Problem 1E: Calculate the quantity of heat, in kilojoules, (a) required to raise the temperature of 9.25 L of... Problem 2E: Calculate the final temperature that results when (a)a 12.6 g sample of waterat 22.9C absorbs 875 J... Problem 3E: Refer to Example 7-2. The experiment is repeated several different metals substituting for the lead.... Problem 4E: A 75.0 g piece of Ag metal is heated to 80.0C and dropped into 50.0 g of water at 23.2 C. The final... Problem 5E: A 465 g chunk of iron is removed from an oven and plunged into 375 g water in an insulated... Problem 6E: A piece of stainless steel (C2=0.50Jg-1C-1) is transferred from an oven at 201C into 1500mL of water... Problem 7E: A 1.00 kg sample of magnesium at 40.0C is added to 1.00 L of water maintained at 20.0C in an... Problem 8E: Brass has a density of 8.40 g/cm2 and a specific heat capacity of 0.385Jg-1C-1 . A 15.2cm2 piece of... Problem 9E: A 74.8 g sample of copper at 143.2C is added to an insulated vessel containing 165 mL of glycerol,... Problem 10E: A 69.0 g sample of gold at 127.1C is added to an insulated vessel containing 543.0 mL of water at... Problem 11E: In the form of heat, 6052 J of energy is transferred to a 1.0 L sample of air (d=1.204mg/cm2) at... Problem 12E: What is the final temperature (in C) of 1.24 g of water with an initial temperature of 200C after... Problem 13E: How much heat, in kilojoules, is associated with one of 283 kg of slaked lime, Ca(OH)2?... Problem 14E: The standard enthalpy of reaction for the combustion of octane is H0=5.48103kJ/molC5H15(I) . How... Problem 15E: How much heat, in kilojoules, is evolved the compete combustion of (a) 1.325gC4H10(g) at 25C and 1... Problem 16E: Upon complete combustion the indicated substances evolve the given quantities of heat. Write a... Problem 17E: The combustion of methane gas, the principal constituent of natural gas, is represented by the... Problem 18E: Refer to the Integrative Example. What volume of the synthesis gas, measured at STP and burned an... Problem 19E: The combustion of hydrogen-oxygen mixtures is used to very high (approximately 2500 C) needed for... Problem 20E: Thermite mixtures are used for certain types of welding, and the thermite reaction is highly... Problem 21E: A 0.205 g pellet of potassium hydroxide, KOH, is added to 55.9 g water in a Styrofoam coffee cup.... Problem 22E: The heat of solution of Kl(s) in water is +20.3kJ/molKI. If a Quantity of KI is added to sufficient... Problem 23E: You are planning lecture demonstration to illustrate an endothermic process. You want to lower the... Problem 24E: Care must be taken in preparing solutions of solutes that liberate heat on dissolving. The heat of... Problem 25E: Refer to Example 7-4. The product of the neutralization is 0.500 M NaCl. For this solution, assume a... Problem 26E Problem 27E Problem 28E Problem 29E: What mass of ice can be meted the same quantity of heat as required to raise the temperature of 3.50... Problem 30E: What will be the final temperature of the water in an insulated as the result of passing 5.00 g of... Problem 31E: A 125 g stainless steel ball bearings (C0=0.50Jg1C1) at 525C is dropped into 75.0 mL of water at... Problem 32E Problem 33E: The enthalpy of sublimation (solid gas) for dry ice (i.e., CO2) is vaH0=5.71kJ/kg at -78.5 C. If... Problem 34E: The enthalpy of vaporization forN2 (I)is 5.56 kJ/mol. How much heat (in J) is required to produce... Problem 35E: A sample gives off 5228 cal when burned in a bomb calorimeter The temperature of the calorimeter... Problem 36E: The following substances undergo complete combustion in a bomb calorimeter. The calorimeter assembly... Problem 37E: A bomb calorimetry experiment is performed withxylose, C3H10O2(s) as the combustible substance. The... Problem 38E: A coffee-cup calorimeter contains 100.0 mL of 0.300 M HCIat 20.3 C. When 1.82 g Zn(s) is added, the... Problem 39E: A 0.75 g sample of KCI is added to 350 g H2O in a Styrofoam cup and stirred it dissolves. The... Problem 40E: The heat of solution of potassium acetate in water is -15.3 kJ/mol KCH2COO. What will be the final... Problem 41E Problem 42E: Salicylic acid, C7H5O2 , has been suggested as a calorimetric standard. Its heat of combustion is... Problem 43E: Refer to Example 7-3. Based on the heat of combustion of sucrose established in the example, what... Problem 