EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781118930144
Author: Willard
Publisher: JOHN WILEY+SONS INC.
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Chapter 7, Problem 3RQ
Interpretation Introduction
Interpretation:
An element with higher
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Identifying electron-donating and
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
NH2
○ donating
NO2
Explanation
Check
withdrawing
no inductive effects
Resonance Effects
Overall Electron-Density
○ donating
O withdrawing
O no resonance effects
O donating
O withdrawing
O donating
withdrawing
O no inductive effects
Ono resonance effects
O electron-rich
electron-deficient
O similar to benzene
O electron-rich
O electron-deficient
O similar to benzene
olo
18
Ar
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
Х
(Choose one)
OH
(Choose one)
OCH3
(Choose one)
OH
(Choose one)
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Assign R or S to all the chiral centers in each compound drawn below
porat
bg
9
Br
Br
Chapter 7 Solutions
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
Ch. 7.1 - Prob. 7.1PCh. 7.1 - Prob. 7.2PCh. 7.1 - Prob. 7.3PCh. 7.2 - Prob. 7.4PCh. 7.2 - Prob. 7.5PCh. 7.2 - Prob. 7.6PCh. 7.3 - Prob. 7.7PCh. 7.3 - Prob. 7.8PCh. 7.3 - Prob. 7.9PCh. 7.4 - Prob. 7.10P
Ch. 7.4 - Prob. 7.11PCh. 7.5 - Prob. 7.12PCh. 7 - Prob. 1RQCh. 7 - Prob. 2RQCh. 7 - Prob. 3RQCh. 7 - Prob. 4RQCh. 7 - Prob. 5RQCh. 7 - Prob. 6RQCh. 7 - Prob. 7RQCh. 7 - Prob. 8RQCh. 7 - Prob. 9RQCh. 7 - Prob. 10RQCh. 7 - Prob. 11RQCh. 7 - Prob. 12RQCh. 7 - Prob. 13RQCh. 7 - Prob. 14RQCh. 7 - Prob. 15RQCh. 7 - Prob. 17RQCh. 7 - Prob. 18RQCh. 7 - Prob. 19RQCh. 7 - Prob. 1PECh. 7 - Prob. 2PECh. 7 - Prob. 3PECh. 7 - Prob. 4PECh. 7 - Prob. 5PECh. 7 - Prob. 6PECh. 7 - Prob. 7PECh. 7 - Prob. 8PECh. 7 - Prob. 9PECh. 7 - Prob. 10PECh. 7 - Prob. 11PECh. 7 - Prob. 12PECh. 7 - Prob. 13PECh. 7 - Prob. 14PECh. 7 - Prob. 15PECh. 7 - Prob. 16PECh. 7 - Prob. 17PECh. 7 - Prob. 18PECh. 7 - Prob. 19PECh. 7 - Prob. 20PECh. 7 - Prob. 21PECh. 7 - Prob. 22PECh. 7 - Prob. 25PECh. 7 - Prob. 26PECh. 7 - Prob. 27PECh. 7 - Prob. 28PECh. 7 - Prob. 29PECh. 7 - Prob. 30PECh. 7 - Prob. 31PECh. 7 - Prob. 32PECh. 7 - Prob. 33PECh. 7 - Prob. 34PECh. 7 - Prob. 35PECh. 7 - Prob. 36PECh. 7 - Prob. 37PECh. 7 - Prob. 38PECh. 7 - Prob. 39PECh. 7 - Prob. 40PECh. 7 - Prob. 41PECh. 7 - Prob. 42PECh. 7 - Prob. 43PECh. 7 - Prob. 44PECh. 7 - Prob. 45PECh. 7 - Prob. 46PECh. 7 - Prob. 47PECh. 7 - Prob. 48PECh. 7 - Prob. 49PECh. 7 - Prob. 50PECh. 7 - Prob. 51PECh. 7 - Prob. 52PECh. 7 - Prob. 53AECh. 7 - Prob. 54AECh. 7 - Prob. 55AECh. 7 - Prob. 56AECh. 7 - Prob. 57AECh. 7 - Prob. 58AECh. 7 - Prob. 59AECh. 7 - Prob. 60AECh. 7 - Prob. 61AECh. 7 - Prob. 62AECh. 7 - Prob. 63AECh. 7 - Prob. 64AECh. 7 - Prob. 65AECh. 7 - Prob. 66AECh. 7 - Prob. 67AECh. 7 - Prob. 68AECh. 7 - Prob. 69AECh. 7 - Prob. 70AECh. 7 - Prob. 71AECh. 7 - Prob. 72AECh. 7 - Prob. 73AECh. 7 - Prob. 74AECh. 7 - Prob. 75AECh. 7 - Prob. 76AECh. 7 - Prob. 77AECh. 7 - Prob. 78AECh. 7 - Prob. 79AECh. 7 - Prob. 80AECh. 7 - Prob. 81AECh. 7 - Prob. 82AECh. 7 - Prob. 83AECh. 7 - Prob. 84AECh. 7 - Prob. 88AECh. 7 - Prob. 89CECh. 7 - Prob. 90CE
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- (c) (4pts) Mechanism: heat (E1) CH3OH + 1.5pts each _E1 _ (1pt) Br CH3OH (d) (4pts) Mechanism: SN1 (1pt) (e) (3pts) 1111 I H 10 Ill!! H LDA THF (solvent) Mechanism: E2 (1pt) NC (f) Bri!!!!! CH3 NaCN (3pts) acetone Mechanism: SN2 (1pt) (SN1) -OCH3 OCH3 1.5pts each 2pts for either product 1pt if incorrect stereochemistry H Br (g) “,、 (3pts) H CH3OH +21 Mechanism: SN2 (1pt) H CH3 2pts 1pt if incorrect stereochemistry H 2pts 1pt if incorrect stereochemistryarrow_forwardA mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixturearrow_forwardQ5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R Harrow_forward
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