
Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 8.1, Problem 8.1.1SR
Interpretation Introduction
Interpretation: for the given reaction equation, the
Concept introduction:
- Chemical equation is the representation of a
chemical reaction , in which the reactants and products of the reactions are represented left and right side of an arrow respectively by using their respective chemical formulas. - Balanced chemical equation of a reaction is written according to law of conservation of mass.
- Stoichiometric coefficients of a chemical reaction is the relation between the numbers of reactants and products of the reaction and it is represented by the coefficients used for the reactants and products involved in the chemical equation.
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-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
What would be the best choices for the missing reagents 1 and 3 in this synthesis?
1. PPh3
3
1
2
2. n-BuLi
• Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like.
• Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is.
• Note: if one of your reagents needs to contain a halogen, use bromine.
Explanation
Check
Click and drag to start drawing a structure.
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Chapter 8 Solutions
Chemistry: Atoms First
Ch. 8.1 - Write and balance the chemical equation for the...Ch. 8.1 - Write and balance the chemical equation that...Ch. 8.1 - Prob. 1PPBCh. 8.1 - Prob. 1PPCCh. 8.1 - Butyric acid (also known as butanoic acid,...Ch. 8.1 - Another compound found in milk fat that appears to...Ch. 8.1 - Prob. 2PPBCh. 8.1 - Prob. 2PPCCh. 8.1 - Prob. 8.3WECh. 8.1 - Prob. 3PPA
Ch. 8.1 - Using the chemical species A2, B, and AB, write a...Ch. 8.1 - Prob. 3PPCCh. 8.1 - Prob. 8.1.1SRCh. 8.1 - Prob. 8.1.2SRCh. 8.1 - Prob. 8.1.3SRCh. 8.1 - Prob. 8.1.4SRCh. 8.1 - Prob. 8.1.5SRCh. 8.2 - Combustion of a 5.50-g sample of benzene produces...Ch. 8.2 - The combustion of a 28.1-g sample of ascorbic acid...Ch. 8.2 - Prob. 4PPBCh. 8.2 - Prob. 4PPCCh. 8.2 - Prob. 8.2.1SRCh. 8.2 - Prob. 8.2.2SRCh. 8.2 - Prob. 8.2.3SRCh. 8.3 - Prob. 8.5WECh. 8.3 - Nitrogen and hydrogen react to form ammonia...Ch. 8.3 - Prob. 5PPBCh. 8.3 - Prob. 5PPCCh. 8.3 - Prob. 8.6WECh. 8.3 - Calculate the mass of water produced by the...Ch. 8.3 - Prob. 6PPBCh. 8.3 - The models here represent the reaction of nitrogen...Ch. 8.3 - Prob. 8.3.1SRCh. 8.3 - What mass of lithium nitride is produced when 75.0...Ch. 8.3 - Prob. 8.3.3SRCh. 8.3 - Determine the stoichiometric amount (in grams) of...Ch. 8.4 - Alka-Seltzer tablets contain aspirin, sodium...Ch. 8.4 - Ammonia is produced by the reaction of nitrogen...Ch. 8.4 - Prob. 7PPBCh. 8.4 - The diagrams show a reaction mixture before and...Ch. 8.4 - Aspirin, acetylsalicylic acid (C9H8O4), is the...Ch. 8.4 - Diethyl ether is produced from ethanol according...Ch. 8.4 - What mass of ether will be produced if 207 g of...Ch. 8.4 - The diagrams show a mixture of reactants and the...Ch. 8.4 - How many moles of NH3 can be produced by the...Ch. 8.4 - Prob. 8.4.2SRCh. 8.4 - What is the percent yield for a process in which...Ch. 8.4 - Prob. 8.4.4SRCh. 8.4 - Reactants A (red) and B (blue) combine to form a...Ch. 8 - Calculate the mass of water produced in the...Ch. 8 - Calcium phosphide (Ca3P2) and water react to form...Ch. 8 - Prob. 8.3KSPCh. 