Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 8, Problem 8.46QP
Reactants A (red) and B (blue) combine in the reaction vessel shown to form a single product C (purple) according to the equation 2A + B → C.
Which of the following scenes represents the contents of the reaction vessel after the reaction is complete?
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 8 Solutions
Chemistry: Atoms First
Ch. 8.1 - Write and balance the chemical equation for the...Ch. 8.1 - Write and balance the chemical equation that...Ch. 8.1 - Prob. 1PPBCh. 8.1 - Prob. 1PPCCh. 8.1 - Butyric acid (also known as butanoic acid,...Ch. 8.1 - Another compound found in milk fat that appears to...Ch. 8.1 - Prob. 2PPBCh. 8.1 - Prob. 2PPCCh. 8.1 - Prob. 8.3WECh. 8.1 - Prob. 3PPA
Ch. 8.1 - Using the chemical species A2, B, and AB, write a...Ch. 8.1 - Prob. 3PPCCh. 8.1 - Prob. 8.1.1SRCh. 8.1 - Prob. 8.1.2SRCh. 8.1 - Prob. 8.1.3SRCh. 8.1 - Prob. 8.1.4SRCh. 8.1 - Prob. 8.1.5SRCh. 8.2 - Combustion of a 5.50-g sample of benzene produces...Ch. 8.2 - The combustion of a 28.1-g sample of ascorbic acid...Ch. 8.2 - Prob. 4PPBCh. 8.2 - Prob. 4PPCCh. 8.2 - Prob. 8.2.1SRCh. 8.2 - Prob. 8.2.2SRCh. 8.2 - Prob. 8.2.3SRCh. 8.3 - Prob. 8.5WECh. 8.3 - Nitrogen and hydrogen react to form ammonia...Ch. 8.3 - Prob. 5PPBCh. 8.3 - Prob. 5PPCCh. 8.3 - Prob. 8.6WECh. 8.3 - Calculate the mass of water produced by the...Ch. 8.3 - Prob. 6PPBCh. 8.3 - The models here represent the reaction of nitrogen...Ch. 8.3 - Prob. 8.3.1SRCh. 8.3 - What mass of lithium nitride is produced when 75.0...Ch. 8.3 - Prob. 8.3.3SRCh. 8.3 - Determine the stoichiometric amount (in grams) of...Ch. 8.4 - Alka-Seltzer tablets contain aspirin, sodium...Ch. 8.4 - Ammonia is produced by the reaction of nitrogen...Ch. 8.4 - Prob. 7PPBCh. 8.4 - The diagrams show a reaction mixture before and...Ch. 8.4 - Aspirin, acetylsalicylic acid (C9H8O4), is the...Ch. 8.4 - Diethyl ether is produced from ethanol according...Ch. 8.4 - What mass of ether will be produced if 207 g of...Ch. 8.4 - The diagrams show a mixture of reactants and the...Ch. 8.4 - How many moles of NH3 can be produced by the...Ch. 8.4 - Prob. 8.4.2SRCh. 8.4 - What is the percent yield for a process in which...Ch. 8.4 - Prob. 8.4.4SRCh. 8.4 - Reactants A (red) and B (blue) combine to form a...Ch. 8 - Calculate the mass of water produced in the...Ch. 8 - Calcium phosphide (Ca3P2) and water react to form...Ch. 8 - Prob. 8.3KSPCh. 8 - Prob. 8.4KSPCh. 