Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
Book Icon
Chapter 8, Problem 79IP

(a)

Interpretation Introduction

Interpretation:

Major products should be drawn for the given elimination reactions.

Concept introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

 (b)

Interpretation Introduction

Interpretation:

Major products should be drawn for the given elimination reactions.

Concept introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

(c)

Interpretation Introduction

Interpretation:

Major products should be drawn for the given elimination reactions.

Concept introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

(d)

Interpretation Introduction

Interpretation:

Major products should be drawn for the given elimination reactions.

Concept introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

 (e)

Interpretation Introduction

Interpretation:

Major products should be drawn for the given elimination reactions.

Concept introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

(f)

Interpretation Introduction

Interpretation:

Major products should be drawn for the given elimination reactions.

Concept introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

(g)

Interpretation Introduction

Interpretation:

Major products should be drawn for the given elimination reactions.

Concept introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

(h)

Interpretation Introduction

Interpretation:

Major products should be drawn for the given elimination reactions.

Concept introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

 (i)

Interpretation Introduction

Interpretation:

Major products should be drawn for the given elimination reactions.

Concept introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

(j)

Interpretation Introduction

Interpretation:

Major products should be drawn for the given elimination reactions.

Concept introduction:

  • Highly polarizable reagents are considered as strong nucleophiles if the conjugate acid of the nucleophile has little nature then those nucleophiles considered as weak bases too. If the reagent is not polarizable and has basic nature, then the reagent is considered as strong base.
  • Reaction mechanism path is depending on both natures of substrate and reagent.
  • If the reagent is strong base as well as strong nucleophile and the substrate is primary alkyl halide then the reaction follows SN2 mechanism if the substrate is secondary alkyl halide then the reaction follows E2 mechanism. For SN2 mechanism reagent should be strong nucleophile.
  • If the substrate is tertiary alkyl halide, then the reaction follows SN1 mechanism rather than SN2 mechanism. (when the reagent is strong nucleophile)
  • If the reagent is strong bulky base, then the reaction follows E2 mechanism. For E2 reaction, reagent should be strong base.

Blurred answer
Students have asked these similar questions
Complete the following esterification reaction by drawing the structural formula of the product formed. HOH HO i catalyst catalyst OH HO (product has rum flavor) (product has orange flavor)
The statements in the tables below are about two different chemical equilibria. The symbols have their usual meaning, for example AG stands for the standard Gibbs free energy of reaction and K stands for the equilibrium constant. In each table, there may be one statement that is faise because it contradicts the other three statements. If you find a false statement, check the box next to t Otherwise, check the "no false statements" box under the table. statement false? AG"1 no false statements: statement false? AG-0 0 InK-0 0 K-1 0 AH-TAS no false statements 2
Complete the following esterification reactions by drawing the line formulas of the carboxylic acid and alcohol required to form the ester shown. catalyst catalyst catalyst apricot fragrance

Chapter 8 Solutions

Organic Chemistry

Ch. 8.5 - Prob. 8PTSCh. 8.6 - Prob. 4LTSCh. 8.6 - Prob. 9PTSCh. 8.6 - Prob. 10PTSCh. 8.6 - Prob. 11ATSCh. 8.6 - Prob. 12ATSCh. 8.7 - Prob. 13CCCh. 8.7 - Prob. 14CCCh. 8.7 - Prob. 5LTSCh. 8.7 - Prob. 15PTSCh. 8.7 - Prob. 16ATSCh. 8.7 - Prob. 17ATSCh. 8.7 - Prob. 6LTSCh. 8.7 - Prob. 18PTSCh. 8.7 - Prob. 19ATSCh. 8.7 - Prob. 20CCCh. 8.7 - Prob. 21CCCh. 8.8 - Prob. 7LTSCh. 8.8 - Prob. 22PTSCh. 8.8 - Prob. 23ATSCh. 8.8 - Prob. 24ATSCh. 8.8 - Prob. 25ATSCh. 8.9 - Prob. 26CCCh. 8.9 - Prob. 27CCCh. 8.9 - Prob. 28CCCh. 8.9 - Prob. 8LTSCh. 8.9 - Prob. 29PTSCh. 8.9 - Prob. 31CCCh. 8.10 - Prob. 32CCCh. 8.10 - Prob. 33CCCh. 8.10 - Prob. 9LTSCh. 8.10 - Prob. 34PTSCh. 8.10 - Prob. 35ATSCh. 8.10 - Prob. 36ATSCh. 8.11 - Prob. 37CCCh. 8.11 - Prob. 38CCCh. 8.12 - Prob. 10LTSCh. 8.13 - Prob. 11LTSCh. 8.14 - Prob. 12LTSCh. 8.14 - Prob. 46PTSCh. 8.14 - Prob. 48ATSCh. 8.14 - Prob. 49ATSCh. 8 - Prob. 50PPCh. 8 - Prob. 51PPCh. 8 - Prob. 52PPCh. 8 - Prob. 53PPCh. 8 - Prob. 54PPCh. 8 - Prob. 55PPCh. 8 - Prob. 56PPCh. 8 - Prob. 57PPCh. 8 - Prob. 58PPCh. 8 - Prob. 59PPCh. 8 - Prob. 60PPCh. 8 - Prob. 61PPCh. 8 - Prob. 62PPCh. 8 - Prob. 63PPCh. 8 - Prob. 64PPCh. 8 - Prob. 65PPCh. 8 - Prob. 66PPCh. 8 - Prob. 67PPCh. 8 - Prob. 68PPCh. 8 - Prob. 69PPCh. 8 - Prob. 70PPCh. 8 - Prob. 71PPCh. 8 - Prob. 72PPCh. 8 - Prob. 73PPCh. 8 - Prob. 74PPCh. 8 - Prob. 75PPCh. 8 - Prob. 76PPCh. 8 - Prob. 77IPCh. 8 - Prob. 78IPCh. 8 - Prob. 79IPCh. 8 - Prob. 80IPCh. 8 - Prob. 81IPCh. 8 - Prob. 82IPCh. 8 - Prob. 83IPCh. 8 - Prob. 84IPCh. 8 - Prob. 85IPCh. 8 - Prob. 86IPCh. 8 - Prob. 87IP
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY