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a)
Interpretation:
The difference in the boiling points of the given set of compounds has to be rationalized.
Concept Introduction:
- Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.
- Intramolecular force refers to type of bonding between the atoms.
- Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.
- If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.
- They are collectively known as “Interparticle forces”. The classification can be summarized as follows –
Figure 1
Figure 2
Figure 3
The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.
Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.
London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.
Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.
b)
Interpretation:
The difference in the boiling points of the given set of compounds has to be rationalized.
Concept Introduction:
- Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.
- Intramolecular force refers to type of bonding between the atoms.
- Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.
- If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.
- They are collectively known as “Interparticle forces”. The classification can be summarized as follows –
Figure 1
Figure 2
Figure 3
The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.
Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.
London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.
Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.
c)
Interpretation:
The difference in the boiling points of the given set of compounds has to be rationalized.
Concept Introduction:
- Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.
- Intramolecular force refers to type of bonding between the atoms.
- Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.
- If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.
- They are collectively known as “Interparticle forces”. The classification can be summarized as follows –
Figure 1
Figure 2
Figure 3
The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.
Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.
London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.
Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.
d)
Interpretation:
The difference in the boiling points of the given set of compounds has to be rationalized.
Concept Introduction:
- Boiling point of any compound, depends upon its strength of Intramolecular force and Intermolecular force present in it.
- Intramolecular force refers to type of bonding between the atoms.
- Intermolecular forces are the forces that bind the molecules together to attribute to a stability of a compound.
- If the strength of intermolecular forces is high, boiling point will be high and if it is low, boiling point will be low.
- They are collectively known as “Interparticle forces”. The classification can be summarized as follows –
Figure 1
Figure 2
Figure 3
The type of bonding between atoms or ions is Intramolecular force. The intramolecular force in ionic compounds is electrostatic force of attraction between the ions of opposite charges. Usually ionic compounds are solids with high melting points. Covalent bonds are of two types, that is polar covalent bond and non-polar covalent bond. Covalent compounds are found as solids and liquids with moderate melting and boiling point. Metallic bond is formed between the metal atoms of an element.
Intermolecular forces are Van der Waals forces. They are weak and are of three types - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule. It is relatively the strongest one. Hydrogen bonded compounds are usually liquids. They exhibit high boiling point.
London dispersion forces exist in all types of molecules. This is the force responsible for the condensation of non-polar compounds into liquids or solids under low temperature.
Dipole-dipole forces exist in polar covalent compounds. Hydrogen bonding exists in polar covalent compounds containing Fluorine, Oxygen or Nitrogen directly bonded to Hydrogen.
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Chapter 9 Solutions
EBK CHEMISTRY: AN ATOMS FIRST APPROACH
- Given the major organic product(s) of each of the following reactions. If none is predicted, write "N.R." [answer 61 a. b. H3C C. NO₂ CH3CH2CH2Cl AICI 3 1) NaOH CI 2) H3O+ NO₂ 1. SnCl2, H3O+ 2. NaOH 3arrow_forwardPlease correct answer and don't used hand raitingarrow_forwardTo answer the following questions, consider the reaction below: CH3 . CH3 OH a. The best reagents for accomplishing the above transformation are.... a. 1. OsO4, pyridine 2. NaHSO3, H₂O b. 1. Hg(OAc)2, H₂O 1. C. 2. NaBH4 RCO₂H, CH2Cl₂ 2. H₂O* d. 1. BH3, THF 2. H₂O₂, OH b. The alcohol product is classified as a: a. 1° alcohol b. 2° alcohol C. 3° alcohol d. 4° alcohol c. The conversion of an alcohol into an alkyl chloride by reaction with SOCI2 is an example of: a. b. ن نخنه C. d. an El process an Syl process an E2 process an Sy2 processarrow_forward
- Estimation of ash in food Questions: Q1: What does the word ash refer to? Q2: Mention the types of ash in food Q3: Mention the benefit of using a glass dryerarrow_forwardDraw structures corresponding to the names given a. m-fluoronitrobenzene b. p-bromoaniline c. o-chlorophenol d. 3,5-dimethylbenzoic acidarrow_forwardIllustrate the reaction mechanism the following reactionarrow_forward
- Propose a synthesis for the following compound using benzene or toluene and any other reagents necessary. Show all major intermediate compounds that would probably be isolated during the course of your synthesis. on. Harrow_forwardProvide correct IUPAC names for each of the following compounds. NOT a. b. C. 2003 H,N- CH3 NH2 CHarrow_forward. Consider the reaction below to answer the following questions. OH 1. NaH 2. CH3I, ether O-CH3 A. Write the complete stepwise mechanism for the reaction. Show all intermediate structures and all electron flow with arrows. B. Mechanistically, the Williamson ether synthesis outlined above is: ن نخنه a. an El process b. an SN1 process C. an E2 process d. an SN2 process C. Alternatively, cyclopentyl methyl ether may be synthesized from cyclopentene. synthesis of cyclopentyl methyl ether from cyclopentene. Outline aarrow_forward
- Q2. A good synthesis of (CH3)3C- would be: A) B) CSI3 0 CH3CC1 (CH3) 3CC1 Benzene AlCl3 AlCl3 (CH3)3CC1 CH3CC1 Benzene C) AlCl3 0 AlCl3 CH3CC1 (CH3) 2C-CH2 Bonzone AlCl3 HF D) More than one of these E) None of thesearrow_forwardDon't used hand raiting and correct answer and don't used Ai solutionarrow_forwardShow how you might carry out the following transformation or reactions: toluene to m-chlorobenzoic acidarrow_forward
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