EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Question
Chapter 7, Problem 7.73P
Interpretation Introduction
Interpretation:
The sample with more mass needs to be determined.
Sample of 2.0 L of O2 at 273K and 500mmHg or sample of 1.5 L of N2 at 298K and 650mmHg.
Concept Introduction:
The concept of ideal gas will be used. The ideal gas equation is represented as follows:
Here,
n = number of moles
P = pressure
V = volume
R = gas constant
T = temperature
Also,
Here, m is mass, n is the number of moles and M is molar mass.
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⚫ worksheets.beyondlabz.com
5 (a). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 6
5 (b). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 7
6. Are there any differences between the spectra you obtained
in Beyond Labz and the predicted spectra? If so, what were
the differences?
<
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Chapter 7 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 7.1 - Prob. 7.1PCh. 7.2 - Convert each pressure unit to the indicated unit....Ch. 7.3 - Prob. 7.3PCh. 7.3 - Prob. 7.4PCh. 7.3 - Prob. 7.5PCh. 7.3 - Prob. 7.6PCh. 7.3 - Prob. 7.7PCh. 7.3 - Prob. 7.8PCh. 7.3 - The pressure inside a 1.0-L balloon at 25C was 750...Ch. 7.4 - A sample of nitrogen gas contains 5.0 mol in a...
Ch. 7.4 - Prob. 7.11PCh. 7.4 - Prob. 7.12PCh. 7.5 - Prob. 7.13PCh. 7.5 - Prob. 7.14PCh. 7.6 - CO2 was added to a cylinder containing 2.5 atm of...Ch. 7.6 - Prob. 7.16PCh. 7.6 - Prob. 7.17PCh. 7.7 - Prob. 7.18PCh. 7.7 - Prob. 7.19PCh. 7.7 - Prob. 7.20PCh. 7.7 - Which species in each pair has stronger...Ch. 7.7 - Prob. 7.22PCh. 7.7 - Prob. 7.23PCh. 7.8 - Prob. 7.24PCh. 7.8 - Would you predict the surface tension of gasoline,...Ch. 7.9 - Prob. 7.26PCh. 7.10 - Prob. 7.27PCh. 7.10 - The human body is composed of about 70% water. How...Ch. 7.10 - How much energy is required to heat 28.0 g of iron...Ch. 7.10 - Prob. 7.30PCh. 7.10 - Prob. 7.31PCh. 7.10 - If the initial temperature of 120. g of ethanol is...Ch. 7.11 - Use the heat of fusion of water from Sample...Ch. 7.11 - Answer the following questions about water, which...Ch. 7.11 - Prob. 7.35PCh. 7.12 - Answer the following questions about the graph...Ch. 7.12 - How much energy (in calories) is released when...Ch. 7.12 - How much energy (in calories) is required to melt...Ch. 7 - Prob. 7.39PCh. 7 - Prob. 7.40PCh. 7 - Prob. 7.41PCh. 7 - The compressed air tank of a scuba diver reads...Ch. 7 - Assume that each of the following samples is at...Ch. 7 - Use the diagrams in Problem 7.43 to answer the...Ch. 7 - Prob. 7.45PCh. 7 - Prob. 7.46PCh. 7 - Prob. 7.47PCh. 7 - Prob. 7.48PCh. 7 - Prob. 7.49PCh. 7 - Prob. 7.50PCh. 7 - Prob. 7.51PCh. 7 - Prob. 7.52PCh. 7 - Prob. 7.53PCh. 7 - If someone takes a breath and the lungs expand...Ch. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - Prob. 7.57PCh. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Prob. 7.60PCh. 7 - Prob. 7.61PCh. 7 - Prob. 7.62PCh. 7 - Prob. 7.63PCh. 7 - Prob. 7.64PCh. 7 - Prob. 7.65PCh. 7 - Prob. 7.66PCh. 7 - Prob. 7.67PCh. 7 - Prob. 7.68PCh. 7 - Prob. 7.69PCh. 7 - Prob. 7.70PCh. 7 - Prob. 7.71PCh. 7 - Prob. 7.72PCh. 7 - Prob. 7.73PCh. 7 - Prob. 7.74PCh. 7 - Prob. 7.75PCh. 7 - Prob. 7.76PCh. 7 - Prob. 7.77PCh. 7 - Prob. 7.78PCh. 7 - Prob. 7.79PCh. 7 - Prob. 7.80PCh. 7 - Prob. 7.81PCh. 7 - Prob. 7.82PCh. 7 - Prob. 7.83PCh. 7 - Prob. 7.84PCh. 7 - Which molecules are capable of intermolecular...Ch. 7 - Prob. 7.86PCh. 7 - Prob. 7.87PCh. 7 - Explain why the boiling point of A is higher than...Ch. 7 - Prob. 7.89PCh. 7 - Prob. 7.90PCh. 7 - Prob. 7.91PCh. 7 - Prob. 7.92PCh. 7 - Prob. 7.93PCh. 7 - Prob. 7.94PCh. 7 - Prob. 7.95PCh. 7 - Prob. 7.96PCh. 7 - Prob. 7.97PCh. 7 - Prob. 7.98PCh. 7 - Prob. 7.99PCh. 7 - How many calories of heat are needed to increase...Ch. 7 - Prob. 7.101PCh. 7 - If it takes 37.0 cal of heat to raise the...Ch. 7 - Prob. 7.103PCh. 7 - What phase change is shown in the accompanying...Ch. 7 - Prob. 7.105PCh. 7 - Which process requires more energy, melting 250 g...Ch. 7 - Consider the cooling curve drawn below a. Which...Ch. 7 - Prob. 7.108PCh. 7 - Draw the heating curve that is observed when...Ch. 7 - Prob. 7.110PCh. 7 - Use the following values to answer each part. The...Ch. 7 - Prob. 7.112PCh. 7 - If you pack a bag of potato chips for a snack on a...Ch. 7 - Prob. 7.114PCh. 7 - Prob. 7.115PCh. 7 - Prob. 7.116PCh. 7 - Prob. 7.117PCh. 7 - If a scuba diver inhales 0.50 L of air at a depth...Ch. 7 - Prob. 7.119CPCh. 7 - As we learned in Chapter 5, an automobile airbag...
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Similar questions
- Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**arrow_forward11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5arrow_forwardО δα HO- H -Br δα HO-- + + -Br [B] 8+ HO- -Br δα नarrow_forward
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