The carbocation intermediate and the type of carbocation present in the given substrates should be identified. Concept introduction: Carbocation intermediate : It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects. Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized. The order of the stability of carbocation,

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Answer 1

Question

Chapter 7, Problem 51PP

(a)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(b)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(c)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(d)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

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Answer 2

Question

Chapter 7, Problem 51PP

(a)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(b)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(c)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(d)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

Expert Solution & Answer

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Answer 3

Question

Chapter 7, Problem 51PP

(a)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(b)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(c)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(d)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

Expert Solution & Answer

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Answer 4

Question

Chapter 7, Problem 51PP

(a)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(b)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(c)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(d)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

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Answer 5

Chapter 7, Problem 51PP

(a)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(b)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(c)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

(d)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

Answer 6

Chapter 7, Problem 51PP

(a)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

Answer 7

Chapter 7, Problem 51PP

(a)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

Answer 8

(b)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

Answer 9

(b)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

Answer 10

(c)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

Answer 11

(c)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

Answer 12

(d)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

Answer 13

(d)

Interpretation Introduction

Interpretation: The carbocation intermediate and the type of carbocation present in the given substrates should be identified.

Concept introduction:

Carbocation intermediate: It is a fragment from the molecule in which the carbon atom bears a positive charge on it. The stability of the carbocation present in a molecule depends on the neighboring atom present in the molecule with respect to its resonance effects.

Resonance: The delocalization of pi electrons or lone pair of electrons present in p orbital within a molecule. The molecule is said to be more stable if it is resonance stabilized.

The order of the stability of carbocation,

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 7.2 - Prob. 1CC Ch. 7.3 - Prob. 1LTS Ch. 7.3 - Prob. 2PTS Ch. 7.3 - Prob. 3PTS Ch. 7.3 - Prob. 4ATS Ch. 7.3 - Prob. 5ATS Ch. 7.4 - Prob. 6CC Ch. 7.4 - Prob. 2LTS Ch. 7.4 - Prob. 7PTS Ch. 7.4 - Prob. 8ATS

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