Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter 7, Problem 7.9YT
Interpretation Introduction

Interpretation:

The missing curved arrow notation is to be supplied for the given E2 step, and the pertinent electron-rich and electron-poor sites are to be identified.

Concept introduction:

Curved arrow notation shows the movement of electrons from an electron-rich site to an electron-poor site.

In an E2 elimination, a base extracts an acidic (relatively electron-poor) hydrogen, with the CH bond pair moving to the next carbon bonded to the halogen (X), and the CX undergoes heterolysis.

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For the reaction below: 1. Draw all reasonable elimination products to the right of the arrow. 2. In the box below the reaction, redraw any product you expect to be a major product. C Major Product: Check + ◎ + X ง © Cl I F2 80 F3 I σ F4 I F5 NaOH Click and drawing F6 A 2025 McGraw Hill LLC. All Rights E F7 F8 $ # % & 2 3 4 5 6 7 8 Q W E R T Y U A S D F G H J
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N Draw the major product of this reaction. Ignore inorganic byproducts. D 1. H₂O, pyridine 2. neutralizing work-up V P W X DE CO e C L

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Organic Chemistry: Principles and Mechanisms (Second Edition)

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