INTRODUCTORY CHEMISTRY-W/SEL.SOLN.MAN.
6th Edition
ISBN: 9780134845609
Author: Tro
Publisher: PEARSON
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Textbook Question
Chapter 7, Problem 13E
What are the solubility rules, and how are they useful?
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Students have asked these similar questions
6. The equilibrium constant for the reaction
2 HBr (g)
→ H2(g) + Br2(g)
Can be expressed by the empirical formula
11790 K
In K-6.375 + 0.6415 In(T K-¹)
-
T
Use this formula to determine A,H as a function of temperature. Calculate A,-H at 25 °C and at
100 °C.
3. Nitrosyl chloride, NOCI, decomposes according to
2 NOCI (g) → 2 NO(g)
+ Cl2(g)
Assuming that we start with no moles of NOCl (g) and no NO(g) or Cl2(g), derive an expression
for Kp in terms of the equilibrium value of the extent of reaction, Seq, and the pressure, P.
Given that K₂ = 2.00 × 10-4, calculate Seq/
of
29/no when P = 0.080 bar. What is the new value
по
ƒª/ at equilibrium when P = 0.160 bar? Is this result in accord with Le Châtelier's
Principle?
Consider the following chemical equilibrium:
2SO2(g) + O2(g) = 2SO3(g)
•
Write the equilibrium constant expression for this reaction.
Now compare it to the equilibrium constant expression for the related reaction:
•
.
1
SO2(g) + O2(g) = SO3(g)
2
How do these two equilibrium expressions differ?
What important principle about the dependence of equilibrium constants on the stoichiometry of a
reaction can you learn from this comparison?
Chapter 7 Solutions
INTRODUCTORY CHEMISTRY-W/SEL.SOLN.MAN.
Ch. 7 - Which process is a chemical reaction? a. Gasoline...Ch. 7 - How many oxygen atoms are on the reactant side of...Ch. 7 - Q3. What is the coefficient for hydrogen in the...Ch. 7 - Q4. Determine the correct set of coefficients to...Ch. 7 - Which compound is soluble in water? a. Fe(OH)2 b....Ch. 7 - Name the precipitate that forms (if any) when...Ch. 7 - Q7. Which set of reactants forms a solid...Ch. 7 - Q8. What is the net ionic equation for the...Ch. 7 - Q9. Complete the equation:
a.
b.
c.
d. No...Ch. 7 - Prob. 10SAQ
Ch. 7 - What are the products of the balanced equation for...Ch. 7 - Q12. Precipitation reactions are best classified...Ch. 7 - 1. What is a chemical reaction? List some...Ch. 7 - If you could observe atoms and molecules with the...Ch. 7 - 3. What are the main indications that a chemical...Ch. 7 - What is a chemical equation? Provide an example...Ch. 7 - Prob. 5ECh. 7 - To balance a chemical equation, adjust the...Ch. 7 - 7. Is the chemical equation balanced? Why or why...Ch. 7 - 8. What is an aqueous solution? List two...Ch. 7 - 9. What does it mean if a compound is referred to...Ch. 7 - Explain what happens to an ionic substance when it...Ch. 7 - Do polyatomic ions dissociate when they dissolve...Ch. 7 - What is a strong electrolyte solution?Ch. 7 - 13. What are the solubility rules, and how are...Ch. 7 - What is a precipitation reaction? Provide an...Ch. 7 - 15. Is the precipitate in a precipitation reaction...Ch. 7 - 16. Describe the difference between a molecular...Ch. 7 - What is an acid-base reaction? List an example and...Ch. 7 - Prob. 18ECh. 7 - What is a gas evolution reaction? Give an example.Ch. 7 - What is a redox reaction? Give an example.Ch. 7 - Prob. 21ECh. 7 - Prob. 22ECh. 7 - 23. Explain the difference between a synthesis...Ch. 7 - 24. Explain the difference between a...Ch. 7 - Which observation is consistent with a chemical...Ch. 7 - Which observation is consistent with a chemical...Ch. 7 - Vinegar forms bubbles when it is poured into the...Ch. 7 - When a chemical drain opener is added to a clogged...Ch. 7 - 29. When a commercial hair bleaching mixture is...Ch. 7 - When water is boiled in a pot, it bubbles. Has a...Ch. 7 - For each chemical equation (which may or may not...Ch. 7 - For each chemical equation (which may or may not...Ch. 7 - 33. Consider the unbalanced chemical equation.
A...Ch. 7 - Consider the unbalanced chemical equation....Ch. 7 - Prob. 35ECh. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - 39. When solid sodium is added to liquid water, it...Ch. 7 - When iron rusts, solid iron reacts with gaseous...Ch. 7 - 41. Sulfuric acid in acid rain forms when gaseous...Ch. 7 - Nitric acid in acid rain forms when gaseous...Ch. 7 - Prob. 43ECh. 7 - Prob. 44ECh. 7 - 45. Write a balance chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - 47. Balance each chemical equation.
a.
b.
c.
d....Ch. 7 - Balance each chemical equation. a....Ch. 7 - 49. Balance each chemical equation.
a.
b.
c.