44E: A 1.397 g sample of thymol, C10H14O(s) (a preservative and a mold and mildew preventative), is... Problem 45E: A g of NaCI is added to a Styrofoam cup of water, and the change in water temperature is 5.0 C. The... Problem 46E: can determine purity of solid materials by using calorimetry. A gold ring (for pure gold, specific... Problem 47E: Calculate the quantity of work associated with a 3.5 L expansion of a gas (V) against a pressure of... Problem 48E: Calculate the quantity of work, in joules, associated with the compression of a gas from 5.62 L to... Problem 49E: A 1.00 g sample of Ne(g) at 1 atm pressure and 27C is allowed to expand into an evacuated vessel of... Problem 50E: Compressed air in aerosol cans is used to free electronic equipment of dust. Does the air do any... Problem 51E: In each of the following processes, is any work done when the reaction is carried out at constant... Problem 52E: In each of the following processes, any work done when the reaction is carried out at constant... Problem 53E: If 325 J of work is done by a system at a pressure of 1.0 atm and 298 K, what is the change in the... Problem 54E: A movable piston a cylinder holding 5.0 L N2(g) is used to lift a 2.41 kg object to a height of 26... Problem 55E: What is the change in internal energy of a system if the system (a) absorbs 58 J of heat and does 58... Problem 56E: Whet the change in internal energy of e system if the surroundings (a) transfer 235 of heat and 128... Problem 57E: The internal energy of a fixed quantity of an ideal gas depends only on its temperature. A sample of... Problem 58E Problem 59E Problem 60E Problem 61E: There are other forms of work besides PV work. For example, electrical work is defined as the... Problem 62E: Another form of work is extension, defined as the tension x change in length, w=fI. A piece of DNA... Problem 63E: Only one of the following quantities is equal to the heat of a chemical reaction, regardless of how... Problem 64E: Determine whether H is equal to, greater than, or less than U for the following processes. Keep in... Problem 65E: The heat of combustion of propan-2-ol at 298.15 K, determined in a bomb calorimeter, is -33.41 kJ/g.... Problem 66E Problem 67E: The standard enthalpy of formation of NH2(g) is -46.11 kJ/mol. What is rH for the following... Problem 68E: Use Hess's law to determine rH for the reaction CO(g)+12O2(g)CO2(g) , given that... Problem 69E: Use Hess's law to determine rH for the reaction 2 HÅg) given that H2(g)+12O2(g)H2O(I)... Problem 70E: Given the following information: 12N2(g)+32H2(g)NH3(g)rH1 NH3(g)+54O2(g)NO(g)+32H2O(I)rH2... Problem 71E: For the reaction C2H4(g)+CIz(g)C2H4CI2(I) , determine rH, given that... Problem 72E: Determine rH for this reaction from the data below. N2H4(I)+2H2O2(I)N2(g)+4H2O(I)... Problem 73E: Substitute natural gas (SNG) is a gaseous mature containing CH4(g) that can be used as a fuel. One... Problem 74E: CCI4 , an important commercial solvent, is prepared by the reaction of CI2(g) with a carbon... Problem 75E: Use Hess's law and the following data CH4(g)+2O2(g)CO2(g)+2H2O(g)rH=802kJmol1... Problem 76E: The standard heats of combustion (rH) of butane-l ,3-diene, C4H5(g) ; butane, C4H10(g) ; and H2(g)... Problem 77E: One glucose molecule, C6H12O6(s) is converted to two lactic acid molecules, CH2CH(OH)COOH(s) during... Problem 78E: The standard of fermentation of glucose to ethanol is C6H12O6(s)2CH3CH2OH(I)+2CO2(g)rH=72kJmol1 Use... Problem 79E: Use standard enthalpies of formation from Table 7.2 and equation (7.22) to the standard enthalpy of... Problem 80E: Use standard enthalpies of formation from Tables 7.2 and 7.3 and equation (7.22) to determine the... Problem 81E: Use the information given here. date from Appendix D, and equation (7.22) to calculate the standard... Problem 82E Problem 83E Problem 84E: Use data from Appendix D to calculate rH for the following reaction at 25C .... Problem 85E Problem 86E: Use data from Table 7.2, together with the factthat rH=3509kJmol1 for the complete combustion of... Problem 87E: Use data from Table 7.2 and rH for re following reaction to determine the standard enthalpy of... Problem 88E: Use data from Table 7.2 and rH for the following reaction to determine the standard enthalpy of... Problem 89E Problem 90E Problem 91E: The decomposition of limestone, CaCO2(s) into