Chemistry: The Molecular Nature of Matter and Change
Chemistry: The Molecular Nature of Matter and Change
9th Edition
ISBN: 9781260477467
Author: Martin Silberberg
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 8, Problem 8.23P

(a)

Interpretation Introduction

Interpretation:

The full ground state electronic configuration of Rb is to be determined.

Concept introduction:

The electronic configuration of an element tells about the distribution of electrons in the atomic orbitals. The energy level that has lower energy is considered to be the ground state. Due to its lower energy, the ground state is taken as a stable state.

The electronic configuration is used to predict the physical, chemical, electrical and magnetic properties of the substance.

The electrons are filled up in accordance with the following three rules:

1. Aufbau principle which states that the electrons are filled up in the increasing order of their orbitals which follows as: 1s2s2p3s3p4s3d.

2. Hund’s rule which states that the pairing of electrons will not start until each of the orbitals is singly occupied.

3. Pauli’s exclusion principle states that no two electrons can have the same value of all the four quantum numbers.

(b)

Interpretation Introduction

Interpretation:

The full ground state electronic configuration of Ge is to be determined.

Concept introduction:

The electronic configuration shows the distribution of electrons of atoms in the atomic orbitals. It is used to predict the physical, chemical, electrical and magnetic properties of the substance.

The electrons are filled up in accordance with the following three rules:

1. Aufbau principle which states that the electrons are filled up in the increasing order of their orbitals which follows as: 1s2s2p3s3p4s3d.

2. Hund’s rule which states that the pairing of electrons will not start until each of the orbitals is singly occupied.

3. Pauli’s exclusion principle states that no two electrons can have the same value of all the four quantum numbers.

(c)

Interpretation Introduction

Interpretation:

The full ground state electronic configuration of Ar is to be determined.

Concept introduction:

The electronic configuration shows the distribution of electrons of atoms in the atomic orbitals. It is used to predict the physical, chemical, electrical and magnetic properties of the substance.

The electrons are filled up in accordance with the following three rules:

1. Aufbau principle which states that the electrons are filled up in the increasing order of their orbitals which follows as: 1s2s2p3s3p4s3d.

2. Hund’s rule which states that the pairing of electrons will not start until each of the orbitals is singly occupied.

3. Pauli’s exclusion principle states that no two electrons can have the same value of all the four quantum numbers.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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Chapter 8 Solutions

Chemistry: The Molecular Nature of Matter and Change

Ch. 8.4 - Prob. 8.6AFPCh. 8.4 - Prob. 8.6BFPCh. 8.4 - Prob. 8.7AFPCh. 8.4 - Prob. 8.7BFPCh. 8 - Prob. 8.1PCh. 8 - Prob. 8.2PCh. 8 - Prob. 8.3PCh. 8 - To test Döbereiner’s idea (Problem 8.3),...Ch. 8 - Summarize the rules for the allowable values of...Ch. 8 - Prob. 8.6PCh. 8 - State the exclusion principle. What does it imply...Ch. 8 - What is the key distinction between sublevel...Ch. 8 - Prob. 8.9PCh. 8 - Prob. 8.10PCh. 8 - Prob. 8.11PCh. 8 - How many electrons in an atom can have each of the...Ch. 8 - Prob. 8.13PCh. 8 - How many electrons in an atom can have each of the...Ch. 8 - Prob. 8.15PCh. 8 - State Hund’s rule in your own words, and show its...Ch. 8 - Prob. 8.17PCh. 8 - For main-group elements, are outer electron...Ch. 8 - Prob. 8.19PCh. 8 - Prob. 8.20PCh. 8 - Prob. 8.21PCh. 8 - Prob. 8.22PCh. 8 - Write the full ground-state electron configuration...Ch. 8 - Prob. 8.24PCh. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - Prob. 8.27PCh. 8 - Draw a partial (valence-level) orbital diagram,...Ch. 8 - Prob. 8.29PCh. 8 - Draw a partial (valence-level) orbital diagram,...Ch. 8 - Draw the partial (valence-level) orbital diagram,...Ch. 8 - Prob. 8.32PCh. 8 - Prob. 8.33PCh. 8 - Prob. 8.34PCh. 8 - Prob. 8.35PCh. 8 - Prob. 8.36PCh. 8 - How many inner, outer, and valence electrons are...Ch. 8 - How many inner, outer, and valence electrons are...Ch. 8 - Prob. 8.39PCh. 8 - Prob. 8.40PCh. 8 - Prob. 8.41PCh. 8 - Prob. 8.42PCh. 8 - Prob. 8.43PCh. 8 - Prob. 8.44PCh. 8 - If the exact outer limit of an isolated atom...Ch. 8 - Given the following partial (valence-level)...Ch. 8 - In what region of the periodic table will you find...Ch. 8 - Why do successive IEs of a given element always...Ch. 8 - Prob. 8.49PCh. 8 - Prob. 8.50PCh. 8 - Prob. 8.51PCh. 8 - Prob. 8.52PCh. 8 - Prob. 8.53PCh. 8 - Prob. 8.54PCh. 8 - Prob. 8.55PCh. 8 - Prob. 8.56PCh. 8 - Prob. 8.57PCh. 8 - Prob. 8.58PCh. 8 - Prob. 8.59PCh. 8 - Prob. 8.60PCh. 8 - Prob. 8.61PCh. 8 - Prob. 8.62PCh. 8 - Prob. 8.63PCh. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - What is a pseudo-noble gas configuration? Give an...Ch. 8 - How are measurements of paramagnetism used to...Ch. 8 - Prob. 8.68PCh. 8 - Prob. 8.69PCh. 8 - Prob. 8.70PCh. 8 - Prob. 8.71PCh. 8 - Prob. 8.72PCh. 8 - Prob. 8.73PCh. 8 - Prob. 8.74PCh. 8 - Prob. 8.75PCh. 8 - Prob. 8.76PCh. 8 - Prob. 8.77PCh. 8 - Prob. 8.78PCh. 8 - Prob. 8.79PCh. 8 - Prob. 8.80PCh. 8 - Which of these atoms are paramagnetic in their...Ch. 8 - Prob. 8.82PCh. 8 - Prob. 8.83PCh. 8 - Write the condensed ground-state electron...Ch. 8 - Prob. 8.85PCh. 8 - Prob. 8.86PCh. 8 - Rank the ions in each set in order of increasing...Ch. 8 - Prob. 8.88PCh. 8 - Prob. 8.89PCh. 8 - Prob. 8.90PCh. 8 - Prob. 8.91PCh. 8 - A fundamental relationship of electrostatics...Ch. 8 - Prob. 8.93PCh. 8 - Prob. 8.94PCh. 8 - Prob. 8.95PCh. 8 - Prob. 8.96PCh. 8 - Prob. 8.97PCh. 8 - Prob. 8.98PCh. 8 - Use Figure 8.16, to find: (a) the longest...Ch. 8 - Prob. 8.100PCh. 8 - Prob. 8.101PCh. 8 - Prob. 8.102P
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