General Chemistry
General Chemistry
7th Edition
ISBN: 9780073402758
Author: Chang, Raymond/ Goldsby
Publisher: McGraw-Hill College
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Chapter 8, Problem 8.101QP

(a)

Interpretation Introduction

Interpretation:

The plot for the given seven ionization energies (IE) for the given atom, the shell that has electrons corresponds to the respective IE and the reason for presence of the break in graph should be determined.

Concept Introduction:

Cation: Removal of electron from the atom results to form positively charged ion called cation.

Anion: Addition of electron to atom results to form negatively charged ion called anion.

The net charge present in the element denotes the presence or absence of electrons in the element.

First ionization energy:

The ionization energy is the minimum energy required to remove the electron from an isolated atom which is in the gaseous state results to give gaseous ion with one positive charge.

atom(g)ion with positive charge(g) + electron

Second ionization:

Repeating the same process that is removal of another electron that is second electron from the resulting ion of first ionization is called second ionization.

Third ionization energy:

Removal of electron from ion that results from the second ionization is called third ionization which results to give ion with three positive charges which shows, three electrons gets removed from the atom and the energy associated with it is called third ionization energy.

To plot: The graph considering the given ionization energies for the given element.

(a)

Expert Solution
Check Mark

Answer to Problem 8.101QP

General Chemistry, Chapter 8, Problem 8.101QP

Figure 1

Analyze the given data and plot the data for the given element.

Explanation of Solution

The graph that shows the ionization energies for the given elements is drawn considering the given data.

The ionization energy increases since it involves removal of electrons such the successive removal of electrons requires more energy compared to the previous as core electrons tends to tightly bound with the nucleus.

(b)

Interpretation Introduction

Interpretation:

The plot for the given seven ionization energies (IE) for the given atom, the shell that has electrons corresponds to the respective IE and the reason for presence of the break in graph should be determined.

Concept Introduction:

Cation: Removal of electron from the atom results to form positively charged ion called cation.

Anion: Addition of electron to atom results to form negatively charged ion called anion.

The net charge present in the element denotes the presence or absence of electrons in the element.

First ionization energy:

The ionization energy is the minimum energy required to remove the electron from an isolated atom which is in the gaseous state results to give gaseous ion with one positive charge.

atom(g)ion with positive charge(g) + electron

Second ionization:

Repeating the same process that is removal of another electron that is second electron from the resulting ion of first ionization is called second ionization.

Third ionization energy:

Removal of electron from ion that results from the second ionization is called third ionization which results to give ion with three positive charges which shows, three electrons gets removed from the atom and the energy associated with it is called third ionization energy.

To determine: The orbital that contains the electron with respect to the energy.

IE13s1IE72p1IE22p6IE82s2IE32p5IE92s1IE42p4IE101s2IE52p3IE111s1IE62p2

(b)

Expert Solution
Check Mark

Explanation of Solution

Examining the graph shows that first the valence electron in the given element gets removed which present in the 3s1 and the successive ionization energy indicates the removal of successive electrons from the orbitals following the order in which the electrons tends to fill.

The orbital that contains electrons with respect to the given energy is determined as above.

(c)

Interpretation Introduction

Interpretation: The plot for the given seven ionization energies (IE) for the given atom, the shell that has electrons corresponds to the respective IE and the reason for presence of the break in graph should be determined.

Concept Introduction:

Cation: Removal of electron from the atom results to form positively charged ion called cation.

Anion: Addition of electron to atom results to form negatively charged ion called anion.

The net charge present in the element denotes the presence or absence of electrons in the element.

First ionization energy:

The ionization energy is the minimum energy required to remove the electron from an isolated atom which is in the gaseous state results to give gaseous ion with one positive charge.

atom(g)ion with positive charge(g) + electron

Second ionization:

Repeating the same process that is removal of another electron that is second electron from the resulting ion of first ionization is called second ionization.

Third ionization energy:

Removal of electron from ion that results from the second ionization is called third ionization which results to give ion with three positive charges which shows, three electrons gets removed from the atom and the energy associated with it is called third ionization energy.

To determine: The reason for the breaks in the curve of the plot for given element.

(c)

Expert Solution
Check Mark

Explanation of Solution

The break in the curve of the plot explains that removal of electrons from one energy level to other level that is break is appeared two times one with going from third to 2nd level and the other from 2nd to the first energy level.

