Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 7, Problem 62E
Which of the following structures would we expect for nitrous acid? Determine the formal charges:
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Chapter 7 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 7 - Does a cation gain protons to form a positive...Ch. 7 - Iron(III) sulfate [Fe2( SO 4)3] is composed of...Ch. 7 - Which of the following atoms would be expected to...Ch. 7 - Which of the following atoms would be expected to...Ch. 7 - Predict the charge on the monatomic ions formed...Ch. 7 - Predict the charge on the monatomic ions formed...Ch. 7 - Write the electron configuration for each of the...Ch. 7 - Write the electron configuration for the monatomic...Ch. 7 - Write out the full electron configuration for each...Ch. 7 - From the labels of several commercial products,...
Ch. 7 - Why is it incorrect to speak of a molecule of...Ch. 7 - What information can you use to predict whether a...Ch. 7 - Predict which of the following compounds are ionic...Ch. 7 - Explain the difference between a nonpolar covalent...Ch. 7 - From its position in the periodic table, determine...Ch. 7 - From its position in the periodic table, determine...Ch. 7 - From their positions in the periodic able, arrange...Ch. 7 - From their positions in the periodic table,...Ch. 7 - Which atoms can bond to sulfur so as to produce a...Ch. 7 - Which is the most polar bond? (a) CC (b) CH (c) NH...Ch. 7 - Identify the more polar bond in each of the...Ch. 7 - Which of the following molecules or ions contain...Ch. 7 - Write the Lewis symbols for each of the following...Ch. 7 - Many monatomic ions are found in seawater,...Ch. 7 - Write the Lewis symbols of the ions in each of the...Ch. 7 - Iii (he Lewis structures listed here, M and X...Ch. 7 - Write the Lewis structure for the diatomic...Ch. 7 - Write Lewis structures for the following: (a) H2...Ch. 7 - Write Lewis structures for the following: (a) O2...Ch. 7 - Write Lewis structures for the following: (a) ClF3...Ch. 7 - Write Lewis structures for the following: (a) SeF6...Ch. 7 - Write Lewis structures for: (a) PO43 (b) ICl4 (c)...Ch. 7 - Correct the following statement: The bonds in...Ch. 7 - Write Lewis structures for the following molecules...Ch. 7 - Methanol, H3COH, is used as the fuel in some race...Ch. 7 - Many planets in our solar system contain organic...Ch. 7 - Carbon tetrachloride was formerly used in fire...Ch. 7 - Identify the atoms that correspond to each of the...Ch. 7 - The arrangement of atoms in several biologically...Ch. 7 - A compound with a molar mass of about 28 g/mol...Ch. 7 - A compound with a molar mass of about 42 g/mol...Ch. 7 - Two arrangements of atoms are possible for a...Ch. 7 - How are single, double, and triple bonds similar?...Ch. 7 - Write resonance forms that describe the...Ch. 7 - Write resonance forms that describe the...Ch. 7 - Write the resonance forms of ozone, Q3, the...Ch. 7 - Sodium nitrite, which has been used to preserve...Ch. 7 - In terms of the bonds present, explain why acetic...Ch. 7 - Write the Lewis structures for the following, and...Ch. 7 - Toothpastes containing sodium hydrogen carbonate...Ch. 7 - Determine the formal charge of each element in the...Ch. 7 - Determine the formal charge of each element in the...Ch. 7 - Calculate the formal charge of chlorine in the...Ch. 7 - 54. Calculate the formal charge of each element in...Ch. 7 - Draw all possible resonance structures for each of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Draw the structure of hydroxylamine, H3NO, and...Ch. 7 - Iodine forms a series of fluorides (listed here)....Ch. 7 - Write the Lewis structure and chemical formula of...Ch. 7 - Which of the following structures would we expect...Ch. 7 - Sulfuric acid is the industrial chemical produced...Ch. 7 - Which bond in each of the following pairs of bonds...Ch. 7 - Using the bond energies in Table 7.2, determine...Ch. 7 - Using the bond energies in Table 7.2, determine...Ch. 7 - When a molecule can form two different structures,...Ch. 7 - How does the bond energy of HCl(g) differ from the...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Complete the following Lewis structure by adding...Ch. 7 - Use the bond energy to calculate an approximate...Ch. 7 - Element First Ionization Energy (kJImol) Second...Ch. 7 - The lattice energy of LiF is 1023 kJ/mol, and the...Ch. 7 - For which of the following substances is the least...Ch. 7 - The reaction of a metal, M, with a halogen, X2,...Ch. 7 - The lattice energy of LiF is 1023 kJ/mol, and the...Ch. 7 - Which compound in each of the following pairs has...Ch. 7 - Which compound in each of the following pairs has...Ch. 7 - Which of the following compounds requires the most...Ch. 7 - Which of the following compounds requires the most...Ch. 7 - The lattice energy of KF is 794 kJ/mol, and the...Ch. 7 - Explain why the HOH molecule is bent, whereas the...Ch. 7 - What feature of a Lewis structure can be used to...Ch. 7 - Explain the difference between electron-pair...Ch. 7 - Why is the HNH angle in NH3 smaller than the HCH...Ch. 7 - Explain how a molecule that contains polar bonds...Ch. 7 - As a general rule, MX molecules (where M...