Chapter 8, Problem 8.9P

Interpretation Introduction

Interpretation:

If the first step of an $\text{E1}$ reaction were much faster than the second step, it is to be determined whether the resulting theoretical rate law for the overall reaction would agree or disagree with the observed dependence of the $\text{E1}$ reaction on the base concentration.

Concept introduction:

The $\text{E1}$ reaction is the unimolecular elimination reaction whose rate determining step involves only one reactant. The rate determining step in the E1 reaction is the formation of a carbocation by removing the leaving group. The rate law involves only the substrate and not the base.