EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Textbook Question
Chapter 7, Problem 7.43P
Assume that each of the following samples is at the same temperature. (a) Which diagram represents the sample at the highest pressure? (b) Which diagram represents the sample at the lowest pressure?
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4. C6H100
5
I peak
3
2
PPM
Integration values: 1.79ppm (2), 4.43ppm (1.33)
Ipeak
None
3. Consider the compounds below and determine if they are aromatic, antiaromatic, or
non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I
electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly
drawn and you should be able to tell that the bonding electrons and lone pair electrons
should reside in which hybridized atomic orbital 2. You should consider ring strain-
flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti-
aromaticity)
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Aromaticity
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Aromatic Aromatic Aromatic Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic TT
electrons
Me
H
Me
Aromaticity
(Circle)
Aromatic Aromatic Aromatic
Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic πT
electrons
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Chapter 7 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 7.1 - Prob. 7.1PCh. 7.2 - Convert each pressure unit to the indicated unit....Ch. 7.3 - Prob. 7.3PCh. 7.3 - Prob. 7.4PCh. 7.3 - Prob. 7.5PCh. 7.3 - Prob. 7.6PCh. 7.3 - Prob. 7.7PCh. 7.3 - Prob. 7.8PCh. 7.3 - The pressure inside a 1.0-L balloon at 25C was 750...Ch. 7.4 - A sample of nitrogen gas contains 5.0 mol in a...
Ch. 7.4 - Prob. 7.11PCh. 7.4 - Prob. 7.12PCh. 7.5 - Prob. 7.13PCh. 7.5 - Prob. 7.14PCh. 7.6 - CO2 was added to a cylinder containing 2.5 atm of...Ch. 7.6 - Prob. 7.16PCh. 7.6 - Prob. 7.17PCh. 7.7 - Prob. 7.18PCh. 7.7 - Prob. 7.19PCh. 7.7 - Prob. 7.20PCh. 7.7 - Which species in each pair has stronger...Ch. 7.7 - Prob. 7.22PCh. 7.7 - Prob. 7.23PCh. 7.8 - Prob. 7.24PCh. 7.8 - Would you predict the surface tension of gasoline,...Ch. 7.9 - Prob. 7.26PCh. 7.10 - Prob. 7.27PCh. 7.10 - The human body is composed of about 70% water. How...Ch. 7.10 - How much energy is required to heat 28.0 g of iron...Ch. 7.10 - Prob. 7.30PCh. 7.10 - Prob. 7.31PCh. 7.10 - If the initial temperature of 120. g of ethanol is...Ch. 7.11 - Use the heat of fusion of water from Sample...Ch. 7.11 - Answer the following questions about water, which...Ch. 7.11 - Prob. 7.35PCh. 7.12 - Answer the following questions about the graph...Ch. 7.12 - How much energy (in calories) is released when...Ch. 7.12 - How much energy (in calories) is required to melt...Ch. 7 - Prob. 7.39PCh. 7 - Prob. 7.40PCh. 7 - Prob. 7.41PCh. 7 - The compressed air tank of a scuba diver reads...Ch. 7 - Assume that each of the following samples is at...Ch. 7 - Use the diagrams in Problem 7.43 to answer the...Ch. 7 - Prob. 7.45PCh. 7 - Prob. 7.46PCh. 7 - Prob. 7.47PCh. 7 - Prob. 7.48PCh. 7 - Prob. 7.49PCh. 7 - Prob. 7.50PCh. 7 - Prob. 7.51PCh. 7 - Prob. 7.52PCh. 7 - Prob. 7.53PCh. 7 - If someone takes a breath and the lungs expand...Ch. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - Prob. 7.57PCh. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Prob. 7.60PCh. 7 - Prob. 7.61PCh. 7 - Prob. 7.62PCh. 7 - Prob. 7.63PCh. 7 - Prob. 7.64PCh. 7 - Prob. 7.65PCh. 7 - Prob. 7.66PCh. 7 - Prob. 7.67PCh. 7 - Prob. 7.68PCh. 7 - Prob. 7.69PCh. 7 - Prob. 7.70PCh. 7 - Prob. 7.71PCh. 7 - Prob. 7.72PCh. 7 - Prob. 7.73PCh. 7 - Prob. 7.74PCh. 7 - Prob. 7.75PCh. 7 - Prob. 7.76PCh. 7 - Prob. 7.77PCh. 7 - Prob. 7.78PCh. 7 - Prob. 7.79PCh. 7 - Prob. 7.80PCh. 7 - Prob. 7.81PCh. 7 - Prob. 7.82PCh. 7 - Prob. 7.83PCh. 7 - Prob. 7.84PCh. 7 - Which molecules are capable of intermolecular...Ch. 7 - Prob. 7.86PCh. 7 - Prob. 7.87PCh. 7 - Explain why the boiling point of A is higher than...Ch. 7 - Prob. 7.89PCh. 7 - Prob. 7.90PCh. 7 - Prob. 7.91PCh. 7 - Prob. 7.92PCh. 7 - Prob. 7.93PCh. 7 - Prob. 7.94PCh. 7 - Prob. 7.95PCh. 7 - Prob. 7.96PCh. 7 - Prob. 7.97PCh. 7 - Prob. 7.98PCh. 7 - Prob. 7.99PCh. 7 - How many calories of heat are needed to increase...Ch. 7 - Prob. 7.101PCh. 7 - If it takes 37.0 cal of heat to raise the...Ch. 7 - Prob. 7.103PCh. 7 - What phase change is shown in the accompanying...Ch. 7 - Prob. 7.105PCh. 7 - Which process requires more energy, melting 250 g...Ch. 7 - Consider the cooling curve drawn below a. Which...Ch. 7 - Prob. 7.108PCh. 7 - Draw the heating curve that is observed when...Ch. 7 - Prob. 7.110PCh. 7 - Use the following values to answer each part. The...Ch. 7 - Prob. 7.112PCh. 7 - If you pack a bag of potato chips for a snack on a...Ch. 7 - Prob. 7.114PCh. 7 - Prob. 7.115PCh. 7 - Prob. 7.116PCh. 7 - Prob. 7.117PCh. 7 - If a scuba diver inhales 0.50 L of air at a depth...Ch. 7 - Prob. 7.119CPCh. 7 - As we learned in Chapter 5, an automobile airbag...
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