quicklime, CaO(s) , and CO2(g) is carried out in a... Problem 92E: Use data from Table 7.2 to calculate the volume of butane, C4H10(g), measured at 24.6C and 756 mmHg,... Problem 93E: Ants release formic acid (HCOOH) when they bite. use the data in Table 7.2 and tie standard enthalpy... Problem 94E Problem 95IAE: A British thermal unit (Btu) is defined as the quantity of heat required to change the temperature... Problem 96IAE: What volume of 18.5C water must be added, together with a1.23 kg piece of iron at 68.5 C, so that... Problem 97IAE: A 7.26 kg shot (as used the sporting event, the shot put) is dropped from the top of building 168 m... Problem 98IAE: An alternative approach to bomb calorimetry is to establish the heat capacity of the calorimeter,... Problem 99IAE Problem 100IAE Problem 101IAE: Determine the missing values of rH in the diagram shown below. Problem 102IAE: A particular natural gas consists, in mole percents, of 830% CH4, 11.2%C2H5 and 5.8% C2H5. A 385 L... Problem 103IAE Problem 104IAE Problem 105IAE: A calorimeter that measures an exothermic heat of reaction by the quantity of ice that can be melted... Problem 106IAE: For the reaction C2H4(g)+3O2(g)2CO2(g)+2H2O(I) rH=1410.9kJmol1 if the H2O were obtained as a gas... Problem 107IAE: Some of the butane, C4H10(g) , in a 200.0 L cylinder at 26.0C is withdrawn and burned at a constant... Problem 108IAE: The metabolism of glucose, C5H12O5 yields CO2(g) and H2O(I) as products. Heat released in the... Problem 109IAE Problem 110IAE: Upon complete combustion, a 1.00 L sample (at STP) of a natural gas gives off 43.6 kJ of heat. If... Problem 111IAE Problem 112IAE: Refer to the discussion of the gasification of coal (page 283), and show that some of the heat... Problem 113IAE: A 1.103 g sample of a gaseous carbon-hydrogen-oxygen compound that occupies a volume of 582 mL at... Problem 114IAE: Several factors are involved in determining the cooking times required for foods in a microwave... Problem 115IAE Problem 116IAE Problem 117IAE Problem 118IAE: In the Are You Wondering 7-1 box, the temperature variation of enthalpy is discussed, and the... Problem 119IAE Problem 120IAE Problem 121IAE: Cetane, C15H34, is a typical petrodiesel with a standard enthalpy of combustion of 10,699.1kJmol1 .... Problem 122IAE: Carbon dioxide emissions have been implicated as a major factor in climate change. Which of the... Problem 123FP Problem 124FP Problem 125FP: We can use the heat liberated by a neutralization reaction as a means of establishing the... Problem 126FP: In a student experiment to confirm Hess's law, the reaction NH3(concdaq)+HCI(aq)NH4CI(aq) was... Problem 127FP Problem 128FP: Refer to Example 7-5 dealing with the work done by 0.100 mol He at 298 K in expanding in a single... Problem 129FP: Look up the specific heat capacity of several elements, and plot the products of the specific heat... Problem 130SAE: In your own words, define or explain the following terms or symbols: (a)rH;(b)PV;(c)rH; (d) standard... Problem 131SAE Problem 132SAE: Explain the important distinctions between each pair of terms: (a) system and surroundings: (b) heat... Problem 133SAE: The temperature increase of 225 mL of water at 25C contained in a Styrofoam cup is noted when a 125... Problem 134SAE: A plausible final temperature when 75.0 ml of water at 80.0C is added to 1000 ml of water at 20C is... Problem 135SAE: U= 100 J for a system that gives off 100 J of heat and (a) does no work; (b) does 200 J of work; (c)... Problem 136SAE Problem 137SAE: The standard molar enthalpy of formation of CO2(g) is equal to (a) 0; (b) the standard molar heat of... Problem 138SAE: Write the formation reaction for each of the following compounds:... Problem 139SAE: Compute rH for the following reactions. The value of rH in kJ mol-1 is given for each substance... Problem 140SAE: When dissolved in water, 1.00 mol LiCI produces 37.12 kJ of heat. What is the final temperature in... Problem 141SAE Problem 142SAE Problem 143SAE Problem 144SAE: A 1.22 kg piece of iron at 126.5C is dropped into 981 g water at 22.1 C. The temperature rises to... Problem 145SAE Problem 146SAE: The standard molar heats of combustion of C(graphite) and CO(g) are -393.5 and -283 kJ/mol,... Problem 147SAE Problem 148SAE Problem 149SAE Problem 150SAE Problem 151SAE Problem 152SAE Problem 153SAE Problem 154SAE format_list_bulleted