EBK GET READY FOR ORGANIC CHEMISTRY
EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 9780321830555
Author: KARTY
Publisher: VST
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Chapter 7, Problem 7.10P
Interpretation Introduction

Interpretation:

The SN2 step that would occur between C6H5CH2I and CH3SNa is to be drawn.

Concept introduction:

In SN2 step, a molecular species called substrate undergoes substitution in which one atom or group of atoms is replaced by another. Nucleophile is the species that reacts with the substrate, and it has an atom that bears partial or full negative charge. A nucleophile is attracted by and forms a bond to the nonhydrogen atom that bears a partial or full positive charge. A nucleophile forms a bond to the substrate, and at the same time, a bond to the leaving group, i.e., the group that is displaced, is broken. Leaving groups are typically conjugate bases of strong acids. The nucleophiles are electron rich as they bear negative charge; an atom of the substrate bears positive charge and is electron poor. In SN2 step, a curved arrow is drawn from the lone pair of the electron rich atom of the nuclepohile to the electron poor atom of the substrate. A second curved arrow is drawn to indicate the breaking of the bond.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv
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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Chapter 7 Solutions

EBK GET READY FOR ORGANIC CHEMISTRY

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