Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 9, Problem 25E
Determine the volume of 1 mol of
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO2 (g) = N2O4(g)
AGº = -5.4 kJ
Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system:
Under these conditions, will the pressure of N2O4 tend to rise or fall?
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
'2'
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
00
rise
☐ x10
fall
yes
no
☐ atm
G
Ar
1
Why do we analyse salt?
Curved arrows are used to illustrate the flow of electrons. Using
the provided starting and product structures, draw the curved
electron-pushing arrows for the following reaction or
mechanistic step(s).
Be sure to account for all bond-breaking and bond-making
steps.
H
H
CH3OH, H+
H
Select to Add Arrows
H°
0:0
'H
+
Q
HH
■ Select to Add Arrows
CH3OH,
H*
H.
H
CH3OH, H+
HH
■ Select to Add Arrows i
Please select a drawing or reagent from the question area
Chapter 9 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 9 - Why are sharp knives more effective than dull...Ch. 9 - Why do some small bridges have weight limits that...Ch. 9 - Why should you roll or belly-crawl rather than...Ch. 9 - A typical barometric pressure in Redding....Ch. 9 - A typical barometric pressure in Denver, Colorado,...Ch. 9 - A typical barometric pressure in Kansas City is...Ch. 9 - Canadian tire pressure gauges are marked in units...Ch. 9 - Dining the Viking landings on Mars, the...Ch. 9 - The pressure of the atmosphere on the surface of...Ch. 9 - A medical laboratory catalog describes the...
Ch. 9 - Consider this scenario and answer the following...Ch. 9 - Why is it necessary to use a nonvolatile liquid in...Ch. 9 - The pressure of a sample of gas is measured at sea...Ch. 9 - The pressure of a sample of gas is measured with...Ch. 9 - The pressure of a sample of gas is measured at sea...Ch. 9 - The pressure of a sample of gas ¡s measured a sea...Ch. 9 - How would the use of a volatile liquid affect the...Ch. 9 - Sometimes leaving a bicycle in the sun on a hot...Ch. 9 - Explain how the volume of the bubbles exhausted by...Ch. 9 - One way to state Boyle’s law is All other things...Ch. 9 - An alternate way to state Avogadro’s law is A1l...Ch. 9 - How would the graph in Figure 9.12 change if the...Ch. 9 - How would the graph in Figure 9.13 change if the...Ch. 9 - In addition to the data found in Figure 9.13, what...Ch. 9 - Determine the volume of 1 mol of CH4 gas at 150 K...Ch. 9 - Determine the pressure of the gas in the syringe...Ch. 9 - A spray can is used until it is empty except for...Ch. 9 - What is the temperature of an 11.2-L sample of...Ch. 9 - À 2.50-L volume of hydrogen measured at —196 C is...Ch. 9 - A balloon inflated with three breaths of air has a...Ch. 9 - A weather balloon contains 8.80 moles of helium at...Ch. 9 - The volume of an automobile air bag was 66.8 L...Ch. 9 - How many moles of gaseous boron trifluoride, BF3,...Ch. 9 - Iodine, I2, is a solid at room temperature but...Ch. 9 - How many grams of gas are present in each of the...Ch. 9 - A high altitude balloon is filled with 1041104 L...Ch. 9 - A cylinder of medical oxygen has a volume of 3S.4...Ch. 9 - A large scuba tank (Figure 9.16) with a volume of...Ch. 9 - A 20.0-L cylinder containing 11.34 kg of butane,...Ch. 9 - While resting, the average 70-kg human male...Ch. 9 - For a given amount of gas showing ideal behavior,...Ch. 9 - A liter of methane gas, CH4, at STP contains more...Ch. 9 - The effect of chlorofluorocarbons (such as CCl2F2)...Ch. 9 - As 1 g of (lie radioactive element radium decays...Ch. 9 - 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A sample of carbon monoxide was collected over...Ch. 9 - In an experiment in a general chemistry...Ch. 9 - Joseph Priestley first prepared pure oxygen by...Ch. 9 - Cavendish prepared hydrogen in 176G by the novel...Ch. 9 - The chlorofluorocarbon CCl2F2 can be recycled into...Ch. 9 - Automobile air bags are inflated with nitrogen...Ch. 9 - Lime, CaO, is produced by heating calcium...Ch. 9 - Before small batteries were available, carbide...Ch. 9 - Calculate the volume of oxygen required to burn...Ch. 9 - What volume of O2 at STP is required to oxidize...Ch. 9 - Consider the following questions: (a) What is the...Ch. 9 - Methanol, CH3OH, is produced industrially by the...Ch. 9 - What volume of oxygen a 423.0 K and a pressure of...Ch. 9 - A 230-L sample of a colorless gas at STP...Ch. 9 - Ethanol, C2H5OH, is produced industrially from...Ch. 9 - One molecule of hemoglobin will combine with four...Ch. 9 - A sample of a compound of xenon and fluorine was...Ch. 9 - One method of analyzing amino acids is the van...Ch. 9 - A balloon filled with helium gas is found to take...Ch. 9 - Explain why the numbers of molecules are not...Ch. 9 - Starting with the definition of rate of effusion...Ch. 9 - Heavy water, D2O (molar mass = 20.03 g mol-1). can...Ch. 9 - Which of the following gases diffuse more slowly...Ch. 9 - During the discussion of gaseous diffusion for...Ch. 9 - Calculate the relative rate of diffusion of 1H2...Ch. 9 - A gas of unknown identity diffuses at a rate of...Ch. 9 - When two cotton plugs. one moistened with ammonia...Ch. 9 - Using the postulates of the kinetic molecular...Ch. 9 - Can the speed of a given molecule in a gas double...Ch. 9 - Describe what happens o the average kinetic energy...Ch. 9 - The distribution of molecular velocities in a...Ch. 9 - What is the ratio of the average kinetic energy of...Ch. 9 - A 1-L sample of CO initially at STP is heated to...Ch. 9 - The root mean square speed of H2, molecules at 25...Ch. 9 - Answer the following questions: (a) Is the...Ch. 9 - Show that the ratio of the rate of diffusion of...Ch. 9 - Graphs showing the behavior of several different...Ch. 9 - Explain why the plot of PV for CO2 differs from...Ch. 9 - Under which of the following sets of conditions...Ch. 9 - Describe the factors responsible for the deviation...Ch. 9 - For which of the following gases should the...Ch. 9 - A 0.245-L flask contains 0.467 mol CO2 at 159 C....Ch. 9 - Answer the following questions: (a) If XX behaved...
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