General, Organic, and Biochemistry
9th Edition
ISBN: 9780078021541
Author: Katherine J Denniston, Joseph J Topping, Dr Danae Quirk Dorr
Publisher: McGraw-Hill Education
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Chapter 7, Problem 7.55QP
Interpretation Introduction
Interpretation:
The way in which the
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When N,N-dimethylaniline is treated with bromine both the ortho and para products
are observed. However when treated with a mixture of nitric acid and sulfuric acid only
the meta product is observed. Explain these results and support your answer with the
appropriate drawings *Hint amines are bases*
N
HNO3
H2SO4
N
NO2
N
Br2
N
Br
+
N
8-8-8
FeBr3
Br
Draw a mechanism that explains the formation of compound
OMe
SO3H
1. Fuming H2SO4
Consider the following two acid-base reactions:
OH
OHI
Based on what you know about the compounds and their acidity, which
direction would you expect both of these reactions to proceed? Show
your reasoning.
A pKa table has been provided in case you need it.
Functional group
Example
pka
CHA
-50
Alkane
-35
Amine
: NH3
Alkyne
RH
25
Water
HO-H
169
16
10
Protonated
amines
NH
10
5
Carboxylic
acids
OH
Hydrochloric
acid
HCI
A chemist intends to run the following reaction on the three substrates shown below:
H₂O
R-CI
product
room temp.
Cl
Cl
(1)
(2)
(3)
They find one will react quickly, one slowly, and one will not react at all. Which is which, and why?
HINT: What is the reaction they're trying to do? Does that mechanism tell you anything about why something would be favored?
Chapter 7 Solutions
General, Organic, and Biochemistry
Ch. 7.1 - Prob. 7.1PPCh. 7.1 - Are the following processes exothermic or...Ch. 7.1 - Prob. 7.2QCh. 7.1 - Prob. 7.3QCh. 7.1 - Prob. 7.4QCh. 7.1 - Prob. 7.2PPCh. 7.1 - Predict whether a reaction with positive ΔH and...Ch. 7.1 - Prob. 7.6QCh. 7.2 - Prob. 7.3PPCh. 7.2 - Prob. 7.4PP
Ch. 7.2 - Prob. 7.7QCh. 7.2 - Prob. 7.8QCh. 7.2 - Prob. 7.5PPCh. 7.3 - Prob. 7.9QCh. 7.3 - Prob. 7.10QCh. 7.3 - Prob. 7.11QCh. 7.3 - Prob. 7.12QCh. 7.3 - Prob. 7.6PPCh. 7.4 - Prob. 7.13QCh. 7.4 - Prob. 7.14QCh. 7.4 - Prob. 7.15QCh. 7.4 - Prob. 7.16QCh. 7.4 - Prob. 7.7PPCh. 7.4 - Prob. 7.8PPCh. 7.4 - Prob. 7.17QCh. 7.4 - Prob. 7.18QCh. 7.4 - Prob. 7.9PPCh. 7.4 - Prob. 7.10PPCh. 7.4 - Prob. 7.11PPCh. 7 - Prob. 7.19QPCh. 7 - State the second law of thermodynamics.
Ch. 7 - Describe what is meant by an exothermic reaction.
Ch. 7 - Describe what is meant by an endothermic...Ch. 7 - Prob. 7.23QPCh. 7 - Prob. 7.24QPCh. 7 - Explain what is meant by the term free energy....Ch. 7 - Prob. 7.26QPCh. 7 - Prob. 7.27QPCh. 7 - Prob. 7.28QPCh. 7 - Predict whether each of the following processes...Ch. 7 - Predict whether each of the following processes...Ch. 7 - Prob. 7.31QPCh. 7 - Energy is required to break chemical bonds during...Ch. 7 - Prob. 7.33QPCh. 7 - Prob. 7.34QPCh. 7 - Prob. 7.35QPCh. 7 - Prob. 7.36QPCh. 7 - Prob. 7.37QPCh. 7 - Prob. 7.38QPCh. 7 - What are the energy units most commonly employed...Ch. 7 - What energy unit is commonly employed in nutrition...Ch. 7 - Prob. 7.41QPCh. 7 - Prob. 7.42QPCh. 7 - A 5.00-g sample of octane is burned in a bomb...Ch. 7 - Prob. 7.44QPCh. 7 - A 30-g sample of chips is burned in a bomb...Ch. 7 - Prob. 7.46QPCh. 7 - Prob. 7.47QPCh. 7 - Prob. 7.48QPCh. 7 - Prob. 7.49QPCh. 7 - Prob. 7.50QPCh. 7 - Prob. 7.51QPCh. 7 - Prob. 7.52QPCh. 7 - Prob. 7.53QPCh. 7 - Lactase is an enzyme featured in Chapter 16,...Ch. 7 - Prob. 7.55QPCh. 7 - Prob. 7.56QPCh. 7 - Prob. 7.57QPCh. 7 - Prob. 7.58QPCh. 7 - Prob. 7.59QPCh. 7 - Prob. 7.60QPCh. 7 - Prob. 7.61QPCh. 7 - Prob. 7.62QPCh. 7 - Prob. 7.63QPCh. 7 - Prob. 7.64QPCh. 7 - For the equilibrium
the rate law is:
at 23°C, k...Ch. 7 - Prob. 7.66QPCh. 7 - Prob. 7.67QPCh. 7 - Prob. 7.68QPCh. 7 - Prob. 7.69QPCh. 7 - Prob. 7.70QPCh. 7 - Prob. 7.71QPCh. 7 - Prob. 7.72QPCh. 7 - Prob. 7.73QPCh. 7 - Label each of the following statements as true or...Ch. 7 - Prob. 7.75QPCh. 7 - Prob. 7.76QPCh. 7 - Prob. 7.77QPCh. 7 - Prob. 7.78QPCh. 7 - Prob. 7.79QPCh. 7 - Prob. 7.80QPCh. 7 - Prob. 7.81QPCh. 7 - Prob. 7.82QPCh. 7 - Prob. 7.83QPCh. 7 - Prob. 7.84QPCh. 7 - Prob. 7.85QPCh. 7 - Prob. 7.86QPCh. 7 - Prob. 7.87QPCh. 7 - Prob. 7.88QPCh. 7 - Prob. 7.89QPCh. 7 - Prob. 7.90QPCh. 7 - Prob. 7.91QPCh. 7 - Prob. 7.92QPCh. 7 - Prob. 7.93QPCh. 7 - Prob. 7.94QPCh. 7 - Prob. 7.95QPCh. 7 - Prob. 7.96QPCh. 7 - Prob. 7.97QPCh. 7 - Prob. 7.98QPCh. 7 - Prob. 7.99QPCh. 7 - Prob. 7.100QPCh. 7 - Prob. 7.101QPCh. 7 - Prob. 7.102QPCh. 7 - Prob. 7.103QPCh. 7 - Prob. 7.104QPCh. 7 - Prob. 7.105QPCh. 7 - Prob. 7.106QPCh. 7 - Predict the sign of G for perspiration...Ch. 7 - Prob. 2CPCh. 7 - Prob. 5CPCh. 7 - Prob. 6CPCh. 7 - Prob. 7CPCh. 7 - Prob. 8CP
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