Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 7, Problem 47E
Sodium nitrite, which has been used to preserve bacon and other meats, is an ionic compound. Write the resonance forms of the nitrite ion,
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Sodium nitrite, which has been used to preserve bacon and other meats, is an ionic compound. Write the resonance forms of the nitrite ion, NO2– .
Acetyl chloride, CH₃C(O)Cl, is used as a reagent for the acylation of salicylic acid in the synthesis of aspirin. Draw the Lewis structure of CH₃C(O)Cl (with minimized formal charges) and then determine if the molecule is polar or nonpolar.
+
Use the Born-Haber cycle to calculate the lattice energy of KF. [The heat of sublimation of K is 91.6 kJ·mol−1 and
ΔfH(KF) = −567.3 kJ·mol−1.
Bond enthalpy for F2 is
158.8 kJ·mol−1.
Other data may be found in the Ionization Energies Table and the Electron Affinities Table.]
Chapter 7 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 7 - Does a cation gain protons to form a positive...Ch. 7 - Iron(III) sulfate [Fe2( SO 4)3] is composed of...Ch. 7 - Which of the following atoms would be expected to...Ch. 7 - Which of the following atoms would be expected to...Ch. 7 - Predict the charge on the monatomic ions formed...Ch. 7 - Predict the charge on the monatomic ions formed...Ch. 7 - Write the electron configuration for each of the...Ch. 7 - Write the electron configuration for the monatomic...Ch. 7 - Write out the full electron configuration for each...Ch. 7 - From the labels of several commercial products,...
Ch. 7 - Why is it incorrect to speak of a molecule of...Ch. 7 - What information can you use to predict whether a...Ch. 7 - Predict which of the following compounds are ionic...Ch. 7 - Explain the difference between a nonpolar covalent...Ch. 7 - From its position in the periodic table, determine...Ch. 7 - From its position in the periodic table, determine...Ch. 7 - From their positions in the periodic able, arrange...Ch. 7 - From their positions in the periodic table,...Ch. 7 - Which atoms can bond to sulfur so as to produce a...Ch. 7 - Which is the most polar bond? 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Calculate the formal charge of each element in...Ch. 7 - Draw all possible resonance structures for each of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Draw the structure of hydroxylamine, H3NO, and...Ch. 7 - Iodine forms a series of fluorides (listed here)....Ch. 7 - Write the Lewis structure and chemical formula of...Ch. 7 - Which of the following structures would we expect...Ch. 7 - Sulfuric acid is the industrial chemical produced...Ch. 7 - Which bond in each of the following pairs of bonds...Ch. 7 - Using the bond energies in Table 7.2, determine...Ch. 7 - Using the bond energies in Table 7.2, determine...Ch. 7 - When a molecule can form two different structures,...Ch. 7 - How does the bond energy of HCl(g) differ from the...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Complete the following Lewis structure by adding...Ch. 7 - Use the bond energy to calculate an approximate...Ch. 7 - Element First Ionization Energy (kJImol) Second...Ch. 7 - The lattice energy of LiF is 1023 kJ/mol, and the...Ch. 7 - For which of the following substances is the least...Ch. 7 - The reaction of a metal, M, with a halogen, X2,...Ch. 7 - The lattice energy of LiF is 1023 kJ/mol, and the...Ch. 7 - Which compound in each of the following pairs has...Ch. 7 - Which compound in each of the following pairs has...Ch. 7 - Which of the following compounds requires the most...Ch. 7 - Which of the following compounds requires the most...Ch. 7 - The lattice energy of KF is 794 kJ/mol, and the...Ch. 7 - Explain why the HOH molecule is bent, whereas the...Ch. 7 - What feature of a Lewis structure can be used to...Ch. 7 - Explain the difference between electron-pair...Ch. 7 - Why is the HNH angle in NH3 smaller than the HCH...Ch. 7 - Explain how a molecule that contains polar bonds...Ch. 7 - As a general rule, MX molecules (where M...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Identify the electron pair geometry and the...Ch. 7 - What are the electron-pair geometry and the...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Identify the electron pair geometry and the...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Which of the following molecules and ions contain...Ch. 7 - Which of these molecules and ions contain polar...Ch. 7 - Which of the following molecules have dipole...Ch. 7 - Identify the molecules with a dipole moment: (a)...Ch. 7 - The molecule XF3 has a dipole moment. 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