
General, Organic, and Biochemistry
9th Edition
ISBN: 9780078021541
Author: Katherine J Denniston, Joseph J Topping, Dr Danae Quirk Dorr
Publisher: McGraw-Hill Education
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Chapter 7.2, Problem 7.4PP
Interpretation Introduction
Interpretation:
The temperature change of a solution that has specific heat of
Concept Introduction:
Specific heat:
The required heat energy to rise a 1 degree Celsius temperature per gram of substance is known as specific heat.
Where,
Q is heat
S is specific heat
m is mass of the substance
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 7 Solutions
General, Organic, and Biochemistry
Ch. 7.1 - Prob. 7.1PPCh. 7.1 - Are the following processes exothermic or...Ch. 7.1 - Prob. 7.2QCh. 7.1 - Prob. 7.3QCh. 7.1 - Prob. 7.4QCh. 7.1 - Prob. 7.2PPCh. 7.1 - Predict whether a reaction with positive ΔH and...Ch. 7.1 - Prob. 7.6QCh. 7.2 - Prob. 7.3PPCh. 7.2 - Prob. 7.4PP
Ch. 7.2 - Prob. 7.7QCh. 7.2 - Prob. 7.8QCh. 7.2 - Prob. 7.5PPCh. 7.3 - Prob. 7.9QCh. 7.3 - Prob. 7.10QCh. 7.3 - Prob. 7.11QCh. 7.3 - Prob. 7.12QCh. 7.3 - Prob. 7.6PPCh. 7.4 - Prob. 7.13QCh. 7.4 - Prob. 7.14QCh. 7.4 - Prob. 7.15QCh. 7.4 - Prob. 7.16QCh. 7.4 - Prob. 7.7PPCh. 7.4 - Prob. 7.8PPCh. 7.4 - Prob. 7.17QCh. 7.4 - Prob. 7.18QCh. 7.4 - Prob. 7.9PPCh. 7.4 - Prob. 7.10PPCh. 7.4 - Prob. 7.11PPCh. 7 - Prob. 7.19QPCh. 7 - State the second law of thermodynamics.
Ch. 7 - Describe what is meant by an exothermic reaction.
Ch. 7 - Describe what is meant by an endothermic...Ch. 7 - Prob. 7.23QPCh. 7 - Prob. 7.24QPCh. 7 - Explain what is meant by the term free energy....Ch. 7 - Prob. 7.26QPCh. 7 - Prob. 7.27QPCh. 7 - Prob. 7.28QPCh. 7 - Predict whether each of the following processes...Ch. 7 - Predict whether each of the following processes...Ch. 7 - Prob. 7.31QPCh. 7 - Energy is required to break chemical bonds during...Ch. 7 - Prob. 7.33QPCh. 7 - Prob. 7.34QPCh. 7 - Prob. 7.35QPCh. 7 - Prob. 7.36QPCh. 7 - Prob. 7.37QPCh. 7 - Prob. 7.38QPCh. 7 - What are the energy units most commonly employed...Ch. 7 - What energy unit is commonly employed in nutrition...Ch. 7 - Prob. 7.41QPCh. 7 - Prob. 7.42QPCh. 7 - A 5.00-g sample of octane is burned in a bomb...Ch. 7 - Prob. 7.44QPCh. 7 - A 30-g sample of chips is burned in a bomb...Ch. 7 - Prob. 7.46QPCh. 7 - Prob. 7.47QPCh. 7 - Prob. 7.48QPCh. 7 - Prob. 7.49QPCh. 7 - Prob. 7.50QPCh. 7 - Prob. 7.51QPCh. 7 - Prob. 7.52QPCh. 7 - Prob. 7.53QPCh. 7 - Lactase is an enzyme featured in Chapter 16,...Ch. 7 - Prob. 7.55QPCh. 7 - Prob. 7.56QPCh. 7 - Prob. 7.57QPCh. 7 - Prob. 7.58QPCh. 7 - Prob. 7.59QPCh. 7 - Prob. 7.60QPCh. 7 - Prob. 7.61QPCh. 7 - Prob. 7.62QPCh. 7 - Prob. 7.63QPCh. 7 - Prob. 7.64QPCh. 7 - For the equilibrium
the rate law is:
at 23°C, k...Ch. 7 - Prob. 7.66QPCh. 7 - Prob. 7.67QPCh. 7 - Prob. 7.68QPCh. 7 - Prob. 7.69QPCh. 7 - Prob. 7.70QPCh. 7 - Prob. 7.71QPCh. 7 - Prob. 7.72QPCh. 7 - Prob. 7.73QPCh. 7 - Label each of the following statements as true or...Ch. 7 - Prob. 7.75QPCh. 7 - Prob. 7.76QPCh. 7 - Prob. 7.77QPCh. 7 - Prob. 7.78QPCh. 7 - Prob. 7.79QPCh. 7 - Prob. 7.80QPCh. 7 - Prob. 7.81QPCh. 7 - Prob. 7.82QPCh. 7 - Prob. 7.83QPCh. 7 - Prob. 7.84QPCh. 7 - Prob. 7.85QPCh. 7 - Prob. 7.86QPCh. 7 - Prob. 7.87QPCh. 7 - Prob. 7.88QPCh. 7 - Prob. 7.89QPCh. 7 - Prob. 7.90QPCh. 7 - Prob. 7.91QPCh. 7 - Prob. 7.92QPCh. 7 - Prob. 7.93QPCh. 7 - Prob. 7.94QPCh. 7 - Prob. 7.95QPCh. 7 - Prob. 7.96QPCh. 7 - Prob. 7.97QPCh. 7 - Prob. 7.98QPCh. 7 - Prob. 7.99QPCh. 7 - Prob. 7.100QPCh. 7 - Prob. 7.101QPCh. 7 - Prob. 7.102QPCh. 7 - Prob. 7.103QPCh. 7 - Prob. 7.104QPCh. 7 - Prob. 7.105QPCh. 7 - Prob. 7.106QPCh. 7 - Predict the sign of G for perspiration...Ch. 7 - Prob. 2CPCh. 7 - Prob. 5CPCh. 7 - Prob. 6CPCh. 7 - Prob. 7CPCh. 7 - Prob. 8CP
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