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Identify the electron pair geometry and the...Ch. 7 - What are the electron-pair geometry and the...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Identify the electron pair geometry and the...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Which of the following molecules and ions contain...Ch. 7 - Which of these molecules and ions contain polar...Ch. 7 - Which of the following molecules have dipole...Ch. 7 - Identify the molecules with a dipole moment: (a)...Ch. 7 - The molecule XF3 has a dipole moment. Is X boron...Ch. 7 - The molecule XCl2 has a dipole moment. Is X...Ch. 7 - Is the Cl2BBCl2 molecule polar or nonpolar?Ch. 7 - There are three possible structures for PCl2F3...Ch. 7 - Describe the molecular structure around the...Ch. 7 - Draw the Lewis structures and predict the shape of...Ch. 7 - A molecule with the formula AB2, in which A and B...Ch. 7 - A molecule with the formula AB3, in which A and B...Ch. 7 - Draw the Lewis electron dot structures for these...Ch. 7 - What is the molecular structure of the stable form...Ch. 7 - A compound with a molar mass of about 42 g/mol...Ch. 7 - Use the simulation...Ch. 7 - Use the simulation...Ch. 7 - Use the Molecule Shape simulator...Ch. 7 - Use the Molecule Shape simulator...Ch. 7 - Use the Molecule Shape simulator...
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1. Why is the quantum-mechanical model of the atom important for understanding chemistry?
Chemistry: Structure and Properties
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- White phosphorus (P4) consists of four phosphorus atoms arranged at the corners of a tetrahedron. Draw the valence electrons on this structure to give a Lewis diagram that satisfies the octet rule.arrow_forwardThe Lewis structure of acetone is Circling the carbonyl carbon, i.e., the carbon atom attached to oxygen, and its octet gives Circling the oxygen atom and its octet gives Thus, atoms share electrons in making bonds, and a pair of electrons may be included in the octet of two different atoms. When computing the formal charge on an atom, the number of electrons that belong to that atom is compared with the number of electrons the atom would have in the unbonded and neutral state. If the two numbers are the same, the formal charge on the atom is zero. In a Lewis structure both electrons in an unshared pair belong to the atom, and one of every pair of shared (bonding) electrons belongs to the atom.arrow_forwardTwo Lewis structures can be written for nitrosyl fluoride, which contains one nitrogen, one oxygen, and one fluorine atom per molecule. Write the two Lewis structures land assign a formal charge to each atom.arrow_forward
- Assign formal charges to all atoms in the following Lewis diagrams. (a) SO42 (b) S2O32 (c) SbF3 (d) SCNarrow_forwardIn the Lewis structure for chloromethane, the chlorine atom is sharing _____ electron pair and “owns” _____ of those electrons. Also, the chlorine atom possesses two electrons from each of _____ unshared pairs. The total number of electrons that belong to chlorine is 7 . Chlorine is a Group ____ element. The formal charge on chlorine in chloromethane is ____.arrow_forwardDraw Lewis diagrams for the following ions. In the formula the symbol of the central atom is given first. (Hint:The valence octet may be expanded for the central atom.) (a) BrO4 (b) PCl6 (c) XeF6+arrow_forward
- Draw Lewis diagrams for the following compounds. In the formula the symbol of the central atom is given first. (Hint: The valence octet may be expanded for the central atom.) (a) PF5 (b) SF4 (c) XeO2F2arrow_forwardSulfur and oxygen form a series of 2 anions including sulfite, SO32, and sulfate, SO42. In addition to these, there are three other more complex anionsdithionite, S2O42, dithionate, S2O62, and tetrathionate, S4O62. Write correct Lewis structures for dithionite, dithionate, and tetrathionate ions.arrow_forwardA stable triatomic molecule can be formed that contains one atom each of nitrogen, sulfur, and fluorine. Three bonding structures are possible, depending on which is the central atom: NSF, SNF, and SFN. (a) Write a Lewis diagram for each of these molecules, indicating the formal charge on each atom. (b) Often, the structure with the least separation of formal charge is the most stable. Is this statement consistent with the observed structure for this molecule—namely, NSF, which has a central sulfur atom? (c) Does consideration of the electronegativities of N, S, and F from Figure 3.18 help rationalize this observed structure? Explain.arrow_forward
- Consider the incomplete structure shown. Determine the formal charge on the bromine atom in the structure. If the atom is formally neutral, indicate a charge of zero.arrow_forwardSome chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, HaPO, , in which the H atoms are bonded to O atoms. (a) What is the predicted dominant Lewis structure if satisfying the octet rule is the top eriterion? (b) What is the predicted dominant Lewis structure if achieving the best formal charges is the top criterion?arrow_forwardCalculate the formal charge assigned to the atom in Lewis structurearrow_forward
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