8 - Prob. 8.4KSPCh. 8 - Prob. 8.1QPCh. 8 - Prob. 8.2QPCh. 8 - Why must a chemical equation he balanced? What law...Ch. 8 - Write an unbalanced equation to represent each of...Ch. 8 - Prob. 8.5QPCh. 8 - Prob. 8.6QPCh. 8 - For each of the following unbalanced chemical...Ch. 8 - Prob. 8.8QPCh. 8 - Balance the following equations using the method...Ch. 8 - Which of the following equations best represents...Ch. 8 - Prob. 8.11QPCh. 8 - Determine whether each of the following equations...Ch. 8 - Prob. 8.13QPCh. 8 - Prob. 8.14QPCh. 8 - Prob. 8.15QPCh. 8 - Prob. 8.16QPCh. 8 - Prob. 8.17QPCh. 8 - Prob. 8.18QPCh. 8 - Prob. 8.19QPCh. 8 - Prob. 8.20QPCh. 8 - Prob. 8.21QPCh. 8 - Prob. 8.22QPCh. 8 - Prob. 8.23QPCh. 8 - On what law is stoichiometry based? Why is it...Ch. 8 - Prob. 8.25QPCh. 8 - Prob. 8.26QPCh. 8 - Prob. 8.27QPCh. 8 - Prob. 8.28QPCh. 8 - Prob. 8.29QPCh. 8 - Prob. 8.30QPCh. 8 - Prob. 8.31QPCh. 8 - Prob. 8.32QPCh. 8 - Prob. 8.33QPCh. 8 - When copper(II) sulfate pentahydrate (CuSO4 5H2O)...Ch. 8 - For many years, the extraction of gold from other...Ch. 8 - Prob. 8.36QPCh. 8 - Nitrous oxide (N2O) is also called laughing gas....Ch. 8 - Prob. 8.38QPCh. 8 - Prob. 8.39QPCh. 8 - Prob. 8.1VCCh. 8 - Prob. 8.2VCCh. 8 - Prob. 8.3VCCh. 8 - Prob. 8.4VCCh. 8 - Prob. 8.40QPCh. 8 - Prob. 8.41QPCh. 8 - Why is the theoretical yield of a reaction...Ch. 8 - Why is the actual yield of a reaction almost...Ch. 8 - Prob. 8.44QPCh. 8 - Prob. 8.45QPCh. 8 - Reactants A (red) and B (blue) combine in the...Ch. 8 - Prob. 8.47QPCh. 8 - Prob. 8.48QPCh. 8 - Prob. 8.49QPCh. 8 - Propane (C3H8) is a minor component of natural gas...Ch. 8 - Prob. 8.51QPCh. 8 - Prob. 8.52QPCh. 8 - Prob. 8.53QPCh. 8 - Prob. 8.54QPCh. 8 - Prob. 8.55QPCh. 8 - Prob. 8.56QPCh. 8 - Disulfur dichloride (S2Cl2) is used in the...Ch. 8 - Prob. 8.58QPCh. 8 - Prob. 8.59QPCh. 8 - Prob. 8.60QPCh. 8 - Prob. 8.61QPCh. 8 - Prob. 8.62QPCh. 8 - Prob. 8.63QPCh. 8 - Prob. 8.64QPCh. 8 - Prob. 8.65QPCh. 8 - Industrially, nitric acid is produced by the...Ch. 8 - Prob. 8.67QPCh. 8 - Prob. 8.68QPCh. 8 - Prob. 8.69QPCh. 8 - Prob. 8.70QPCh. 8 - Prob. 8.71QPCh. 8 - Prob. 8.72QPCh. 8 - Prob. 8.73QPCh. 8 - Prob. 8.74QPCh. 8 - Prob. 8.75QPCh. 8 - Prob. 8.76QPCh. 8 - Prob. 8.77QPCh. 8 - Prob. 8.78QPCh. 8 - Prob. 8.79QPCh. 8 - The combustion of a 5.50-g sample of oxalic acid...Ch. 8 - Prob. 8.81QPCh. 8 - Prob. 8.82QPCh. 8 - Prob. 8.83QPCh. 8 - Prob. 8.84QPCh. 8 - Prob. 8.85QPCh. 8 - Prob. 8.86QPCh. 8 - Potash is any potassium mineral that is used for...Ch. 8 - A 21.496-g sample of magnesium is burned in air to...Ch. 8 - Prob. 8.89QPCh. 8 - Prob. 8.90QPCh. 8 - Prob. 8.91QPCh. 8 - Prob. 8.92QPCh. 8 - Prob. 8.93QPCh. 8 - Prob. 8.94QPCh. 8 - Prob. 8.95QPCh. 8 - Prob. 8.96QPCh. 8 - Prob. 8.97QPCh. 8 - Prob. 8.98QPCh. 8 - A compound X contains 63.3 percent manganese (Mn)...
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