EBK GET READY FOR ORGANIC CHEMISTRY
EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 9780321830555
Author: KARTY
Publisher: VST
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Chapter 7, Problem 7.2P
Interpretation Introduction

Interpretation:

The electron-rich and electron-poor sites of the reactants are to be identified, and the curved arrow that represents the flow of electrons from an electron-rich site to an electron-poor site is to be drawn for the proton transfer between trimethylamine ((CH3)3N) and water (H2O).

Concept introduction:

Electron poor atoms or molecules have fewer electrons than the number of electrons required for maximum stability. In a proton transfer reaction, a proton is transferred from a Bronsted Lowry acid (proton donor) to a Bronsted–Lowry base (proton acceptor). In an elementary step, electrons tend to flow from an electron-rich site to an electron-poor site. The curved arrow notation shows the movement of valence electrons.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv
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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

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EBK GET READY FOR ORGANIC CHEMISTRY

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