant
stereochemistry or the complete
reaction conditions for the following
reactions. More than one step may be
required for each reaction arrow, in
which case the steps must be
numbered 1), 2) etc. (2 marks each
box) h)
i)
h)
OH
i)
HO
H3PO4, heat
2
Br
None
Indicate which option is false(A). Resistivity has a residual component and a thermal component.(B). In some materials resistivity increases with T and in others it decreases.(C). In insulating materials, resistivity is very low.
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Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY