Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Chapter 7, Problem 104E
There are three possible structures for
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There are three possible structures for PCl2F3 with phosphorus as the central atom. Draw them and discuss how measurements of dipole moments could help distinguish among them.
. Assume that the third-period element phosphorus forms a diatomic molecule, P2, in an analogous way as nitrogen does to form N2. (a) Write the electronic configuration for P2. Use [Ne2] to represent the electron configuration for the first two periods. (b) Calculate its bond order. (c) What are its magnetic properties (diamagnetic or paramagnetic)?
Phosphorus pentachloride, a key industrial compound with annual world production of about 2 x 107 kg, is used to make other compounds. It reacts with sulfur dioxide to produce phosphorus oxychloride (POCl3) and thionyl chloride (SOCl2). Draw a Lewis structure, and name the molecular shape of each product.
Chapter 7 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 7 - Does a cation gain protons to form a positive...Ch. 7 - Iron(III) sulfate [Fe2( SO 4)3] is composed of...Ch. 7 - Which of the following atoms would be expected to...Ch. 7 - Which of the following atoms would be expected to...Ch. 7 - Predict the charge on the monatomic ions formed...Ch. 7 - Predict the charge on the monatomic ions formed...Ch. 7 - Write the electron configuration for each of the...Ch. 7 - Write the electron configuration for the monatomic...Ch. 7 - Write out the full electron configuration for each...Ch. 7 - From the labels of several commercial products,...
Ch. 7 - Why is it incorrect to speak of a molecule of...Ch. 7 - What information can you use to predict whether a...Ch. 7 - Predict which of the following compounds are ionic...Ch. 7 - Explain the difference between a nonpolar covalent...Ch. 7 - From its position in the periodic table, determine...Ch. 7 - From its position in the periodic table, determine...Ch. 7 - From their positions in the periodic able, arrange...Ch. 7 - From their positions in the periodic table,...Ch. 7 - Which atoms can bond to sulfur so as to produce a...Ch. 7 - Which is the most polar bond? (a) CC (b) CH (c) NH...Ch. 7 - Identify the more polar bond in each of the...Ch. 7 - Which of the following molecules or ions contain...Ch. 7 - Write the Lewis symbols for each of the following...Ch. 7 - Many monatomic ions are found in seawater,...Ch. 7 - Write the Lewis symbols of the ions in each of the...Ch. 7 - Iii (he Lewis structures listed here, M and X...Ch. 7 - Write the Lewis structure for the diatomic...Ch. 7 - Write Lewis structures for the following: (a) H2...Ch. 7 - Write Lewis structures for the following: (a) O2...Ch. 7 - Write Lewis structures for the following: (a) ClF3...Ch. 7 - Write Lewis structures for the following: (a) SeF6...Ch. 7 - Write Lewis structures for: (a) PO43 (b) ICl4 (c)...Ch. 7 - Correct the following statement: The bonds in...Ch. 7 - Write Lewis structures for the following molecules...Ch. 7 - Methanol, H3COH, is used as the fuel in some race...Ch. 7 - Many planets in our solar system contain organic...Ch. 7 - Carbon tetrachloride was formerly used in fire...Ch. 7 - Identify the atoms that correspond to each of the...Ch. 7 - The arrangement of atoms in several biologically...Ch. 7 - A compound with a molar mass of about 28 g/mol...Ch. 7 - A compound with a molar mass of about 42 g/mol...Ch. 7 - Two arrangements of atoms are possible for a...Ch. 7 - How are single, double, and triple bonds similar?...Ch. 7 - Write resonance forms that describe the...Ch. 7 - Write resonance forms that describe the...Ch. 7 - Write the resonance forms of ozone, Q3, the...Ch. 7 - Sodium nitrite, which has been used to preserve...Ch. 7 - In terms of the bonds present, explain why acetic...Ch. 7 - Write the Lewis structures for the following, and...Ch. 7 - Toothpastes containing sodium hydrogen carbonate...Ch. 7 - Determine the formal charge of each element in the...Ch. 7 - Determine the formal charge of each element in the...Ch. 7 - Calculate the formal charge of chlorine in the...Ch. 7 - 54. Calculate the formal charge of each element in...Ch. 7 - Draw all possible resonance structures for each of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Draw the structure of hydroxylamine, H3NO, and...Ch. 7 - Iodine forms a series of fluorides (listed here)....Ch. 7 - Write the Lewis structure and chemical formula of...Ch. 7 - Which of the following structures would we expect...Ch. 7 - Sulfuric acid is the industrial chemical produced...Ch. 7 - Which bond in each of the following pairs of bonds...Ch. 7 - Using the bond energies in Table 7.2, determine...Ch. 7 - Using the bond energies in Table 7.2, determine...Ch. 7 - When a molecule can form two different structures,...Ch. 7 - How does the bond energy of HCl(g) differ from the...