Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 9, Problem 33E
How many moles of gaseous boron trifluoride,
Expert Solution & Answer
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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that
both of them
have a molecular ion peak at m/2 =128. However ketone
(A) has a fragment peak at m/2 = 99 and 72
while ketone (B) snowed a
fragment peak at m/2 = 113 and 58.
9) Propose the most plausible structures for both ketones
b) Explain how you arrived at your conclusion by drawing the
Structures of the distinguishing fragments for each ketone,
including their fragmentation mechanisms.
Part V. Draw the structure of compound tecla using the IR spectrum Cobtained from
the compound in KBr pellet) and the mass spectrum as shown below.
The mass spectrum of compound Tesla showed strong mt peak at 71.
TRANSMITTANCE
LOD
Relative Intensity
100
MS-NW-1539
40
20
80
T
44
55
10
15
20
25
30
35
40
45
50
55
60
65
70
75
m/z
D
4000
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500
HAVENUMBERI-11
Chapter 9 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 9 - Why are sharp knives more effective than dull...Ch. 9 - Why do some small bridges have weight limits that...Ch. 9 - Why should you roll or belly-crawl rather than...Ch. 9 - A typical barometric pressure in Redding....Ch. 9 - A typical barometric pressure in Denver, Colorado,...Ch. 9 - A typical barometric pressure in Kansas City is...Ch. 9 - Canadian tire pressure gauges are marked in units...Ch. 9 - Dining the Viking landings on Mars, the...Ch. 9 - The pressure of the atmosphere on the surface of...Ch. 9 - A medical laboratory catalog describes the...
Ch. 9 - Consider this scenario and answer the following...Ch. 9 - Why is it necessary to use a nonvolatile liquid in...Ch. 9 - The pressure of a sample of gas is measured at sea...Ch. 9 - The pressure of a sample of gas is measured with...Ch. 9 - The pressure of a sample of gas is measured at sea...Ch. 9 - The pressure of a sample of gas ¡s measured a sea...Ch. 9 - How would the use of a volatile liquid affect the...Ch. 9 - Sometimes leaving a bicycle in the sun on a hot...Ch. 9 - Explain how the volume of the bubbles exhausted by...Ch. 9 - One way to state Boyle’s law is All other things...Ch. 9 - An alternate way to state Avogadro’s law is A1l...Ch. 9 - How would the graph in Figure 9.12 change if the...Ch. 9 - How would the graph in Figure 9.13 change if the...Ch. 9 - In addition to the data found in Figure 9.13, what...Ch. 9 - Determine the volume of 1 mol of CH4 gas at 150 K...Ch. 9 - Determine the pressure of the gas in the syringe...Ch. 9 - A spray can is used until it is empty except for...Ch. 9 - What is the temperature of an 11.2-L sample of...Ch. 9 - À 2.50-L volume of hydrogen measured at —196 C is...Ch. 9 - A balloon inflated with three breaths of air has a...Ch. 9 - A weather balloon contains 8.80 moles of helium at...Ch. 9 - The volume of an automobile air bag was 66.8 L...Ch. 9 - How many moles of gaseous boron trifluoride, BF3,...Ch. 9 - Iodine, I2, is a solid at room temperature but...Ch. 9 - How many grams of gas are present in each of the...Ch. 9 - A high altitude balloon is filled with 1041104 L...Ch. 9 - A cylinder of medical oxygen has a volume of 3S.4...Ch. 9 - A large scuba tank (Figure 9.16) with a volume of...Ch. 9 - A 20.0-L cylinder containing 11.34 kg of butane,...Ch. 9 - While resting, the average 70-kg human male...Ch. 9 - For a given amount of gas showing ideal behavior,...Ch. 9 - A liter of methane gas, CH4, at STP contains more...Ch. 9 - The effect of chlorofluorocarbons (such as CCl2F2)...Ch. 9 - As 1 g of (lie radioactive element radium decays...Ch. 9 - 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A