Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Chapter 7, Problem 103E
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How many neighbors does the proton that produces the multiplet below have?
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Draw a partial structure from the multiplet below. (The integration of the multiplet is 6)
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Using the additivity constants found in appendix G of your lab manual, calculate the approximate chemical
shifts of the protons indicated below. (Show your work!!!)
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1) Suppose 0.1 kg ice at 0°C (273K) is in 0.5kg water at 20°C (293K). What is the change in entropy of the ice as it melts at 0°?
To produce the original "water gas" mixture, carbon (in a combustible form known as coke) is reacted with steam: 131.4 kJ + H20(g) + C(s) → CO(g) + H2(g) From this information and the equations in the previous problem, calculate the enthalpy for the combustion or carbon to form carbon dioxide.
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An 'H-NMR of a compound is acquired. The integration for signal A is 5692 and the integration for signal
B is 25614. What is the simplest whole number ratio of protons for signals A and B? (Show your work!!!)
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Assign the carbons in the NMR below as either carbonyl, aromatic, or alkyl.
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Chapter 7 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 7 - Does a cation gain protons to form a positive...Ch. 7 - Iron(III) sulfate [Fe2( SO 4)3] is composed of...Ch. 7 - Which of the following atoms would be expected to...Ch. 7 - Which of the following atoms would be expected to...Ch. 7 - Predict the charge on the monatomic ions formed...Ch. 7 - Predict the charge on the monatomic ions formed...Ch. 7 - Write the electron configuration for each of the...Ch. 7 - Write the electron configuration for the monatomic...Ch. 7 - Write out the full electron configuration for each...Ch. 7 - From the labels of several commercial products,...
Ch. 7 - Why is it incorrect to speak of a molecule of...Ch. 7 - What information can you use to predict whether a...Ch. 7 - Predict which of the following compounds are ionic...Ch. 7 - Explain the difference between a nonpolar covalent...Ch. 7 - From its position in the periodic table, determine...Ch. 7 - From its position in the periodic table, determine...Ch. 7 - From their positions in the periodic able, arrange...Ch. 7 - From their positions in the periodic table,...Ch. 7 - Which atoms can bond to sulfur so as to produce a...Ch. 7 - Which is the most polar bond? (a) CC (b) CH (c) NH...Ch. 7 - Identify the more polar bond in each of the...Ch. 7 - Which of the following molecules or ions contain...Ch. 7 - Write the Lewis symbols for each of the following...Ch. 7 - Many monatomic ions are found in seawater,...Ch. 7 - Write the Lewis symbols of the ions in each of the...Ch. 7 - Iii (he Lewis structures listed here, M and X...Ch. 7 - Write the Lewis structure for the diatomic...Ch. 7 - Write Lewis structures for the following: (a) H2...Ch. 7 - Write Lewis structures for the following: (a) O2...Ch. 7 - Write Lewis structures for the following: (a) ClF3...Ch. 7 - Write Lewis structures for the following: (a) SeF6...Ch. 7 - Write Lewis structures for: (a) PO43 (b) ICl4 (c)...Ch. 7 - Correct the following statement: The bonds in...Ch. 7 - Write Lewis structures for the following molecules...Ch. 7 - Methanol, H3COH, is used as the fuel in some race...Ch. 7 - Many planets in our solar system contain organic...Ch. 7 - Carbon tetrachloride was formerly used in fire...Ch. 7 - Identify the atoms that correspond to each of the...Ch. 7 - The arrangement of atoms in several biologically...Ch. 7 - A compound with a molar mass of about 28 g/mol...Ch. 7 - A compound with a molar mass of about 42 g/mol...Ch. 7 - Two arrangements of atoms are possible for a...Ch. 7 - How are single, double, and triple bonds similar?...Ch. 7 - Write resonance forms that describe the...Ch. 7 - Write resonance forms that describe the...Ch. 7 - Write the resonance forms of ozone, Q3, the...Ch. 7 - Sodium nitrite, which has been used to preserve...Ch. 7 - In terms of the bonds present, explain why acetic...Ch. 7 - Write the Lewis structures for the following, and...Ch. 7 - Toothpastes containing sodium hydrogen carbonate...Ch. 7 - Determine the formal charge of each element in the...Ch. 7 - Determine the formal charge of each element in the...Ch. 7 - Calculate the formal charge of chlorine in the...Ch. 7 - 54. Calculate the formal charge of each element in...Ch. 7 - Draw all possible resonance structures for each of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Based on formal charge considerations, which of...Ch. 7 - Draw the structure of hydroxylamine, H3NO, and...Ch. 7 - Iodine forms a series of fluorides (listed here)....Ch. 7 - Write the Lewis structure and chemical formula of...Ch. 7 - Which of the following structures would we expect...Ch. 7 - Sulfuric acid is the industrial chemical produced...Ch. 7 - Which bond in each of the following pairs of bonds...Ch. 7 - Using the bond energies in Table 7.2, determine...Ch. 7 - Using the bond energies in Table 7.2, determine...Ch. 7 - When a molecule can form two different structures,...Ch. 7 - How does the bond energy of HCl(g) differ from the...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Using the standard enthalpy of formation data in...Ch. 7 - Complete the following Lewis structure by adding...Ch. 7 - Use the bond energy to calculate an approximate...Ch. 7 - Element First Ionization Energy (kJImol) Second...Ch. 7 - The lattice energy of LiF is 1023 kJ/mol, and the...Ch. 7 - For which of the following substances is the least...Ch. 7 - The reaction of a metal, M, with a halogen, X2,...Ch. 7 - The lattice energy of LiF is 1023 kJ/mol, and the...Ch. 7 - Which compound in each of the following pairs has...Ch. 7 - Which compound in each of the following pairs has...Ch. 7 - Which of the following compounds requires the most...Ch. 7 - Which of the following compounds requires the most...Ch. 7 - The lattice energy of KF is 794 kJ/mol, and the...Ch. 7 - Explain why the HOH molecule is bent, whereas the...Ch. 7 - What feature of a Lewis structure can be used to...Ch. 7 - Explain the difference between electron-pair...Ch. 7 - Why is the HNH angle in NH3 smaller than the HCH...Ch. 7 - Explain how a molecule that contains polar bonds...Ch. 7 - As a general rule, MX molecules (where M...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Identify the electron pair geometry and the...Ch. 7 - What are the electron-pair geometry and the...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Identify the electron pair geometry and the...Ch. 7 - Predict the electron pair geometry and the...Ch. 7 - Which of the following molecules and ions contain...Ch. 7 - Which of these molecules and ions contain polar...Ch. 7 - Which of the following molecules have dipole...Ch. 7 - Identify the molecules with a dipole moment: (a)...Ch. 7 - The molecule XF3 has a dipole moment. Is X boron...Ch. 7 - The molecule XCl2 has a dipole moment. Is X...Ch. 7 - Is the Cl2BBCl2 molecule polar or nonpolar?Ch. 7 - There are three possible structures for PCl2F3...Ch. 7 - Describe the molecular structure around the...Ch. 7 - Draw the Lewis structures and predict the shape of...Ch. 7 - A molecule with the formula AB2, in which A and B...Ch. 7 - A molecule with the formula AB3, in which A and B...Ch. 7 - Draw the Lewis electron dot structures for these...Ch. 7 - What is the molecular structure of the stable form...Ch. 7 - A compound with a molar mass of about 42 g/mol...Ch. 7 - Use the simulation...Ch. 7 - Use the simulation...Ch. 7 - Use the Molecule Shape simulator...Ch. 7 - Use the Molecule Shape simulator...Ch. 7 - Use the Molecule Shape simulator...
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