8 - Prob. 8.1QPCh. 8 - Prob. 8.2QPCh. 8 - Why must a chemical equation he balanced? What law...Ch. 8 - Write an unbalanced equation to represent each of...Ch. 8 - Prob. 8.5QPCh. 8 - Prob. 8.6QPCh. 8 - For each of the following unbalanced chemical...Ch. 8 - Prob. 8.8QPCh. 8 - Balance the following equations using the method...Ch. 8 - Which of the following equations best represents...Ch. 8 - Prob. 8.11QPCh. 8 - Determine whether each of the following equations...Ch. 8 - Prob. 8.13QPCh. 8 - Prob. 8.14QPCh. 8 - Prob. 8.15QPCh. 8 - Prob. 8.16QPCh. 8 - Prob. 8.17QPCh. 8 - Prob. 8.18QPCh. 8 - Prob. 8.19QPCh. 8 - Prob. 8.20QPCh. 8 - Prob. 8.21QPCh. 8 - Prob. 8.22QPCh. 8 - Prob. 8.23QPCh. 8 - On what law is stoichiometry based? Why is it...Ch. 8 - Prob. 8.25QPCh. 8 - Prob. 8.26QPCh. 8 - Prob. 8.27QPCh. 8 - Prob. 8.28QPCh. 8 - Prob. 8.29QPCh. 8 - Prob. 8.30QPCh. 8 - Prob. 8.31QPCh. 8 - Prob. 8.32QPCh. 8 - Prob. 8.33QPCh. 8 - When copper(II) sulfate pentahydrate (CuSO4 5H2O)...Ch. 8 - For many years, the extraction of gold from other...Ch. 8 - Prob. 8.36QPCh. 8 - Nitrous oxide (N2O) is also called laughing gas....Ch. 8 - Prob. 8.38QPCh. 8 - Prob. 8.39QPCh. 8 - Prob. 8.1VCCh. 8 - Prob. 8.2VCCh. 8 - Prob. 8.3VCCh. 8 - Prob. 8.4VCCh. 8 - Prob. 8.40QPCh. 8 - Prob. 8.41QPCh. 8 - Why is the theoretical yield of a reaction...Ch. 8 - Why is the actual yield of a reaction almost...Ch. 8 - Prob. 8.44QPCh. 8 - Prob. 8.45QPCh. 8 - Reactants A (red) and B (blue) combine in the...Ch. 8 - Prob. 8.47QPCh. 8 - Prob. 8.48QPCh. 8 - Prob. 8.49QPCh. 8 - Propane (C3H8) is a minor component of natural gas...Ch. 8 - Prob. 8.51QPCh. 8 - Prob. 8.52QPCh. 8 - Prob. 8.53QPCh. 8 - Prob. 8.54QPCh. 8 - Prob. 8.55QPCh. 8 - Prob. 8.56QPCh. 8 - Disulfur dichloride (S2Cl2) is used in the...Ch. 8 - Prob. 8.58QPCh. 8 - Prob. 8.59QPCh. 8 - Prob. 8.60QPCh. 8 - Prob. 8.61QPCh. 8 - Prob. 8.62QPCh. 8 - Prob. 8.63QPCh. 8 - Prob. 8.64QPCh. 8 - Prob. 8.65QPCh. 8 - Industrially, nitric acid is produced by the...Ch. 8 - Prob. 8.67QPCh. 8 - Prob. 8.68QPCh. 8 - Prob. 8.69QPCh. 8 - Prob. 8.70QPCh. 8 - Prob. 8.71QPCh. 8 - Prob. 8.72QPCh. 8 - Prob. 8.73QPCh. 8 - Prob. 8.74QPCh. 8 - Prob. 8.75QPCh. 8 - Prob. 8.76QPCh. 8 - Prob. 8.77QPCh. 8 - Prob. 8.78QPCh. 8 - Prob. 8.79QPCh. 8 - The combustion of a 5.50-g sample of oxalic acid...Ch. 8 - Prob. 8.81QPCh. 8 - Prob. 8.82QPCh. 8 - Prob. 8.83QPCh. 8 - Prob. 8.84QPCh. 8 - Prob. 8.85QPCh. 8 - Prob. 8.86QPCh. 8 - Potash is any potassium mineral that is used for...Ch. 8 - A 21.496-g sample of magnesium is burned in air to...Ch. 8 - Prob. 8.89QPCh. 8 - Prob. 8.90QPCh. 8 - Prob. 8.91QPCh. 8 - Prob. 8.92QPCh. 8 - Prob. 8.93QPCh. 8 - Prob. 8.94QPCh. 8 - Prob. 8.95QPCh. 8 - Prob. 8.96QPCh. 8 - Prob. 8.97QPCh. 8 - Prob. 8.98QPCh. 8 - A compound X contains 63.3 percent manganese (Mn)...
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