Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction. Concept introduction: Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2. E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration. r ∝ [substrate] E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration. r ∝ [substrate] [ base ] Elimination of compound in presence of bulky base leads to less substituted alkene , in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 1

Question

Chapter 8.9, Problem 26CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 2

Question

Chapter 8.9, Problem 26CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Expert Solution & Answer

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Answer 3

Question

Chapter 8.9, Problem 26CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 4

Question

Chapter 8.9, Problem 26CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 5

Chapter 8.9, Problem 26CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 6

Chapter 8.9, Problem 26CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 7

Chapter 8.9, Problem 26CC

(a)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Rate of the reaction should be predicted at different concentrations of substrate and reagent for a second order reaction.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Rate of the reaction depends only on substrate concentration.
r∝[substrate]

E2 reaction: elimination follows concerted pathway of mechanism. Rate of the reaction depends on both substrates as well as reagent concentration.
r∝[substrate][base]

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 8.3 - Prob. 1LTS Ch. 8.3 - Prob. 1PTS Ch. 8.3 - Prob. 2ATS Ch. 8.3 - Prob. 3ATS Ch. 8.3 - Prob. 4CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 5PTS Ch. 8.4 - Prob. 6ATS Ch. 8.5 - Prob. 3LTS Ch. 8.5 - Prob. 7PTS

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Chapter 8 Solutions