ELEM.PRIN.OF CHEM.PROCESS-ACCESS
ELEM.PRIN.OF CHEM.PROCESS-ACCESS
4th Edition
ISBN: 9781119099918
Author: FELDER
Publisher: WILEY
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Chapter 7, Problem 7.15P
Interpretation Introduction

(a)

Interpretation:

The reference state that is used to generate the listed specific internal energies is to be stated.

Concept introduction:

The reference states are considered as the stable and pure states of the chemical substances. The change in specific internal energy and change in specific enthalpy is represented by ΔU and ΔH respectively. The relationship between ΔU and ΔH is shown below,

ΔH=ΔU+PΔV

Interpretation Introduction

(b)

Interpretation:

The values of ΔU(kJ/mol) and ΔH(kJ/mol) for a process in which bromine vapor condensed at 300K and constant pressure are to be calculated. The value of ΔH(kJ) for 5.00mol of bromine undergoing the process is to be calculated.

Concept introduction:

The change in specific internal energy and change in specific enthalpy is represented by ΔU and ΔH respectively. The relationship between ΔU and ΔH is shown below,

ΔH=ΔU+PΔV

Interpretation Introduction

(c)

Interpretation:

The heat that must be transferred to the gas to achieve the desired temperature increase by assuming that U is independent of pressure is to be calculated.

Concept introduction:

The change in specific internal energy and change in specific enthalpy is represented by ΔU and ΔH respectively. The relationship between ΔU and ΔH is shown below,

ΔH=ΔU+PΔV

The equation for energy balance when there is only one output and one input stream is shown below.

Q+Ws=ΔU+ΔEk+ΔEp

Interpretation Introduction

(d)

Interpretation:

The two reasons for the requirement of more heat than the amount calculated in part (c) is to be stated.

Concept introduction:

The reference states are considered as the stable and pure states of the chemical substances. The change in specific internal energy and change in specific enthalpy is represented by ΔU and ΔH respectively. The relationship between ΔU and ΔH is shown below,

ΔH=ΔU+PΔV

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Chapter 7 Solutions

ELEM.PRIN.OF CHEM.PROCESS-ACCESS

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