a) Interpretation: The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement. Concept introduction: In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide. To predict: The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Question

PQ-10. What is the major product of this reaction? (A) (C) 930 Me HO O=S=O O-8-CF, C 어 Me H+ OH 270 O 0-5-0 O=S=O O-S-CF CF3 2

Answer 1

Question

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

PQ-10. What is the major product of this reaction? (A) (C) 930 Me HO O=S=O O-8-CF, C 어 Me H+ OH 270 O 0-5-0 O=S=O O-S-CF CF3 2

Predict the major organic product(s) of the following reactions. Include stereochemistry when necessary. Write NR if no reaction, try to explain.

Q2: Explain why epoxides that react in an SN1 manner will not show any stereochemical inversion in the product. Q3: Rationalize why Alcohol B will react under the indicated reaction conditions, but Alcohol A will not. A ☑ OH B OH PBr3 R-Br

Answer 2

Question

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 5

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 6

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 7

Chapter 7.SE, Problem 27MP

Interpretation Introduction

a)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 8

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 9

Interpretation Introduction

b)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the hydrogen of the alkyl halide to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give another more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 10

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 11

Interpretation Introduction

c)

Interpretation:

The product and the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Concept introduction:

In electrophilic addition reactions, the first step is the attack of the π electrons of the double bond on the H+ of the acid to yield a carbocation. One of the carbon in C=C gets attached to hydrogen while the other acquires a positive charge. In the second step, the carbocation formed can rearrange to give a more stable carbocation either by a hydride shift (shift of hydrogen atom with its electron pair) or by an alkyl shift (shift of an alkyl group with its electron pair) between neighboring carbons. In the last step the carbocation produced reacts with the halide ion to give the alkyl halide.

To predict:

The product and to show the complete arrow-pushing mechanism for the electrophilic reaction given which involves a carbocation rearrangement.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 15

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 16

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 17

Trending nowThis is a popular solution!

Answer 18

Trending nowThis is a popular solution!

Answer 19

Trending nowThis is a popular solution!

Answer 20

Trending now

Answer 21

This is a popular solution!

Answer 22

See solution

Check out sample textbook solution

Answer 23

Ch. 7.2 - Calculate the degree of unsaturation in each of...Ch. 7.2 - Prob. 2P Ch. 7.2 - Diazepam, marketed as an antianxiety medication...Ch. 7.3 - Give IUPAC names for the following compounds:Ch. 7.3 - Prob. 5P Ch. 7.3 - Prob. 6P Ch. 7.3 - Prob. 7P Ch. 7.4 - Prob. 8P Ch. 7.4 - Prob. 9P Ch. 7.4 - Prob. 10P

Concept explainers

Chapter 7 Solutions