Organic And Biological Chemistry
7th Edition
ISBN: 9781305638686
Author: H. Stephen Stoker
Publisher: Brooks Cole
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Chapter 7.10, Problem 1QQ
Interpretation Introduction
Interpretation:
The number of different forms of a D-monosaccharide which are present at equilibrium in an aqueous solution of the monosaccharide has to be predicted
Concept introduction:
Open chain structures of monosaccharides which contain five or more carbon atoms exist in equilibrium with two cyclic structures. These cyclic structures are the dominating forms at equilibrium. The carbonyl group in the open-chain structure of monosaccharide reacts intramolecularly with a hydroxyl group which results in the formation of cyclic forms. These cyclic compounds are called cyclic hemiacetals.
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For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 →> NO₂+ NO3_(K1)
NO2 + NO3 → N2O5 (k-1)
NO2 + NO3 →
→
NO2 + O2 + NO (K2)
NO + N2O5-
NO2 + NO2 + NO2 (K3)
d[N₂O5] __2k‚k₂[N2O5]
Indicate whether the following rate expression is acceptable:
dt
k₁₁+ k₂
Consider the following decomposition reaction of N2O5(g):
For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 → NO2 + NO3 (K1)
NO2 + NO3 → N2O5 (k-1)
NO2 + NO3 → NO2 + O2 + NO (K2)
NO + N2O5 → NO2 + NO2 + NO2 (K3)
Indicate whether the following rate expression is acceptable:
d[N2O5]
= -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³
dt
In a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.
Chapter 7 Solutions
Organic And Biological Chemistry
Ch. 7.1 - In terms of mass percent, which of the following...Ch. 7.1 - Which of the following is the most abundant type...Ch. 7.2 - Which of the following statements concerning the...Ch. 7.2 - Prob. 2QQCh. 7.3 - Prob. 1QQCh. 7.3 - Prob. 2QQCh. 7.3 - Which of the following is not a possible value for...Ch. 7.3 - The complete hydrolysis of a polysaccharide...Ch. 7.4 - Prob. 1QQCh. 7.4 - Prob. 2QQ
Ch. 7.4 - Prob. 3QQCh. 7.4 - Prob. 4QQCh. 7.5 - Prob. 1QQCh. 7.5 - Prob. 2QQCh. 7.6 - Prob. 1QQCh. 7.6 - Which of the following Fischer projection formulas...Ch. 7.6 - Prob. 3QQCh. 7.6 - Prob. 4QQCh. 7.7 - Prob. 1QQCh. 7.7 - Prob. 2QQCh. 7.8 - Prob. 1QQCh. 7.8 - Which of the following statements about...Ch. 7.8 - Prob. 3QQCh. 7.9 - Prob. 1QQCh. 7.9 - Prob. 2QQCh. 7.9 - Prob. 3QQCh. 7.9 - In which of the following pairs of monosaccharides...Ch. 7.9 - In which of the following pairs of monosaccharides...Ch. 7.10 - Prob. 1QQCh. 7.10 - Which of the following structures represents a...Ch. 7.10 - Prob. 3QQCh. 7.10 - Prob. 4QQCh. 7.10 - Prob. 5QQCh. 7.11 - Prob. 1QQCh. 7.11 - Which of the following is the correct Haworth...Ch. 7.12 - Prob. 1QQCh. 7.12 - Prob. 2QQCh. 7.12 - Prob. 3QQCh. 7.12 - Prob. 4QQCh. 7.12 - Prob. 5QQCh. 7.13 - Which of the following disaccharides contains...Ch. 7.13 - Which of the following disaccharides will produce...Ch. 7.13 - In which of the following disaccharides is the...Ch. 7.13 - In which of the following pairs of disaccharides...Ch. 