INTRODUCTORY CHEMISTRY-W/SEL.SOLN.MAN.
6th Edition
ISBN: 9780134845609
Author: Tro
Publisher: PEARSON
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Chapter 7, Problem 1E
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z)
is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra
are provided. Draw the structure of the product as the resonance contributor lacking any formal charges.
13C NMR
DEPT 90
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120
80
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DEPT 135
T
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Draw the unknown amide.
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Chapter 7 Solutions
INTRODUCTORY CHEMISTRY-W/SEL.SOLN.MAN.
Ch. 7 - Which process is a chemical reaction? a. Gasoline...Ch. 7 - How many oxygen atoms are on the reactant side of...Ch. 7 - Q3. What is the coefficient for hydrogen in the...Ch. 7 - Q4. Determine the correct set of coefficients to...Ch. 7 - Which compound is soluble in water? a. Fe(OH)2 b....Ch. 7 - Name the precipitate that forms (if any) when...Ch. 7 - Q7. Which set of reactants forms a solid...Ch. 7 - Q8. What is the net ionic equation for the...Ch. 7 - Q9. Complete the equation:
a.
b.
c.
d. No...Ch. 7 - Prob. 10SAQ
Ch. 7 - What are the products of the balanced equation for...Ch. 7 - Q12. Precipitation reactions are best classified...Ch. 7 - 1. What is a chemical reaction? List some...Ch. 7 - If you could observe atoms and molecules with the...Ch. 7 - 3. What are the main indications that a chemical...Ch. 7 - What is a chemical equation? Provide an example...Ch. 7 - Prob. 5ECh. 7 - To balance a chemical equation, adjust the...Ch. 7 - 7. Is the chemical equation balanced? Why or why...Ch. 7 - 8. What is an aqueous solution? List two...Ch. 7 - 9. What does it mean if a compound is referred to...Ch. 7 - Explain what happens to an ionic substance when it...Ch. 7 - Do polyatomic ions dissociate when they dissolve...Ch. 7 - What is a strong electrolyte solution?Ch. 7 - 13. What are the solubility rules, and how are...Ch. 7 - What is a precipitation reaction? Provide an...Ch. 7 - 15. Is the precipitate in a precipitation reaction...Ch. 7 - 16. Describe the difference between a molecular...Ch. 7 - What is an acid-base reaction? List an example and...Ch. 7 - Prob. 18ECh. 7 - What is a gas evolution reaction? Give an example.Ch. 7 - What is a redox reaction? Give an example.Ch. 7 - Prob. 21ECh. 7 - Prob. 22ECh. 7 - 23. Explain the difference between a synthesis...Ch. 7 - 24. Explain the difference between a...Ch. 7 - Which observation is consistent with a chemical...Ch. 7 - Which observation is consistent with a chemical...Ch. 7 - Vinegar forms bubbles when it is poured into the...Ch. 7 - When a chemical drain opener is added to a clogged...Ch. 7 - 29. When a commercial hair bleaching mixture is...Ch. 7 - When water is boiled in a pot, it bubbles. Has a...Ch. 7 - For each chemical equation (which may or may not...Ch. 7 - For each chemical equation (which may or may not...Ch. 7 - 33. Consider the unbalanced chemical equation.
A...Ch. 7 - Consider the unbalanced chemical equation....Ch. 7 - Prob. 35ECh. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - 39. When solid sodium is added to liquid water, it...Ch. 7 - When iron rusts, solid iron reacts with gaseous...Ch. 7 - 41. Sulfuric acid in acid rain forms when gaseous...Ch. 7 - Nitric acid in acid rain forms when gaseous...Ch. 7 - Prob. 43ECh. 7 - Prob. 44ECh. 7 - 45. Write a balance chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - 47. Balance each chemical equation.
a.
b.
c.
d....Ch. 7 - Balance each chemical equation. a....Ch. 7 - 49. Balance each chemical equation.
a.
b.
c.