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Chapter 8 Solutions

General Chemistry

Ch. 8.6 - Prob. 1PECh. 8.6 - Prob. 1RCCh. 8 - Prob. 8.1QPCh. 8 - Prob. 8.2QPCh. 8 - Prob. 8.3QPCh. 8 - Prob. 8.4QPCh. 8 - Prob. 8.5QPCh. 8 - Prob. 8.6QPCh. 8 - Prob. 8.7QPCh. 8 - Prob. 8.8QPCh. 8 - Prob. 8.9QPCh. 8 - Prob. 8.10QPCh. 8 - Prob. 8.11QPCh. 8 - Prob. 8.12QPCh. 8 - Prob. 8.13QPCh. 8 - 8.14 Use die first-row transition metals (Sc to...Ch. 8 - 8.15 In the periodic table, the element hydrogen...Ch. 8 - 8.16 A neutral atom of a certain element has 17...Ch. 8 - Prob. 8.17QPCh. 8 - Prob. 8.18QPCh. 8 - Prob. 8.19QPCh. 8 - Prob. 8.20QPCh. 8 - Prob. 8.21QPCh. 8 - 8.21 An ion M2+ derived from a metal in the first...Ch. 8 - Prob. 8.23QPCh. 8 - Prob. 8.24QPCh. 8 - Prob. 8.25QPCh. 8 - Prob. 8.26QPCh. 8 - Prob. 8.27QPCh. 8 - Prob. 8.28QPCh. 8 - Prob. 8.29QPCh. 8 - Prob. 8.30QPCh. 8 - 8.31 Which of these species are isoelectronic with...Ch. 8 - 8.32 Group the species that are isoelectronic:...Ch. 8 - Prob. 8.33QPCh. 8 - 8.34 How does atomic radius change as we move (a)...Ch. 8 - Prob. 8.35QPCh. 8 - Prob. 8.36QPCh. 8 - 8.37 On the basis of their positions in the...Ch. 8 - Prob. 8.38QPCh. 8 - 8.39 Which is the largest atom in Group 4A? Ch. 8 - Prob. 8.40QPCh. 8 - Prob. 8.41QPCh. 8 - Prob. 8.42QPCh. 8 - Prob. 8.43QPCh. 8 - Prob. 8.44QPCh. 8 - Prob. 8.45QPCh. 8 - Prob. 8.46QPCh. 8 - Prob. 8.47QPCh. 8 - Prob. 8.48QPCh. 8 - 8.49 Define ionization energy. Ionization energy...Ch. 8 - Prob. 8.50QPCh. 8 - Prob. 8.51QPCh. 8 - Prob. 8.52QPCh. 8 - Prob. 8.53QPCh. 8 - Prob. 8.54QPCh. 8 - Prob. 8.55QPCh. 8 - Prob. 8.56QPCh. 8 - Prob. 8.57QPCh. 8 - Prob. 8.58QPCh. 8 - Prob. 8.59QPCh. 8 - Prob. 8.60QPCh. 8 - Prob. 8.61QPCh. 8 - Prob. 8.62QPCh. 8 - Prob. 8.63QPCh. 8 - Prob. 8.64QPCh. 8 - Prob. 8.65QPCh. 8 - Prob. 8.66QPCh. 8 - Prob. 8.67QPCh. 8 - 8.68 Why are the Group 1B elements more stable...Ch. 8 - Prob. 8.69QPCh. 8 - Prob. 8.70QPCh. 8 - Prob. 8.71QPCh. 8 - Prob. 8.72QPCh. 8 - Prob. 8.73QPCh. 8 - Prob. 8.74QPCh. 8 - Prob. 8.75QPCh. 8 - Prob. 8.76QPCh. 8 - Prob. 8.77QPCh. 8 - Prob. 8.78QPCh. 8 - Prob. 8.79QPCh. 8 - Prob. 8.80QPCh. 8 - Prob. 8.81QPCh. 8 - Prob. 8.82QPCh. 8 - Prob. 8.83QPCh. 8 - Prob. 8.84QPCh. 8 - Prob. 8.85QPCh. 8 - Prob. 8.86QPCh. 8 - Prob. 8.87QPCh. 8 - Prob. 8.88QPCh. 8 - Prob. 8.89QPCh. 8 - 8.90 Write the formulas and names of the oxides of...Ch. 8 - Prob. 8.91QPCh. 8 - Prob. 8.92QPCh. 8 - Prob. 8.93QPCh. 8 - Prob. 8.94QPCh. 8 - Prob. 8.95QPCh. 8 - Prob. 8.96QPCh. 8 - Prob. 8.97QPCh. 8 - Prob. 8.98QPCh. 8 - 8.99 Explain why the electron affinity of nitrogen...Ch. 8 - Prob. 8.100QPCh. 8 - Prob. 8.101QPCh. 8 - Prob. 8.102QPCh. 8 - Prob. 8.103QPCh. 8 - Prob. 8.104QPCh. 8 - Prob. 8.105QPCh. 8 - Prob. 8.106QPCh. 8 - Prob. 8.107SPCh. 8 - 8.108 In the late 1800s the British physicist Lord...Ch. 8 - Prob. 8.109SPCh. 8 - Prob. 8.110SPCh. 8 - Prob. 8.111SPCh. 8 - Prob. 8.112SPCh. 8 - Prob. 8.113SPCh. 8 - Prob. 8.114SP
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