Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 9, Problem 85E
Which of the following gases diffuse more slowly than oxygen?
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
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Print Last Name, First Name Initial
Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
4th total
• 6H total
래
• 4H total
21 total
ZH
2H
Statistical
H < 3° C-H weakest
-
product
abstraction here
bund
leads to thermo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Product
6
Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
II
HA
H
CH3O-H
H
①
Chapter 9 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 9 - Why are sharp knives more effective than dull...Ch. 9 - Why do some small bridges have weight limits that...Ch. 9 - Why should you roll or belly-crawl rather than...Ch. 9 - A typical barometric pressure in Redding....Ch. 9 - A typical barometric pressure in Denver, Colorado,...Ch. 9 - A typical barometric pressure in Kansas City is...Ch. 9 - Canadian tire pressure gauges are marked in units...Ch. 9 - Dining the Viking landings on Mars, the...Ch. 9 - The pressure of the atmosphere on the surface of...Ch. 9 - A medical laboratory catalog describes the...
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- 8b. Explain, using key intermediates, why the above two products are formed instead of the 1,2-and 1,4- products shown in the reaction below. CIarrow_forward(5pts) Provide the complete arrow pushing mechanism for the chemical transformation depicted below Use proper curved arrow notation that explicitly illustrates all bonds being broken, and all bonds formed in the transformation. Also, be sure to include all lone pairs and formal charges on all atoms involved in the flow of electrons. CH3O H I I CH3O-H H I ① Harrow_forward6. Draw the products) formed from the following reactions. (a) HIarrow_forward
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