d....Ch. 7 - Balance each chemical equation. a....Ch. 7 - 51. Is each chemical equation correctly balanced?...Ch. 7 - Prob. 52ECh. 7 - Prob. 53ECh. 7 - Propane camping stoves produce heat by the...Ch. 7 - 55. Catalytic converters work to remove nitrogen...Ch. 7 - Prob. 56ECh. 7 - 57. Is each compound soluble or insoluble? For the...Ch. 7 - 58. Is each compound soluble or insoluble? For the...Ch. 7 - 59. Pair each cation on the left with an anion on...Ch. 7 - Pair each cation on the left with an anion on the...Ch. 7 - 61. Move any misplaced compounds to the correct...Ch. 7 - Prob. 62ECh. 7 - Complete and balance each equation. If no reaction...Ch. 7 - Complete and balance each equation. If no reaction...Ch. 7 - Write a molecular equation for the precipitation...Ch. 7 - Write a molecular equation for the precipitation...Ch. 7 - Correct any incorrect equations. If no reaction...Ch. 7 - 68. Correct any incorrect equations. If no...Ch. 7 - 69. Identify the spectator ions in the complete...Ch. 7 - Identify the spectator ions in the complete ionic...Ch. 7 - 71. Write balanced complete ionic and net ionic...Ch. 7 - Write balanced complete ionic and net ionic...Ch. 7 - Mercury(I) ions (Hg22+) can be removed from...Ch. 7 - 74. Lead ions can be removed from solution by...Ch. 7 - Write complete ionic and net ionic equations for...Ch. 7 - 76. Write complete ionic and net ionic equations...Ch. 7 - When a hydrochloric acid solution is combined with...Ch. 7 - 78. A breaker of nitric acid is neutralized with...Ch. 7 - 79. Complete and balance each acid-base...Ch. 7 - Complete and balance each acid-base reaction. a....Ch. 7 - 81. Complete and balance each gas evolution...Ch. 7 - Complete and balance each gas evolution reaction....Ch. 7 - Which reactions are redox reactions? a....Ch. 7 - Which reactions are redox reactions? a....Ch. 7 - Prob. 85ECh. 7 - 86. Complete and balance each combustion...Ch. 7 - 87. Write a balanced chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - 89. Classify each chemical reaction as a...Ch. 7 - 90. Classify each chemical reaction as a...Ch. 7 - Prob. 91ECh. 7 - 92. A main source of soulful oxide pollutants are...Ch. 7 - Predict the products of each reaction and write...Ch. 7 - Predict the products of each reaction and write...Ch. 7 - Prob. 95ECh. 7 - 96. Predict the products of each reaction and...Ch. 7 - Predict the type of reaction (if any) that occurs...Ch. 7 - Prob. 98ECh. 7 - Classify each reaction in as many ways as...Ch. 7 - Classify each reaction in as many ways as...Ch. 7 - Hard water often contains dissolved Ca2+ and Mg2+...Ch. 7 - Lakes that have been acidified by acid rain...Ch. 7 - 103. What solution can you add to each cation...Ch. 7 - Prob. 104ECh. 7 - A solution contains an unknown amount of dissolved...Ch. 7 - Prob. 106ECh. 7 - Prob. 107ECh. 7 - Prob. 108ECh. 7 - 109. Shown here are molecular views of two...Ch. 7 - Precipitation reactions often produce brilliant...Ch. 7 - Prob. 111QGWCh. 7 - Memorize the solubility rules. Without referring...Ch. 7 - Define and give an example of each of the...Ch. 7 - Water samples often contain dissolved ions such as...
