The order for increasing S N 2 reaction of the given alkoxide nucleophile is to be ranked. Concept introduction: Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over S N 2 reactions as the reaction rate for S N 2 decreases for the bulkier nucleophile.

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Chapter 9, Problem 9.11P

Interpretation Introduction

Interpretation:

The order for increasing SN2 reaction of the given alkoxide nucleophile is to be ranked.

Concept introduction:

Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over SN2 reactions as the reaction rate for SN2 decreases for the bulkier nucleophile.

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יווי 10 20 30 40 50 60 70 3.5 3 2.5 2 1.5 1 [ppm] 3.5 3 2.5 2 1.5 1 6 [ppm] 1 1.5 -2.5 3.5

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Answer 2

Question

Chapter 9, Problem 9.11P

Interpretation Introduction

Interpretation:

The order for increasing SN2 reaction of the given alkoxide nucleophile is to be ranked.

Concept introduction:

Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over SN2 reactions as the reaction rate for SN2 decreases for the bulkier nucleophile.

Expert Solution & Answer

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Answer 3

Question

Chapter 9, Problem 9.11P

Interpretation Introduction

Interpretation:

The order for increasing SN2 reaction of the given alkoxide nucleophile is to be ranked.

Concept introduction:

Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over SN2 reactions as the reaction rate for SN2 decreases for the bulkier nucleophile.

Expert Solution & Answer

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Answer 4

Question

Chapter 9, Problem 9.11P

Interpretation Introduction

Interpretation:

The order for increasing SN2 reaction of the given alkoxide nucleophile is to be ranked.

Concept introduction:

Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over SN2 reactions as the reaction rate for SN2 decreases for the bulkier nucleophile.

Expert Solution & Answer

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Answer 5

Chapter 9, Problem 9.11P

Interpretation Introduction

Interpretation:

The order for increasing SN2 reaction of the given alkoxide nucleophile is to be ranked.

Concept introduction:

Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over SN2 reactions as the reaction rate for SN2 decreases for the bulkier nucleophile.

Answer 6

Chapter 9, Problem 9.11P

Interpretation Introduction

Interpretation:

The order for increasing SN2 reaction of the given alkoxide nucleophile is to be ranked.

Concept introduction:

Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over SN2 reactions as the reaction rate for SN2 decreases for the bulkier nucleophile.

Answer 7

Chapter 9, Problem 9.11P

Interpretation Introduction

Interpretation:

The order for increasing SN2 reaction of the given alkoxide nucleophile is to be ranked.

Concept introduction:

Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over SN2 reactions as the reaction rate for SN2 decreases for the bulkier nucleophile.

Answer 8

Expert Solution & Answer

Answer 9

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Answer 10

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Answer 11

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

The order for increasing S N 2 reaction of the given alkoxide nucleophile is to be ranked. Concept introduction: Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over S N 2 reactions as the reaction rate for S N 2 decreases for the bulkier nucleophile.

Solution Summary: The author analyzes how the order of increasing S_ NText2 reaction for the given alkoxide nucleophile is ranked.

Interpretation:

The order for increasing SN2 reaction of the given alkoxide nucleophile is to be ranked.

Concept introduction:

Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over SN2 reactions as the reaction rate for SN2 decreases for the bulkier nucleophile.

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Chapter 9 Solutions

The order for increasing S N 2 reaction of the given alkoxide nucleophile is to be ranked. Concept introduction: Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over S N 2 reactions as the reaction rate for S N 2 decreases for the bulkier nucleophile.

Solution Summary: The author analyzes how the order of increasing S_ NText2 reaction for the given alkoxide nucleophile is ranked.

Interpretation: The order for increasing SN2 reaction of the given alkoxide nucleophile is to be ranked. Concept introduction: Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over SN2 reactions as the reaction rate for SN2 decreases for the bulkier nucleophile.

Want to see the full answer?

Chapter 9 Solutions

Interpretation:

The order for increasing SN2 reaction of the given alkoxide nucleophile is to be ranked.

Concept introduction:

Strong, bulky bases (such as the tert-butoxide anion) tend to favor E2 reactions over SN2 reactions as the reaction rate for SN2 decreases for the bulkier nucleophile.