d....Ch. 7 - Balance each chemical equation. a....Ch. 7 - 51. Is each chemical equation correctly balanced?...Ch. 7 - Prob. 52ECh. 7 - Prob. 53ECh. 7 - Propane camping stoves produce heat by the...Ch. 7 - 55. Catalytic converters work to remove nitrogen...Ch. 7 - Prob. 56ECh. 7 - 57. Is each compound soluble or insoluble? For the...Ch. 7 - 58. Is each compound soluble or insoluble? For the...Ch. 7 - 59. Pair each cation on the left with an anion on...Ch. 7 - Pair each cation on the left with an anion on the...Ch. 7 - 61. Move any misplaced compounds to the correct...Ch. 7 - Prob. 62ECh. 7 - Complete and balance each equation. If no reaction...Ch. 7 - Complete and balance each equation. If no reaction...Ch. 7 - Write a molecular equation for the precipitation...Ch. 7 - Write a molecular equation for the precipitation...Ch. 7 - Correct any incorrect equations. If no reaction...Ch. 7 - 68. Correct any incorrect equations. If no...Ch. 7 - 69. Identify the spectator ions in the complete...Ch. 7 - Identify the spectator ions in the complete ionic...Ch. 7 - 71. Write balanced complete ionic and net ionic...Ch. 7 - Write balanced complete ionic and net ionic...Ch. 7 - Mercury(I) ions (Hg22+) can be removed from...Ch. 7 - 74. Lead ions can be removed from solution by...Ch. 7 - Write complete ionic and net ionic equations for...Ch. 7 - 76. Write complete ionic and net ionic equations...Ch. 7 - When a hydrochloric acid solution is combined with...Ch. 7 - 78. A breaker of nitric acid is neutralized with...Ch. 7 - 79. Complete and balance each acid-base...Ch. 7 - Complete and balance each acid-base reaction. a....Ch. 7 - 81. Complete and balance each gas evolution...Ch. 7 - Complete and balance each gas evolution reaction....Ch. 7 - Which reactions are redox reactions? a....Ch. 7 - Which reactions are redox reactions? a....Ch. 7 - Prob. 85ECh. 7 - 86. Complete and balance each combustion...Ch. 7 - 87. Write a balanced chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - 89. Classify each chemical reaction as a...Ch. 7 - 90. Classify each chemical reaction as a...Ch. 7 - Prob. 91ECh. 7 - 92. A main source of soulful oxide pollutants are...Ch. 7 - Predict the products of each reaction and write...Ch. 7 - Predict the products of each reaction and write...Ch. 7 - Prob. 95ECh. 7 - 96. Predict the products of each reaction and...Ch. 7 - Predict the type of reaction (if any) that occurs...Ch. 7 - Prob. 98ECh. 7 - Classify each reaction in as many ways as...Ch. 7 - Classify each reaction in as many ways as...Ch. 7 - Hard water often contains dissolved Ca2+ and Mg2+...Ch. 7 - Lakes that have been acidified by acid rain...Ch. 7 - 103. What solution can you add to each cation...Ch. 7 - Prob. 104ECh. 7 - A solution contains an unknown amount of dissolved...Ch. 7 - Prob. 106ECh. 7 - Prob. 107ECh. 7 - Prob. 108ECh. 7 - 109. Shown here are molecular views of two...Ch. 7 - Precipitation reactions often produce brilliant...Ch. 7 - Prob. 111QGWCh. 7 - Memorize the solubility rules. Without referring...Ch. 7 - Define and give an example of each of the...Ch. 7 - Water samples often contain dissolved ions such as...
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- Given Kp for 2 reactions. Find the Kp for the following reaction: BrCl(g)+ 1/2 I2(g) ->IBr(g) + 1/2 Cl2(g)arrow_forwardFor a certain gas-phase reaction at constant pressure, the equilibrium constant Kp is observed to double when the temperature increases from 300 K to 400 K. Calculate the enthalpy change of the reaction, Ah, using this information.arrow_forwardHydrogen bonding in water plays a key role in its physical properties. Assume that the energy required to break a hydrogen bond is approximately 8 kJ/mol. Consider a simplified two-state model where a "formed" hydrogen bond is in the ground state and a "broken" bond is in the excited state. Using this model: • Calculate the fraction of broken hydrogen bonds at T = 300 K, and also at T = 273 K and T = 373 K. • At what temperature would approximately 50% of the hydrogen bonds be broken? • What does your result imply about the accuracy or limitations of the two-state model in describing hydrogen bonding in water? Finally, applying your understanding: • Would you expect it to be easier or harder to vaporize water at higher temperatures? Why? If you were to hang wet laundry outside, would it dry more quickly on a warm summer day or on a cold winter day, assuming humidity is constant?arrow_forward
- (3 pts) Use the Kapustinskii equation to calculate the lattice enthalpy for MgBr2 anddiscuss any differences between this result and that from #4.arrow_forward(3 pts) Silver metal adopts a fcc unit cell structure and has an atomic radius of 144 pm. Fromthis information, calculate the density of silver. Show all work.arrow_forward4. (3 pts) From the information below, determine the lattice enthalpy for MgBr2. Show all work. AH/(kJ mol-¹) Sublimation of Mg(s) +148 lonization of Mg(g) +2187 to Mg2+(g) Vaporization of Br₂(1) +31 Dissociation of Br,(g) +193 Electron gain by Br(g) -331 Formation of MgBr₂(s) -524arrow_forward
- 1. (4 pts-2 pts each part) Consider the crystal structures of NaCl, ZnS, and CsCl (not necessarily shown in this order). a. For one of the three compounds, justify that the unit cell is consistent with stoichiometry of the compound. b. In each of the crystal structures, the cations reside in certain holes in the anions' packing structures. For each compound, what type of holes are occupied by the cations and explain why those particular types of holes are preferred.arrow_forward(2 pts) What do you expect to happen in a Na2O crystal if a Cl− ion replaces one of the O2−ions in the lattice?arrow_forward(2 pts) WSe2 is an ionic compound semiconductor that can be made to be p-type or n-type.What must happen to the chemical composition for it to be p-type? What must happen tothe chemical composition for it to be n-type?arrow_forward
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