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- Identify the unknown compound from its IR and proton NMR spectra. C4H6O: 'H NMR: 82.43 (1H, t, J = 2 Hz); 8 3.41 (3H, s); 8 4.10 (2H, d, J = 2 Hz) IR: 2125, 3300 cm¹ The C4H6O compound liberates a gas when treated with C2H5 MgBr. Draw the unknown compound. Select Draw с H Templates Morearrow_forwardPlease help with number 6 I got a negative number could that be right?arrow_forward1,4-Dimethyl-1,3-cyclohexadiene can undergo 1,2- or 1,4-addition with hydrogen halides. (a) 1,2-Addition i. Draw the carbocation intermediate(s) formed during the 1,2-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,2-addition product formed during the reaction in (i)? (b) 1,4-Addition i. Draw the carbocation intermediate(s) formed during the 1,4-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,4-addition product formed from the reaction in (i)? (c) What is the kinetic product from the reaction of one mole of hydrobromic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (d) What is the thermodynamic product from the reaction of one mole of hydrobro-mic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (e) What major product will result when 1,4-dimethyl-1,3-cyclohexadiene is treated with one mole of hydrobromic acid at - 78 deg * C ? Explain your reasoning.arrow_forward
- Give the product of the bimolecular elimination from each of the isomeric halogenated compounds. Reaction A Reaction B. КОВ CH₂ HotBu +B+ ко HOIBU +Br+ Templates More QQQ Select Cv Templates More Cras QQQ One of these compounds undergoes elimination 50x faster than the other. Which one and why? Reaction A because the conformation needed for elimination places the phenyl groups and to each other Reaction A because the conformation needed for elimination places the phenyl groups gauche to each other. ◇ Reaction B because the conformation needed for elimination places the phenyl groups gach to each other. Reaction B because the conformation needed for elimination places the phenyl groups anti to each other.arrow_forwardFive isomeric alkenes. A through each undergo catalytic hydrogenation to give 2-methylpentane The IR spectra of these five alkenes have the key absorptions (in cm Compound Compound A –912. (§), 994 (5), 1643 (%), 3077 (1) Compound B 833 (3), 1667 (W), 3050 (weak shoulder on C-Habsorption) Compound C Compound D) –714 (5), 1665 (w), 3010 (m) 885 (3), 1650 (m), 3086 (m) 967 (5), no aharption 1600 to 1700, 3040 (m) Compound K Match each compound to the data presented. Compound A Compound B Compound C Compound D Compoundarrow_forward7. The three sets of replicate results below were accumulated for the analysis of the same sample. Pool these data to obtain the most efficient estimate of the mean analyte content and the standard deviation. Lead content/ppm: Set 1 Set 2 Set 3 1. 9.76 9.87 9.85 2. 9.42 9.64 9.91 3. 9.53 9.71 9.42 9.81 9.49arrow_forward
- Draw the Zaitsev product famed when 2,3-dimethylpentan-3-of undergoes an El dehydration. CH₂ E1 OH H₁PO₁ Select Draw Templates More QQQ +H₂Oarrow_forwardComplete the clean-pushing mechanism for the given ether synthesia from propanol in concentrated sulfurica140°C by adding any mining aloms, bands, charges, nonbonding electron pairs, and curved arrows. Draw hydrogen bonded to cayan, when applicable. ore 11,0 HPC Step 1: Draw curved arrows Step 2: Complete the intend carved Q2Q 56 QQQ Step 3: Complete the intermediate and add curved Step 4: Modify the structures to draw the QQQ QQQarrow_forward6. In an experiment the following replicate set of volume measurements (cm3) was recorded: (25.35, 25.80, 25.28, 25.50, 25.45, 25.43) A. Calculate the mean of the raw data. B. Using the rejection quotient (Q-test) reject any questionable results. C. Recalculate the mean and compare it with the value obtained in 2(a).arrow_forward
- A student proposes the transformation below in one step of an organic synthesis. There may be one or more reactants missing from the left-hand side, but there are no products missing from the right-hand side. There may also be catalysts, small inorganic reagents, and other important reaction conditions missing from the arrow. • Is the student's transformation possible? If not, check the box under the drawing area. • If the student's transformation is possible, then complete the reaction by adding any missing reactants to the left-hand side, and adding required catalysts, inorganic reagents, or other important reaction conditions above and below the arrow. • You do not need to balance the reaction, but be sure every important organic reactant or product is shown. + T G OH де OH This transformation can't be done in one step.arrow_forwardMacmillan Leaming Draw the major organic product of the reaction. 1. CH3CH2MgBr 2. H+ - G Select Draw Templates More H о QQarrow_forwardDraw the condensed structure of 3-hydroxy-2-butanone. Click anywhere to draw the first atom of your structure.arrow_forward
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