CHEM PRINCIPLES LL W/ACHIEVE ONE-SEM
7th Edition
ISBN: 9781319420994
Author: ATKINS
Publisher: MAC HIGHER
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Chapter 7, Problem 7E.6E
Interpretation Introduction
Interpretation:
The overall reaction of the given mechanism has to be stated and the reaction intermediate and catalyst have to be identified.
Concept Introduction:
The elementary reactions are categorized according to their molecularity. The term molecularity is referred to the number of reacting species which can be molecules, ions or atoms in an elementary reaction. The species in the reaction mechanism is referred to as the reaction intermediate which does not participate in the overall reaction of the proposed mechanism.
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Please help with number 6 I got a negative number could that be right?
1,4-Dimethyl-1,3-cyclohexadiene can undergo 1,2- or 1,4-addition with hydrogen halides. (a) 1,2-Addition i. Draw the carbocation intermediate(s) formed during the 1,2-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,2-addition product formed during the reaction in (i)? (b) 1,4-Addition i. Draw the carbocation intermediate(s) formed during the 1,4-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,4-addition product formed from the reaction in (i)? (c) What is the kinetic product from the reaction of one mole of hydrobromic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (d) What is the thermodynamic product from the reaction of one mole of hydrobro-mic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (e) What major product will result when 1,4-dimethyl-1,3-cyclohexadiene is treated with one mole of hydrobromic acid at - 78 deg * C ? Explain your reasoning.
Give the product of the bimolecular elimination from each of the isomeric halogenated compounds.
Reaction A
Reaction B.
КОВ
CH₂
HotBu
+B+
ко
HOIBU
+Br+
Templates More
QQQ
Select Cv Templates More
Cras
QQQ
One of these compounds undergoes elimination 50x faster than the other. Which one and why?
Reaction A because the conformation needed for elimination places the phenyl groups and to each other
Reaction A because the conformation needed for elimination places the phenyl groups gauche to each other.
◇ Reaction B because the conformation needed for elimination places the phenyl groups gach to each other.
Reaction B because the conformation needed for elimination places the phenyl groups anti to each other.
Chapter 7 Solutions
CHEM PRINCIPLES LL W/ACHIEVE ONE-SEM
Ch. 7 - Prob. 7A.1ASTCh. 7 - Prob. 7A.1BSTCh. 7 - Prob. 7A.2ASTCh. 7 - Prob. 7A.2BSTCh. 7 - Prob. 7A.3ASTCh. 7 - Prob. 7A.3BSTCh. 7 - Prob. 7A.4ASTCh. 7 - Prob. 7A.4BSTCh. 7 - Prob. 7A.1ECh. 7 - Prob. 7A.2E
Ch. 7 - Prob. 7A.3ECh. 7 - Prob. 7A.4ECh. 7 - Prob. 7A.7ECh. 7 - Prob. 7A.8ECh. 7 - Prob. 7A.9ECh. 7 - Prob. 7A.10ECh. 7 - Prob. 7A.11ECh. 7 - Prob. 7A.12ECh. 7 - Prob. 7A.13ECh. 7 - Prob. 7A.14ECh. 7 - Prob. 7A.15ECh. 7 - Prob. 7A.16ECh. 7 - Prob. 7A.17ECh. 7 - Prob. 7A.18ECh. 7 - Prob. 7B.1ASTCh. 7 - Prob. 7B.1BSTCh. 7 - Prob. 7B.2ASTCh. 7 - Prob. 7B.2BSTCh. 7 - Prob. 7B.3ASTCh. 7 - Prob. 7B.3BSTCh. 7 - Prob. 7B.4ASTCh. 7 - Prob. 7B.4BSTCh. 7 - Prob. 7B.5ASTCh. 7 - Prob. 7B.5BSTCh. 7 - Prob. 7B.1ECh. 7 - Prob. 7B.2ECh. 7 - Prob. 7B.3ECh. 7 - Prob. 7B.4ECh. 7 - Prob. 7B.5ECh. 7 - Prob. 7B.6ECh. 7 - Prob. 7B.7ECh. 7 - Prob. 7B.8ECh. 7 - Prob. 7B.9ECh. 7 - Prob. 7B.10ECh. 7 - Prob. 7B.13ECh. 7 - Prob. 7B.14ECh. 7 - Prob. 7B.15ECh. 7 - Prob. 7B.16ECh. 7 - Prob. 7B.17ECh. 7 - Prob. 7B.18ECh. 7 - Prob. 7B.19ECh. 7 - Prob. 7B.20ECh. 7 - Prob. 7B.21ECh. 7 - Prob. 7B.22ECh. 7 - Prob. 7C.1ASTCh. 7 - Prob. 7C.1BSTCh. 7 - Prob. 7C.2ASTCh. 7 - Prob. 7C.2BSTCh. 7 - Prob. 7C.1ECh. 7 - Prob. 7C.2ECh. 7 - Prob. 7C.3ECh. 7 - Prob. 7C.4ECh. 7 - Prob. 7C.5ECh. 7 - Prob. 7C.6ECh. 7 - Prob. 7C.7ECh. 7 - Prob. 7C.8ECh. 7 - Prob. 7C.9ECh. 7 - Prob. 7C.11ECh. 7 - Prob. 7C.12ECh. 7 - Prob. 7D.1ASTCh. 7 - Prob. 7D.1BSTCh. 7 - Prob. 7D.2ASTCh. 7 - Prob. 7D.2BSTCh. 7 - Prob. 7D.1ECh. 7 - Prob. 7D.2ECh. 7 - Prob. 7D.3ECh. 7 - Prob. 7D.5ECh. 7 - Prob. 7D.6ECh. 7 - Prob. 7D.7ECh. 7 - Prob. 7D.8ECh. 7 - Prob. 7E.1ASTCh. 7 - Prob. 7E.1BSTCh. 7 - Prob. 7E.1ECh. 7 - Prob. 7E.2ECh. 7 - Prob. 7E.3ECh. 7 - Prob. 7E.4ECh. 7 - Prob. 7E.5ECh. 7 - Prob. 7E.6ECh. 7 - Prob. 7E.7ECh. 7 - Prob. 7E.8ECh. 7 - Prob. 7E.9ECh. 7 - Prob. 1OCECh. 7 - Prob. 7.1ECh. 7 - Prob. 7.2ECh. 7 - Prob. 7.3ECh. 7 - Prob. 7.4ECh. 7 - Prob. 7.5ECh. 7 - Prob. 7.6ECh. 7 - Prob. 7.7ECh. 7 - Prob. 7.9ECh. 7 - Prob. 7.11ECh. 7 - Prob. 7.14ECh. 7 - Prob. 7.15ECh. 7 - Prob. 7.17ECh. 7 - Prob. 7.19ECh. 7 - Prob. 7.20ECh. 7 - Prob. 7.23ECh. 7 - Prob. 7.25ECh. 7 - Prob. 7.26ECh. 7 - Prob. 7.29ECh. 7 - Prob. 7.30ECh. 7 - Prob. 7.31E
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