Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter 7, Problem 7.30P
Interpretation Introduction

Interpretation:

Products for the given electrophilic addition are to be drawn and the more stable is to be predicted.

Concept introduction:

In the electrophilic addition reaction, the substrate containing a non-polar π bond (as part of a double or triple bond) approaches a strongly electron-deficient species (an electrophile) and a bond forms between an atom of the π bond and the electrophile. The other carbon of the π bond gets a positive charge as the π bond pair moves away from it. The product is a carbocation which is highly unstable because it bears a positive charge and has an incomplete octet. A carbocation can be stabilized by resonance.

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SYNTHESIS REACTIONS. For the following reactions, synthesize the given products from the given reactants. Multiple reactions/steps will be needed. For the one of the steps (ie reactions) in each synthesis, write out the mechanism for that reaction and draw an energy diagram showing the correct number of hills and valleys for that step's mechanism. CI b. a. Use acetylene (ethyne) and any alkyl halide as your starting materials Br C. d. "OH OH III. OH

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Organic Chemistry: Principles and Mechanisms (Second Edition)

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