Stereo isomer of 1,2,3,4,5,6-hexachlorocyclohexane should be drawn which cannot participate in E2 elimination process. Concept introduction: Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2. E1 reaction: elimination follows stepwise mechanism. Carbocation is intermediate in this process. E2 reaction: elimination follows concerted pathway of mechanism. Elimination occurs when two leaving groups are anti to each other. Elimination of compound in presence of bulky base leads to less substituted alkene , in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 1

Question

Chapter 8, Problem 85IP

Interpretation Introduction

Interpretation:

Stereo isomer of 1,2,3,4,5,6-hexachlorocyclohexane should be drawn which cannot participate in E2 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Carbocation is intermediate in this process.

E2 reaction: elimination follows concerted pathway of mechanism. Elimination occurs when two leaving groups are anti to each other.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 2

Question

Chapter 8, Problem 85IP

Interpretation Introduction

Interpretation:

Stereo isomer of 1,2,3,4,5,6-hexachlorocyclohexane should be drawn which cannot participate in E2 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Carbocation is intermediate in this process.

E2 reaction: elimination follows concerted pathway of mechanism. Elimination occurs when two leaving groups are anti to each other.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 3

Question

Chapter 8, Problem 85IP

Interpretation Introduction

Interpretation:

Stereo isomer of 1,2,3,4,5,6-hexachlorocyclohexane should be drawn which cannot participate in E2 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Carbocation is intermediate in this process.

E2 reaction: elimination follows concerted pathway of mechanism. Elimination occurs when two leaving groups are anti to each other.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 4

Question

Chapter 8, Problem 85IP

Interpretation Introduction

Interpretation:

Stereo isomer of 1,2,3,4,5,6-hexachlorocyclohexane should be drawn which cannot participate in E2 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Carbocation is intermediate in this process.

E2 reaction: elimination follows concerted pathway of mechanism. Elimination occurs when two leaving groups are anti to each other.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

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Answer 5

Chapter 8, Problem 85IP

Interpretation Introduction

Interpretation:

Stereo isomer of 1,2,3,4,5,6-hexachlorocyclohexane should be drawn which cannot participate in E2 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Carbocation is intermediate in this process.

E2 reaction: elimination follows concerted pathway of mechanism. Elimination occurs when two leaving groups are anti to each other.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 6

Chapter 8, Problem 85IP

Interpretation Introduction

Interpretation:

Stereo isomer of 1,2,3,4,5,6-hexachlorocyclohexane should be drawn which cannot participate in E2 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Carbocation is intermediate in this process.

E2 reaction: elimination follows concerted pathway of mechanism. Elimination occurs when two leaving groups are anti to each other.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 7

Chapter 8, Problem 85IP

Interpretation Introduction

Interpretation:

Stereo isomer of 1,2,3,4,5,6-hexachlorocyclohexane should be drawn which cannot participate in E2 elimination process.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination reactions are two types, E1 and E2.

E1 reaction: elimination follows stepwise mechanism. Carbocation is intermediate in this process.

E2 reaction: elimination follows concerted pathway of mechanism. Elimination occurs when two leaving groups are anti to each other.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 8.3 - Prob. 1LTS Ch. 8.3 - Prob. 1PTS Ch. 8.3 - Prob. 2ATS Ch. 8.3 - Prob. 3ATS Ch. 8.3 - Prob. 4CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 5PTS Ch. 8.4 - Prob. 6ATS Ch. 8.5 - Prob. 3LTS Ch. 8.5 - Prob. 7PTS

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Chapter 8 Solutions