The name of the given alcohol has to be given. Concept introduction: Nomenclature of alcohols: The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon. The longest chain containing the functional group will be the parent chain. While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number. The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent. There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

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Answer 1

Question

Chapter 9, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

(b)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

(c)

Interpretation Introduction

Interpretation:

The name of the given ether has to be given.

Concept introduction:

IUPAC naming of Ether compounds:

An Ether group consists of oxygen atom attached between two carbon chains. The shorter of two chains becomes the first part of the name with ‘ane’ changes to ‘oxy’ and the longer alkane becomes the suffix of the name of the ether.

When the Oxygen is not attached to the end of main chain of alkane, then the shorter alkyl group and the Ether group is treated as side chain and prefixed with its binding position on the main chain.

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1,4-Dimethyl-1,3-cyclohexadiene can undergo 1,2- or 1,4-addition with hydrogen halides. (a) 1,2-Addition i. Draw the carbocation intermediate(s) formed during the 1,2-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,2-addition product formed during the reaction in (i)? (b) 1,4-Addition i. Draw the carbocation intermediate(s) formed during the 1,4-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,4-addition product formed from the reaction in (i)? (c) What is the kinetic product from the reaction of one mole of hydrobromic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (d) What is the thermodynamic product from the reaction of one mole of hydrobro-mic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (e) What major product will result when 1,4-dimethyl-1,3-cyclohexadiene is treated with one mole of hydrobromic acid at - 78 deg * C ? Explain your reasoning.

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Five isomeric alkenes. A through each undergo catalytic hydrogenation to give 2-methylpentane The IR spectra of these five alkenes have the key absorptions (in cm Compound Compound A –912. (§), 994 (5), 1643 (%), 3077 (1) Compound B 833 (3), 1667 (W), 3050 (weak shoulder on C-Habsorption) Compound C Compound D) –714 (5), 1665 (w), 3010 (m) 885 (3), 1650 (m), 3086 (m) 967 (5), no aharption 1600 to 1700, 3040 (m) Compound K Match each compound to the data presented. Compound A Compound B Compound C Compound D Compound

Answer 2

Question

Chapter 9, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

(b)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

(c)

Interpretation Introduction

Interpretation:

The name of the given ether has to be given.

Concept introduction:

IUPAC naming of Ether compounds:

An Ether group consists of oxygen atom attached between two carbon chains. The shorter of two chains becomes the first part of the name with ‘ane’ changes to ‘oxy’ and the longer alkane becomes the suffix of the name of the ether.

When the Oxygen is not attached to the end of main chain of alkane, then the shorter alkyl group and the Ether group is treated as side chain and prefixed with its binding position on the main chain.

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Answer 3

Question

Chapter 9, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

(b)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

(c)

Interpretation Introduction

Interpretation:

The name of the given ether has to be given.

Concept introduction:

IUPAC naming of Ether compounds:

An Ether group consists of oxygen atom attached between two carbon chains. The shorter of two chains becomes the first part of the name with ‘ane’ changes to ‘oxy’ and the longer alkane becomes the suffix of the name of the ether.

When the Oxygen is not attached to the end of main chain of alkane, then the shorter alkyl group and the Ether group is treated as side chain and prefixed with its binding position on the main chain.

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Answer 4

Question

Chapter 9, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

(b)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

(c)

Interpretation Introduction

Interpretation:

The name of the given ether has to be given.

Concept introduction:

IUPAC naming of Ether compounds:

An Ether group consists of oxygen atom attached between two carbon chains. The shorter of two chains becomes the first part of the name with ‘ane’ changes to ‘oxy’ and the longer alkane becomes the suffix of the name of the ether.

When the Oxygen is not attached to the end of main chain of alkane, then the shorter alkyl group and the Ether group is treated as side chain and prefixed with its binding position on the main chain.

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Answer 5

Chapter 9, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

(b)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

(c)

Interpretation Introduction

Interpretation:

The name of the given ether has to be given.

Concept introduction:

IUPAC naming of Ether compounds:

An Ether group consists of oxygen atom attached between two carbon chains. The shorter of two chains becomes the first part of the name with ‘ane’ changes to ‘oxy’ and the longer alkane becomes the suffix of the name of the ether.

When the Oxygen is not attached to the end of main chain of alkane, then the shorter alkyl group and the Ether group is treated as side chain and prefixed with its binding position on the main chain.

Answer 6

Chapter 9, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

Answer 7

Chapter 9, Problem 36P

(a)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The name of the given alcohol has to be given.

Concept introduction:

Nomenclature of alcohols:

The suffix used to denote the -OH group will be “ol” and this has to be replaced with “e” at the end of the name of the parent hydrocarbon.

The longest chain containing the functional group will be the parent chain.

While numbering the parent chain, care must be taken to number in a direction that gives the functional group suffix the lowest possible number.

The functional group suffix has to get the lowest possible number in the presence of a functional group suffix and a substituent.

There is no need to designate the position of a functional group suffix in a cyclic compound since it is assumed to be at the first position.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The name of the given ether has to be given.

Concept introduction:

IUPAC naming of Ether compounds:

An Ether group consists of oxygen atom attached between two carbon chains. The shorter of two chains becomes the first part of the name with ‘ane’ changes to ‘oxy’ and the longer alkane becomes the suffix of the name of the ether.

When the Oxygen is not attached to the end of main chain of alkane, then the shorter alkyl group and the Ether group is treated as side chain and prefixed with its binding position on the main chain.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The name of the given ether has to be given.

Concept introduction:

IUPAC naming of Ether compounds:

An Ether group consists of oxygen atom attached between two carbon chains. The shorter of two chains becomes the first part of the name with ‘ane’ changes to ‘oxy’ and the longer alkane becomes the suffix of the name of the ether.

When the Oxygen is not attached to the end of main chain of alkane, then the shorter alkyl group and the Ether group is treated as side chain and prefixed with its binding position on the main chain.

Answer 12

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Answer 13

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Answer 15

Ch. 9.1 - Draw the structures of straight-chain alcohols...Ch. 9.1 - Prob. 2P Ch. 9.1 - Prob. 3P Ch. 9.2 - Why are NH3 and CH3NH2 no longer nucleophiles when...Ch. 9.2 - Prob. 5P Ch. 9.2 - The observed relative reactivities of primary,...Ch. 9.4 - Which of the following alcohols would dehydrate...Ch. 9.4 - Prob. 10P Ch. 9.4 - Prob. 11P Ch. 9.4 - Prob. 12P

Solution Summary: The author explains the structure of the compound, which is an alcohol with nine carbons in the parent chain.

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