Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
2nd Edition
ISBN: 9780393655551
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Chapter 8, Problem 8.8YT
Interpretation Introduction
Interpretation:
How would the reaction rate be affected if the concentration of
Concept introduction:
The rate of an
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K
Problem 22 of 24
Submit
Draw the missing organic structures
in the following multistep synthesis
at physiological pH (pH = 7.4). Ignore
any inorganic byproducts formed.
0
0
ΝΘ
BrCH(CO2CH2CH3)2
Select to Draw
1. NaOCH2CH3 2.
(CH3)2CHCI
Devise electrochemical cells in which the following reactions could be made to occur. If liquid
junctions are necessary, note them in the cell schematic appropriately, but neglect their effects.
(a) H2OH + OH¯
(b) 2H2O2
H₂O
(c) 2PbSO4 + 2H2O
(d) An
TMPD
PыO₂+ Pb + 4H+ + 20%¯¯
An + TMPD (in acetonitrile, where An and An are anthracene and its
anion radical, and TMPD and TMPD are N,N,N',N'-tetramethyl-p-phenylenediamine and its
cation radical. Use anthracene potentials for DMF solutions given in Appendix C.3).
(e) 2Ce3+ + 2H + BQ 2Ce4+ + H2Q (aqueous, where BQ is p-benzoquinone and H₂Q is p-
hydroquinone)
(f) Ag +Agl (aqueous)
(g) Fe3+ + Fe(CN)6 Fe²+ + Fe(CN) (aqueous)
Consider each of the following electrode-solution interfaces, and write the equation for the elec-
trode reaction that occurs first when the potential is moved in (1) a negative direction and (2) a posi-
tive direction from the open-circuit potential. Next to each reaction write the approximate potential
for the reaction in V vs. SCE (assuming the reaction is reversible).
(a) Pt/Cu2+ (0.01 M), Cd2+ (0.01 M), H2SO4(1 M)
(b) Pt/Sn2+ (0.01 M), Sn4+ (0.01 M), HCl(1 M)
(c) Hg/Cd2+ (0.01 M), Zn2+ (0.01 M), HCl(1 M)
Chapter 8 Solutions
Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
Ch. 8 - Prob. 8.1PCh. 8 - Prob. 8.2PCh. 8 - Prob. 8.3PCh. 8 - Prob. 8.4PCh. 8 - Prob. 8.5PCh. 8 - Prob. 8.6PCh. 8 - Prob. 8.7PCh. 8 - Prob. 8.8PCh. 8 - Prob. 8.9PCh. 8 - Prob. 8.10P
Ch. 8 - Prob. 8.11PCh. 8 - Prob. 8.12PCh. 8 - Prob. 8.13PCh. 8 - Prob. 8.14PCh. 8 - Prob. 8.15PCh. 8 - Prob. 8.16PCh. 8 - Prob. 8.17PCh. 8 - Prob. 8.18PCh. 8 - Prob. 8.19PCh. 8 - Prob. 8.20PCh. 8 - Prob. 8.21PCh. 8 - Prob. 8.22PCh. 8 - Prob. 8.23PCh. 8 - Prob. 8.24PCh. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - Prob. 8.27PCh. 8 - Prob. 8.28PCh. 8 - Prob. 8.29PCh. 8 - Prob. 8.30PCh. 8 - Prob. 8.31PCh. 8 - Prob. 8.32PCh. 8 - Prob. 8.33PCh. 8 - Prob. 8.34PCh. 8 - Prob. 8.35PCh. 8 - Prob. 8.36PCh. 8 - Prob. 8.37PCh. 8 - Prob. 8.38PCh. 8 - Prob. 8.39PCh. 8 - Prob. 8.40PCh. 8 - Prob. 8.41PCh. 8 - Prob. 8.42PCh. 8 - Prob. 8.43PCh. 8 - Prob. 8.44PCh. 8 - Prob. 8.45PCh. 8 - Prob. 8.46PCh. 8 - Prob. 8.47PCh. 8 - Prob. 8.48PCh. 8 - Prob. 8.49PCh. 8 - Prob. 8.50PCh. 8 - Prob. 8.51PCh. 8 - Prob. 8.52PCh. 8 - Prob. 8.53PCh. 8 - Prob. 8.54PCh. 8 - Prob. 8.55PCh. 8 - Prob. 8.56PCh. 8 - Prob. 8.57PCh. 8 - Prob. 8.58PCh. 8 - Prob. 8.59PCh. 8 - Prob. 8.60PCh. 8 - Prob. 8.61PCh. 8 - Prob. 8.62PCh. 8 - Prob. 8.63PCh. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - Prob. 8.66PCh. 8 - Prob. 8.67PCh. 8 - Prob. 8.68PCh. 8 - Prob. 8.69PCh. 8 - Prob. 8.70PCh. 8 - Prob. 8.71PCh. 8 - Prob. 8.72PCh. 8 - Prob. 8.73PCh. 8 - Prob. 8.74PCh. 8 - Prob. 8.75PCh. 8 - Prob. 8.76PCh. 8 - Prob. 8.1YTCh. 8 - Prob. 8.2YTCh. 8 - Prob. 8.3YTCh. 8 - Prob. 8.4YTCh. 8 - Prob. 8.5YTCh. 8 - Prob. 8.6YTCh. 8 - Prob. 8.7YTCh. 8 - Prob. 8.8YTCh. 8 - Prob. 8.9YTCh. 8 - Prob. 8.10YTCh. 8 - Prob. 8.11YTCh. 8 - Prob. 8.12YTCh. 8 - Prob. 8.13YTCh. 8 - Prob. 8.14YTCh. 8 - Prob. 8.15YTCh. 8 - Prob. 8.16YTCh. 8 - Prob. 8.17YTCh. 8 - Prob. 8.18YTCh. 8 - Prob. 8.19YT
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