sample of carbon monoxide was collected over...Ch. 9 - In an experiment in a general chemistry...Ch. 9 - Joseph Priestley first prepared pure oxygen by...Ch. 9 - Cavendish prepared hydrogen in 176G by the novel...Ch. 9 - The chlorofluorocarbon CCl2F2 can be recycled into...Ch. 9 - Automobile air bags are inflated with nitrogen...Ch. 9 - Lime, CaO, is produced by heating calcium...Ch. 9 - Before small batteries were available, carbide...Ch. 9 - Calculate the volume of oxygen required to burn...Ch. 9 - What volume of O2 at STP is required to oxidize...Ch. 9 - Consider the following questions: (a) What is the...Ch. 9 - Methanol, CH3OH, is produced industrially by the...Ch. 9 - What volume of oxygen a 423.0 K and a pressure of...Ch. 9 - A 230-L sample of a colorless gas at STP...Ch. 9 - Ethanol, C2H5OH, is produced industrially from...Ch. 9 - One molecule of hemoglobin will combine with four...Ch. 9 - A sample of a compound of xenon and fluorine was...Ch. 9 - One method of analyzing amino acids is the van...Ch. 9 - A balloon filled with helium gas is found to take...Ch. 9 - Explain why the numbers of molecules are not...Ch. 9 - Starting with the definition of rate of effusion...Ch. 9 - Heavy water, D2O (molar mass = 20.03 g mol-1). can...Ch. 9 - Which of the following gases diffuse more slowly...Ch. 9 - During the discussion of gaseous diffusion for...Ch. 9 - Calculate the relative rate of diffusion of 1H2...Ch. 9 - A gas of unknown identity diffuses at a rate of...Ch. 9 - When two cotton plugs. one moistened with ammonia...Ch. 9 - Using the postulates of the kinetic molecular...Ch. 9 - Can the speed of a given molecule in a gas double...Ch. 9 - Describe what happens o the average kinetic energy...Ch. 9 - The distribution of molecular velocities in a...Ch. 9 - What is the ratio of the average kinetic energy of...Ch. 9 - A 1-L sample of CO initially at STP is heated to...Ch. 9 - The root mean square speed of H2, molecules at 25...Ch. 9 - Answer the following questions: (a) Is the...Ch. 9 - Show that the ratio of the rate of diffusion of...Ch. 9 - Graphs showing the behavior of several different...Ch. 9 - Explain why the plot of PV for CO2 differs from...Ch. 9 - Under which of the following sets of conditions...Ch. 9 - Describe the factors responsible for the deviation...Ch. 9 - For which of the following gases should the...Ch. 9 - A 0.245-L flask contains 0.467 mol CO2 at 159 C....Ch. 9 - Answer the following questions: (a) If XX behaved...
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- Technetium is the first element in the periodic chart that does not have any stable isotopes. Technetium-99m is an especially interesting and valuable isotope as it emits a gamma ray with a half life ideally suited for medical tests. It would seem that the decay of technetium should fit the treatment above with the result In(c/c) = -kt. The table below includes data from the two sites: http://dailymed.nlm.nih.gov/dailymed/druginfo.cfm?id=7130 http://wiki.medpedia.com/Clinical: Neutrospec_(Technetium_(99m Tc)_fanolesomab). a. b. C. Graph the fraction (c/c.) on the vertical axis versus the time on the horizontal axis. Also graph In(c/c.) on the vertical axis versus time on the horizontal axis. When half of the original amount of starting material has hours fraction remaining disappeared, c/c = ½ and the equation In(c/c.) = -kt becomes In(0.5) = -kt1/2 where t₁₂ is the half life (the time for half of the material to decay away). Determine the slope of your In(c/c.) vs t graph and…arrow_forwardPlease correct answer and don't use hand ratingarrow_forward1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)arrow_forward
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