Mechanism should be drawn for the given elimination reactions. Concept introduction: Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another. Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc. Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene , in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 1

Question

Chapter 8.6, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai

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Answer 2

Question

Chapter 8.6, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 3

Question

Chapter 8.6, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 8.6, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 8.6, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

(c)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 6

Chapter 8.6, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 7

Chapter 8.6, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given elimination reactions.

Concept introduction:

Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.

Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 12

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Answer 13

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Answer 15

Ch. 8.3 - Prob. 1LTS Ch. 8.3 - Prob. 1PTS Ch. 8.3 - Prob. 2ATS Ch. 8.3 - Prob. 3ATS Ch. 8.3 - Prob. 4CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 5PTS Ch. 8.4 - Prob. 6ATS Ch. 8.5 - Prob. 3LTS Ch. 8.5 - Prob. 7PTS

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