EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781118930144
Author: Willard
Publisher: JOHN WILEY+SONS INC.
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Chapter 7, Problem 44PE
Interpretation Introduction
Interpretation:
The empirical formula and molecular formula of a dixanthogen has to be given.
Concept Introduction:
Empirical Formula:
The empirical formula of a compound is the simplest whole number ratio of each type of atom in a compound. It can be the same as the compound’s molecular formula but not always. An empirical formula can be calculated from information about the mass of each element in a compound or from the percentage composition.
The steps for determining the empirical formula of a compound as follows:
- Obtain the mass of each element present in grams.
- Determine the number of moles of each atom present.
- Divide the number of moles of each element by the smallest number of moles.
- Convert the numbers to whole numbers. The set of whole numbers are the subscripts in the empirical formula.
Molecular formula:
The molecular formula is the expression of the number of atoms of each element in one molecule of a compound if the molar mass value is known the molecular formula is calculated by the empirical formula.
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1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly
where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial
credit will be given. Note: You may need to draw in lone pairs before drawing the arrows.
A.
B.
H-Br
人
C
Θ
CI
H
Cl
Θ
+
Br
O
Chapter 7 Solutions
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
Ch. 7.1 - Prob. 7.1PCh. 7.1 - Prob. 7.2PCh. 7.1 - Prob. 7.3PCh. 7.2 - Prob. 7.4PCh. 7.2 - Prob. 7.5PCh. 7.2 - Prob. 7.6PCh. 7.3 - Prob. 7.7PCh. 7.3 - Prob. 7.8PCh. 7.3 - Prob. 7.9PCh. 7.4 - Prob. 7.10P
Ch. 7.4 - Prob. 7.11PCh. 7.5 - Prob. 7.12PCh. 7 - Prob. 1RQCh. 7 - Prob. 2RQCh. 7 - Prob. 3RQCh. 7 - Prob. 4RQCh. 7 - Prob. 5RQCh. 7 - Prob. 6RQCh. 7 - Prob. 7RQCh. 7 - Prob. 8RQCh. 7 - Prob. 9RQCh. 7 - Prob. 10RQCh. 7 - Prob. 11RQCh. 7 - Prob. 12RQCh. 7 - Prob. 13RQCh. 7 - Prob. 14RQCh. 7 - Prob. 15RQCh. 7 - Prob. 17RQCh. 7 - Prob. 18RQCh. 7 - Prob. 19RQCh. 7 - Prob. 1PECh. 7 - Prob. 2PECh. 7 - Prob. 3PECh. 7 - Prob. 4PECh. 7 - Prob. 5PECh. 7 - Prob. 6PECh. 7 - Prob. 7PECh. 7 - Prob. 8PECh. 7 - Prob. 9PECh. 7 - Prob. 10PECh. 7 - Prob. 11PECh. 7 - Prob. 12PECh. 7 - Prob. 13PECh. 7 - Prob. 14PECh. 7 - Prob. 15PECh. 7 - Prob. 16PECh. 7 - Prob. 17PECh. 7 - Prob. 18PECh. 7 - Prob. 19PECh. 7 - Prob. 20PECh. 7 - Prob. 21PECh. 7 - Prob. 22PECh. 7 - Prob. 25PECh. 7 - Prob. 26PECh. 7 - Prob. 27PECh. 7 - Prob. 28PECh. 7 - Prob. 29PECh. 7 - Prob. 30PECh. 7 - Prob. 31PECh. 7 - Prob. 32PECh. 7 - Prob. 33PECh. 7 - Prob. 34PECh. 7 - Prob. 35PECh. 7 - Prob. 36PECh. 7 - Prob. 37PECh. 7 - Prob. 38PECh. 7 - Prob. 39PECh. 7 - Prob. 40PECh. 7 - Prob. 41PECh. 7 - Prob. 42PECh. 7 - Prob. 43PECh. 7 - Prob. 44PECh. 7 - Prob. 45PECh. 7 - Prob. 46PECh. 7 - Prob. 47PECh. 7 - Prob. 48PECh. 7 - Prob. 49PECh. 7 - Prob. 50PECh. 7 - Prob. 51PECh. 7 - Prob. 52PECh. 7 - Prob. 53AECh. 7 - Prob. 54AECh. 7 - Prob. 55AECh. 7 - Prob. 56AECh. 7 - Prob. 57AECh. 7 - Prob. 58AECh. 7 - Prob. 59AECh. 7 - Prob. 60AECh. 7 - Prob. 61AECh. 7 - Prob. 62AECh. 7 - Prob. 63AECh. 7 - Prob. 64AECh. 7 - Prob. 65AECh. 7 - Prob. 66AECh. 7 - Prob. 67AECh. 7 - Prob. 68AECh. 7 - Prob. 69AECh. 7 - Prob. 70AECh. 7 - Prob. 71AECh. 7 - Prob. 72AECh. 7 - Prob. 73AECh. 7 - Prob. 74AECh. 7 - Prob. 75AECh. 7 - Prob. 76AECh. 7 - Prob. 77AECh. 7 - Prob. 78AECh. 7 - Prob. 79AECh. 7 - Prob. 80AECh. 7 - Prob. 81AECh. 7 - Prob. 82AECh. 7 - Prob. 83AECh. 7 - Prob. 84AECh. 7 - Prob. 88AECh. 7 - Prob. 89CECh. 7 - Prob. 90CE
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