(a) Interpretation: The curved arrow notation for the elimination of H + from the carbocation shown is to be drawn along with the product. Concept introduction: Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond. A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

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Answer 1

Question

Chapter 7, Problem 7.35P

Interpretation Introduction

(a)

Interpretation:

The curved arrow notation for the elimination of H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

Interpretation Introduction

(b)

Interpretation:

The curved arrow notation for the elimination of SO3H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

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Answer 2

Question

Chapter 7, Problem 7.35P

Interpretation Introduction

(a)

Interpretation:

The curved arrow notation for the elimination of H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

Interpretation Introduction

(b)

Interpretation:

The curved arrow notation for the elimination of SO3H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

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Answer 3

Question

Chapter 7, Problem 7.35P

Interpretation Introduction

(a)

Interpretation:

The curved arrow notation for the elimination of H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

Interpretation Introduction

(b)

Interpretation:

The curved arrow notation for the elimination of SO3H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

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Answer 4

Question

Chapter 7, Problem 7.35P

Interpretation Introduction

(a)

Interpretation:

The curved arrow notation for the elimination of H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

Interpretation Introduction

(b)

Interpretation:

The curved arrow notation for the elimination of SO3H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

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Answer 5

Chapter 7, Problem 7.35P

Interpretation Introduction

(a)

Interpretation:

The curved arrow notation for the elimination of H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

Interpretation Introduction

(b)

Interpretation:

The curved arrow notation for the elimination of SO3H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

Answer 6

Chapter 7, Problem 7.35P

Interpretation Introduction

(a)

Interpretation:

The curved arrow notation for the elimination of H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

Answer 7

Chapter 7, Problem 7.35P

Interpretation Introduction

(a)

Interpretation:

The curved arrow notation for the elimination of H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved arrow notation for the elimination of SO3H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved arrow notation for the elimination of SO3H+ from the carbocation shown is to be drawn along with the product.

Concept introduction:

Curved arrows are used to represent the movement of electrons in a reaction mechanism. The arrow starts on an electron-rich atom or an electron-rich region such as a pi bond. It ends on an electron poor atom when the movement results in the formation of a new sigma bond. If the result is the formation of a pi bond, the arrow ends in the region between the two atoms that form the bond.

A carbocation is a positively charged carbon atom that is electron-poor, two electrons short of an octet. A nearby bond or a lone pair on a nearby atom acts as an electron-rich region and can transfer the pair of electrons to the electron-poor atom. This can result in the formation of a more stable neutral species, accompanied by the loss of an electrophile. The electrophile may be a proton or another cationic species and is extracted by any base that may be present.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 7 - Prob. 7.1P Ch. 7 - Prob. 7.2P Ch. 7 - Prob. 7.3P Ch. 7 - Prob. 7.4P Ch. 7 - Prob. 7.5P Ch. 7 - Prob. 7.6P Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

Solution Summary: The author explains that curved arrows represent the movement of electrons in a reaction mechanism.

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Chapter 7 Solutions