7.13 - Which of the following disaccharides is not a...Ch. 7.13 - The terms milk sugar and table sugar apply,...Ch. 7.14 - Prob. 1QQCh. 7.14 - Prob. 2QQCh. 7.15 - Which of the following statements about...Ch. 7.15 - Prob. 2QQCh. 7.16 - Which of the following storage polysaccharides has...Ch. 7.16 - Prob. 2QQCh. 7.16 - Prob. 3QQCh. 7.16 - Prob. 4QQCh. 7.17 - Prob. 1QQCh. 7.17 - Which of the following statements about cellulose...Ch. 7.17 - Chitin is a polysaccharide in which the...Ch. 7.18 - Which of the following statements about the...Ch. 7.18 - Which of the following statements about the...Ch. 7.19 - Which of the following is not classified as a...Ch. 7.19 - Prob. 2QQCh. 7.20 - Which of the following types of compounds are...Ch. 7.20 - Which of the following is not a biochemical...Ch. 7 - Prob. 7.1EPCh. 7 - Prob. 7.2EPCh. 7 - Prob. 7.3EPCh. 7 - Prob. 7.4EPCh. 7 - Prob. 7.5EPCh. 7 - Prob. 7.6EPCh. 7 - Prob. 7.7EPCh. 7 - Prob. 7.8EPCh. 7 - Prob. 7.9EPCh. 7 - Prob. 7.10EPCh. 7 - Prob. 7.11EPCh. 7 - Prob. 7.12EPCh. 7 - Prob. 7.13EPCh. 7 - Prob. 7.14EPCh. 7 - Prob. 7.15EPCh. 7 - Prob. 7.16EPCh. 7 - Prob. 7.17EPCh. 7 - Prob. 7.18EPCh. 7 - Prob. 7.19EPCh. 7 - Prob. 7.20EPCh. 7 - Prob. 7.21EPCh. 7 - Prob. 7.22EPCh. 7 - Prob. 7.23EPCh. 7 - Prob. 7.24EPCh. 7 - Prob. 7.25EPCh. 7 - Indicate whether or not each of the molecules in...Ch. 7 - Prob. 7.27EPCh. 7 - Prob. 7.28EPCh. 7 - Prob. 7.29EPCh. 7 - Prob. 7.30EPCh. 7 - Prob. 7.31EPCh. 7 - Prob. 7.32EPCh. 7 - Prob. 7.33EPCh. 7 - Prob. 7.34EPCh. 7 - Prob. 7.35EPCh. 7 - Draw the Fischer projection formula for each of...Ch. 7 - Prob. 7.37EPCh. 7 - Prob. 7.38EPCh. 7 - Prob. 7.39EPCh. 7 - Prob. 7.40EPCh. 7 - Prob. 7.41EPCh. 7 - Prob. 7.42EPCh. 7 - Prob. 7.43EPCh. 7 - Prob. 7.44EPCh. 7 - Prob. 7.45EPCh. 7 - Prob. 7.46EPCh. 7 - Prob. 7.47EPCh. 7 - Prob. 7.48EPCh. 7 - Prob. 7.49EPCh. 7 - Prob. 7.50EPCh. 7 - Prob. 7.51EPCh. 7 - Prob. 7.52EPCh. 7 - Prob. 7.53EPCh. 7 - Prob. 7.54EPCh. 7 - Prob. 7.55EPCh. 7 - Prob. 7.56EPCh. 7 - Prob. 7.57EPCh. 7 - Prob. 7.58EPCh. 7 - Prob. 7.59EPCh. 7 - Prob. 7.60EPCh. 7 - Prob. 7.61EPCh. 7 - Prob. 7.62EPCh. 7 - Prob. 7.63EPCh. 7 - Prob. 7.64EPCh. 7 - Prob. 7.65EPCh. 7 - Prob. 7.66EPCh. 7 - Prob. 7.67EPCh. 7 - Prob. 7.68EPCh. 7 - Prob. 7.69EPCh. 7 - Prob. 7.70EPCh. 7 - Prob. 7.71EPCh. 7 - Prob. 7.72EPCh. 7 - Prob. 7.73EPCh. 7 - Prob. 7.74EPCh. 7 - Prob. 7.75EPCh. 7 - Prob. 7.76EPCh. 7 - Prob. 7.77EPCh. 7 - Prob. 7.78EPCh. 7 - Prob. 7.79EPCh. 7 - Prob. 7.80EPCh. 7 - Prob. 7.81EPCh. 7 - Prob. 7.82EPCh. 7 - Prob. 7.83EPCh. 7 - Prob. 7.84EPCh. 7 - Prob. 7.85EPCh. 7 - Prob. 7.86EPCh. 7 - Prob. 7.87EPCh. 7 - Prob. 7.88EPCh. 7 - Prob. 7.89EPCh. 7 - Prob. 7.90EPCh. 7 - Prob. 7.91EPCh. 7 - Prob. 7.92EPCh. 7 - Prob. 7.93EPCh. 7 - Prob. 7.94EPCh. 7 - Prob. 7.95EPCh. 7 - Prob. 7.96EPCh. 7 - Prob. 7.97EPCh. 7 - Classify each of the glucose derivatives in...Ch. 7 - Prob. 7.99EPCh. 7 - Prob. 7.100EPCh. 7 - Prob. 7.101EPCh. 7 - Prob. 7.102EPCh. 7 - Prob. 7.103EPCh. 7 - Prob. 7.104EPCh. 7 - 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