INTRODUCTORY CHEMISTRY-W/SEL.SOLN.MAN.
6th Edition
ISBN: 9780134845609
Author: Tro
Publisher: PEARSON
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Chapter 7, Problem 62E
Interpretation Introduction
Interpretation:
Correct the given misplaced soluble and insoluble compounds by moving it into to the correct columns.
Concept Introduction:
A substance is soluble in a liquid when it dissolves in it and is insoluble when it cannot dissolves in a liquid.
The ability of a compound to dissolve in a liquid is referred to as solubility.
An aqueous solution contains variety of ions which can combine together to give many ionic compounds.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 7 Solutions
INTRODUCTORY CHEMISTRY-W/SEL.SOLN.MAN.
Ch. 7 - Which process is a chemical reaction? a. Gasoline...Ch. 7 - How many oxygen atoms are on the reactant side of...Ch. 7 - Q3. What is the coefficient for hydrogen in the...Ch. 7 - Q4. Determine the correct set of coefficients to...Ch. 7 - Which compound is soluble in water? a. Fe(OH)2 b....Ch. 7 - Name the precipitate that forms (if any) when...Ch. 7 - Q7. Which set of reactants forms a solid...Ch. 7 - Q8. What is the net ionic equation for the...Ch. 7 - Q9. Complete the equation:
a.
b.
c.
d. No...Ch. 7 - Prob. 10SAQ
Ch. 7 - What are the products of the balanced equation for...Ch. 7 - Q12. Precipitation reactions are best classified...Ch. 7 - 1. What is a chemical reaction? List some...Ch. 7 - If you could observe atoms and molecules with the...Ch. 7 - 3. What are the main indications that a chemical...Ch. 7 - What is a chemical equation? Provide an example...Ch. 7 - Prob. 5ECh. 7 - To balance a chemical equation, adjust the...Ch. 7 - 7. Is the chemical equation balanced? Why or why...Ch. 7 - 8. What is an aqueous solution? List two...Ch. 7 - 9. What does it mean if a compound is referred to...Ch. 7 - Explain what happens to an ionic substance when it...Ch. 7 - Do polyatomic ions dissociate when they dissolve...Ch. 7 - What is a strong electrolyte solution?Ch. 7 - 13. What are the solubility rules, and how are...Ch. 7 - What is a precipitation reaction? Provide an...Ch. 7 - 15. Is the precipitate in a precipitation reaction...Ch. 7 - 16. Describe the difference between a molecular...Ch. 7 - What is an acid-base reaction? List an example and...Ch. 7 - Prob. 18ECh. 7 - What is a gas evolution reaction? Give an example.Ch. 7 - What is a redox reaction? Give an example.Ch. 7 - Prob. 21ECh. 7 - Prob. 22ECh. 7 - 23. Explain the difference between a synthesis...Ch. 7 - 24. Explain the difference between a...Ch. 7 - Which observation is consistent with a chemical...Ch. 7 - Which observation is consistent with a chemical...Ch. 7 - Vinegar forms bubbles when it is poured into the...Ch. 7 - When a chemical drain opener is added to a clogged...Ch. 7 - 29. When a commercial hair bleaching mixture is...Ch. 7 - When water is boiled in a pot, it bubbles. Has a...Ch. 7 - For each chemical equation (which may or may not...Ch. 7 - For each chemical equation (which may or may not...Ch. 7 - 33. Consider the unbalanced chemical equation.
A...Ch. 7 - Consider the unbalanced chemical equation....Ch. 7 - Prob. 35ECh. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - 39. When solid sodium is added to liquid water, it...Ch. 7 - When iron rusts, solid iron reacts with gaseous...Ch. 7 - 41. Sulfuric acid in acid rain forms when gaseous...Ch. 7 - Nitric acid in acid rain forms when gaseous...Ch. 7 - Prob. 43ECh. 7 - Prob. 44ECh. 7 - 45. Write a balance chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - 47. Balance each chemical equation.
a.
b.
c.
d....Ch. 7 - Balance each chemical equation. a....Ch. 7 - 49. Balance each chemical equation.
a.
b.
c.
d....Ch. 7 - Balance each chemical equation. a....Ch. 7 - 51. Is each chemical equation correctly balanced?...Ch. 7 - Prob. 52ECh. 7 - Prob. 53ECh. 7 - Propane camping stoves produce heat by the...Ch. 7 - 55. Catalytic converters work to remove nitrogen...Ch. 7 - Prob. 56ECh. 7 - 57. Is each compound soluble or insoluble? For the...Ch. 7 - 58. Is each compound soluble or insoluble? For the...Ch. 7 - 59. Pair each cation on the left with an anion on...Ch. 7 - Pair each cation on the left with an anion on the...Ch. 7 - 61. Move any misplaced compounds to the correct...Ch. 7 - Prob. 62ECh. 7 - Complete and balance each equation. If no reaction...Ch. 7 - Complete and balance each equation. If no reaction...Ch. 7 - Write a molecular equation for the precipitation...Ch. 7 - Write a molecular equation for the precipitation...Ch. 7 - Correct any incorrect equations. If no reaction...Ch. 7 - 68. Correct any incorrect equations. If no...Ch. 7 - 69. Identify the spectator ions in the complete...Ch. 7 - Identify the spectator ions in the complete ionic...Ch. 7 - 71. Write balanced complete ionic and net ionic...Ch. 7 - Write balanced complete ionic and net ionic...Ch. 7 - Mercury(I) ions (Hg22+) can be removed from...Ch. 7 - 74. Lead ions can be removed from solution by...Ch. 7 - Write complete ionic and net ionic equations for...Ch. 7 - 76. Write complete ionic and net ionic equations...Ch. 7 - When a hydrochloric acid solution is combined with...Ch. 7 - 78. A breaker of nitric acid is neutralized with...Ch. 7 - 79. Complete and balance each acid-base...Ch. 7 - Complete and balance each acid-base reaction. a....Ch. 7 - 81. Complete and balance each gas evolution...Ch. 7 - Complete and balance each gas evolution reaction....Ch. 7 - Which reactions are redox reactions? a....Ch. 7 - Which reactions are redox reactions? a....Ch. 7 - Prob. 85ECh. 7 - 86. Complete and balance each combustion...Ch. 7 - 87. Write a balanced chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - 89. Classify each chemical reaction as a...Ch. 7 - 90. Classify each chemical reaction as a...Ch. 7 - Prob. 91ECh. 7 - 92. A main source of soulful oxide pollutants are...Ch. 7 - Predict the products of each reaction and write...Ch. 7 - Predict the products of each reaction and write...Ch. 7 - Prob. 95ECh. 7 - 96. Predict the products of each reaction and...Ch. 7 - Predict the type of reaction (if any) that occurs...Ch. 7 - Prob. 98ECh. 7 - Classify each reaction in as many ways as...Ch. 7 - Classify each reaction in as many ways as...Ch. 7 - Hard water often contains dissolved Ca2+ and Mg2+...Ch. 7 - Lakes that have been acidified by acid rain...Ch. 7 - 103. What solution can you add to each cation...Ch. 7 - Prob. 104ECh. 7 - A solution contains an unknown amount of dissolved...Ch. 7 - Prob. 106ECh. 7 - Prob. 107ECh. 7 - Prob. 108ECh. 7 - 109. Shown here are molecular views of two...Ch. 7 - Precipitation reactions often produce brilliant...Ch. 7 - Prob. 111QGWCh. 7 - Memorize the solubility rules. Without referring...Ch. 7 - Define and give an example of each of the...Ch. 7 - Water samples often contain dissolved ions such as...
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