
Concept explainers
(a)
Interpretation:
The reactant which is limiting needs to be determined and the mass of NaNH2 which is expected needs to be determined.
Concept Introduction:
Calculate mol using the following expression:
(a)

Answer to Problem 37A
The limiting reagent is Na
mass NaNH2= 84.63 g
Explanation of Solution
Given data:
mass NH3= 50 .0 g
mass Na = 50.0 g
Now, calculate mol using the following expression:
Molar Mass NH3 = 17 g/mol
mol NH3 = 2.94 mol
Molar Mass Na = 23.0 g/mol
mol Na = 2.17 mol
Now, calculate limiting reagent for this it is assumed that all the Na is completely consumed the NH3 mol necessary for all the Na to react completely
mol Na = 2.17 mol
note that the NH3 moles needed for all Na to react completely is less than the amount initially available so Na is the limiting reagent and NH3 is the excess reagent
Now by stoichiometry we calculate mol NaNH2
mol NaNH2= 2.17 mol
Now we calculate mass NaNH2 using the following expression :
(b)
Interpretation:
The reactant which is limiting needs to be determined and the mass of BaSO4which is expected needs to be determined.
Concept Introduction:
Calculate mol using the following expression
Molar Mass BaCl2= 208.2 g/mol
(b)

Answer to Problem 37A
The limiting reagent is BaCl2
mass BaSO4= 56.01 g
Explanation of Solution
mass BaCl2 = 50.0 g
mass NaSO4 = 50.0 g
We calculate mol using the following expression
Molar Mass BaCl2= 208.2 g/mol
mol BaCl2= 0.240 mol
Molar Mass Na2SO4= 142.06 g/mol
mol Na2SO4= 0.352 mol
Now, calculate limiting reagent for this it is assumed that all the BaCl2 is completely consumed, for the Na2SO4 mol necessary for all the Na to react completely
mol Na2SO4= 0.240 mol
note that the Na2SO4 moles needed for all BaCl2 to react completely is less than the amount initially available so BaCl2 is the limiting reagent and Na2SO4 is the excess reagent
Now by stoichiometry we calculate mol BaSO4
mol BaSO4= 0.240 mol
Now, calculate mass BaSO4
(c)
Interpretation:
The reactant which is limiting needs to be determined and the mass of Na2SO3which is expected needs to be determined.
SO2(g) + 2 NaOH(aq) → Na2SO3(s) + H2O(l)
Concept Introduction:
Calculate mol using the following expression
Molar Mass SO2 = 64.06 g/mol
(c)

Answer to Problem 37A
The limiting reagent is NaOH
Mass Na2SO3= 78.8 g
Explanation of Solution
mass SO2 = 50.0 g
mass NaOH = 50.0 g
Calculate mol using the following expression
Molar Mass SO2 = 64.06 g/mol
mol SO2= 0.781 mol
Molar Mass NaOH = 50.0 g/mol
mol NaOH = 1.25 mol
SO2(g) + 2 NaOH(aq) → Na2SO3(s) + H2O(l)
Calculate limiting reagent for this it is assumed that all the NaOH is completely consumed for the SO2 mol necessary for all the NaOH to react completely
Calculate
mol SO2= 0.625 mol
note that the SO2 moles needed for all NaOH to react completely is less than the amount initially available.sSo, NaOH is the limiting reagent and SO2 is the excess reagent
by stoichiometry we calculate mol Na2SO3 from limiting reagent
mol Na2SO3= 0.625 mol
Molar mass Na2SO3= 126.06 g/mol
(d)
Interpretation:
The limiting reagent needs to be determined. Also, the mass of Al2(SO4)3needs to be determined.
Concept Introduction:
The number of moles can be calculated using the following expression
(d)

Answer to Problem 37A
limiting reagent is H2SO4
mass Al2(SO4)3 = 58.17 g
Explanation of Solution
mass Al = 50.0 g/mol
mass H2SO4 = 50.0 g/mol
First, calculate mol using the following expression
mol Al = 1.85 mol
Molar H2SO4 = 98 g/mol
mol H2SO4 = 0.510 mol
calculate limiting reagent for this it is assumed that all the H2SO4 is completely consumed for the mol of Al necessary for all the H2SO4 to react completely
mol Al = 0.340 mol
note that the Al moles needed for all H2SO4 to react completely is less than the amount initially available so H2SO4 is the limiting reagent and Al is the excess reagent
Now from limiting reagent we calculate mol Al2(SO4)3
mol Al2(SO4)3 = 0.170 mol
now we calculate mass Al2(SO4)3 using the following expression
Chapter 9 Solutions
World of Chemistry, 3rd edition
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