The mechanism for the solvomercuration step of the ether synthesis and the use of solvomercuration-demercuration to prepare tert-butyl methyl ether is to be shown. The reason for the fact that Hg ( OAc ) 2 is less reactive than Hg ( O 2 CCF 3 ) 2 is to be explained. Concept Introduction: Oxymercuration-demercuration: An organic reaction in which the double bonds of alkenes or alkynes are broken by HgOAc . In this reaction, the multiple carbon–carbon bond has been replaced by OH group. When HgOAc is added to alkenes, they undergo oxymercuration-demercuration and form alcohols. When the solvent molecule attack as a nucleophile, then the process is known as solvomercuration-demercuration and the reagent used is Hg ( O 2 CCF 3 ) 2 .

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Chapter 8, Problem 10PP

Interpretation Introduction

Interpretation:

The mechanism for the solvomercuration step of the ether synthesis and the use of solvomercuration-demercuration to prepare tert-butyl methyl ether is to be shown. The reason for the fact that Hg(OAc)2 is less reactive than Hg(O2CCF3)2 is to be explained.

Concept Introduction:

Oxymercuration-demercuration: An organic reaction in which the double bonds of alkenes or alkynes are broken by HgOAc. In this reaction, the multiple carbon–carbon bond has been replaced by OH group.

When HgOAc is added to alkenes, they undergo oxymercuration-demercuration and form alcohols.

When the solvent molecule attack as a nucleophile, then the process is known as solvomercuration-demercuration and the reagent used is Hg(O2CCF3)2.

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