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Complete the following Lewis structure by adding...Ch. 7 - Use the bond energy to calculate an approximate...Ch. 7 - Element First Ionization Energy (kJImol) Second...Ch. 7 - The lattice energy of LiF is 1023 kJ/mol, and the...Ch. 7 - For which of the following substances is the least...Ch. 7 - The reaction of a metal, M, with a halogen, X2,...Ch. 7 - The lattice energy of LiF is 1023 kJ/mol, and the...Ch. 7 - Which compound in each of the following pairs has...Ch. 7 - Which compound in each of the following pairs has...Ch. 7 - Which of the following compounds requires the most...Ch. 7 - Which of the following compounds requires the most...Ch. 7 - The lattice energy of KF is 794 kJ/mol, and the...Ch. 7 - Explain why the HOH molecule is bent, whereas the...Ch. 7 - What feature of a Lewis structure can be used to...Ch. 7 - Explain the difference between electron-pair...Ch. 7 - Why is the HNH angle in NH3 smaller than the HCH...Ch. 7 - Explain how a molecule that contains polar bonds...Ch. 7 - As a general rule, MX molecules (where M...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Identify the electron pair geometry and the...Ch. 7 - What are the electron-pair geometry and the...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Identify the electron pair geometry and the...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Which of the following molecules and ions contain...Ch. 7 - Which of these molecules and ions contain polar...Ch. 7 - Which of the following molecules have dipole...Ch. 7 - Identify the molecules with a dipole moment: (a)...Ch. 7 - The molecule XF3 has a dipole moment. Is X boron...Ch. 7 - The molecule XCl2 has a dipole moment. Is X...Ch. 7 - Is the Cl2BBCl2 molecule polar or nonpolar?Ch. 7 - There are three possible structures for PCl2F3...Ch. 7 - Describe the molecular structure around the...Ch. 7 - Draw the Lewis structures and predict the shape of...Ch. 7 - A molecule with the formula AB2, in which A and B...Ch. 7 - A molecule with the formula AB3, in which A and B...Ch. 7 - Draw the Lewis electron dot structures for these...Ch. 7 - What is the molecular structure of the stable form...Ch. 7 - A compound with a molar mass of about 42 g/mol...Ch. 7 - Use the simulation...Ch. 7 - Use the simulation...Ch. 7 - Use the Molecule Shape simulator...Ch. 7 - Use the Molecule Shape simulator...Ch. 7 - Use the Molecule Shape simulator...
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- It is possible to write a simple Lewis structure for the SO42- ion, involving only single bonds, which follows the octet rule. However, Linus Pauling and others have suggested an alternative structure, involving double bonds, in which the sulfur atom is surrounded by six electron pairs. (a) Draw the two Lewis structures. (b) What geometries are predicted for the two structures? (c) What is the hybridization of sulfur in each case? (d) What are the formal charges of the atoms in the two structures?arrow_forwardDescribe the structure of a P2 molecule in valence-bond terms. Why is P4 a more stable form of molecular phosphorus than P2?arrow_forwardFormic acid (HCOOH; structural formula shown below) is secreted by certain species of ants when they bite. Rank the relative strengths of (a) the C-O and C=O bonds and (b) the H¬C and H¬O bonds. Explain these rankings.arrow_forward
- Which of the following bonds are polar: (a) P—O; (b) S—F; (c) Br—Br; (d) O—Cl? Which is the more electronegative atom in each polar bond?arrow_forwardChloral, Cl3C—CH=O, reacts with water to form the sedative and hypnotic agent chloral hydrate, Cl3C—CH(OH)2. Draw Lewis structures for these substances, and describe the change in molecular shape, if any, that occurs around each of the carbon atoms during the reaction.arrow_forwardChemical species are said to be isoelectronic if they have the same Lewis structure (regardless of charge). Consider these ions and write a Lewis structure for a neutral molecule that is isoelectronic with them. (a) CN–, (b) NH4+ (c) CO3 2–arrow_forward
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